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This book presents the status quo of the structure, preparation, properties and applications of tetrahedrally bonded amorphous carbon (ta-C) films and compares them with related film systems. Tetrahedrally bonded amorphous carbon films (ta-C) combine some of the outstanding properties of diamond with the versatility of amorphous materials. The book compares experimental results with the predictions of theoretical analyses, condensing them to practicable rules. It is strictly application oriented, emphasizing the exceptional potential of ta-C for tribological coatings of tools and components.
Superlubricity - the state between sliding systems where friction is reduced to almost immeasurable amounts - holds great potential for improving both the economic and environmental credentials of moving mechanical systems. Research in this field has progressed tremendously in recent years, and there now exist several theoretical models, recognised techniques for computational simulations and interesting experimental evidence of superlubricity in practise. Superlubricity, Second Edition, presents an extensively revised and updated overview of these important developments, providing a comprehensive guide to the physical chemistry underpinning molecular mechanisms of friction and lubrication, current theoretical models used to explore and assess superlubricity, examples of its achievement in experimental systems, and discussion of potential future applications. Drawing on the extensive knowledge of its expert editors and global team of authors from across academia and industry, Superlubricity, Second Edition, is a great resource for all those with a need to understand, model or manipulate surface interactions for improved performance. - Fully expanded and updated to include the latest developments in the field, including a new section on liquid superlubricity - Highlights the key superlubricity theoretical models and reviews state of the art tools and techniques for superlubricity simulation - Includes information on the practical aspects and potential impact of superlubricity in moving mechanical systems ranging from nano/micro scales to meso/macro scales
A riveting look at the science, technology and people involved in overcoming early impracticalities of the fledgling chemical vapor deposition (CVD) synthesis method and its development in today's state of commercial readiness. Provides insights into numerous vapor phase techniques. Surveys the synthesis, structure, properties and applications of diamondlike carbon. Details current and rapidly emerging applications, manufacturing and markets.
A comprehensive look at the most widely employed carbon-based electrode materials and the numerous electroanalytical applications associated with them. A valuable reference for the emerging age of carbon-based electronics and electrochemistry, this book discusses diverse applications for nanocarbon materials in electrochemical sensing. It highlights the advantages and disadvantages of the different nanocarbon materials currently used for electroanalysis, covering the electrochemical sensing of small-sized molecules, such as metal ions and endocrine disrupting chemicals (EDCs), as well as large biomolecules such as DNA, RNA, enzymes and proteins. A comprehensive look at state-of-the-art applications for nanocarbon materials in electrochemical sensors Emphasizes the relationship between the carbon structures and surface chemistry, and electrochemical performance Covers a wide array of carbon nanomaterials, including nanocarbon films, carbon nanofibers, graphene, diamond nanostructures, and carbon-dots Edited by internationally renowned experts in the field with contributions from researchers at the cutting edge of nanocarbon electroanalysis Nanocarbons for Electroanalysis is a valuable working resource for all chemists and materials scientists working on carbon based-nanomaterials and electrochemical sensors. It also belongs on the reference shelves of academic researchers and industrial scientists in the fields of nanochemistry and nanomaterials, materials chemistry, material science, electrochemistry, analytical chemistry, physical chemistry, and biochemistry.
This book provides a theoretical background to X-ray photoelectron spectroscopy (XPS) and a practical guide to the analysis of the XPS spectra using the RxpsG software, a powerful tool for XPS analysis. Although there are several publications and books illustrating the theory behind XPS and the origin of the spectral feature, this book provides an additional practical introduction to the use of RxpsG. It illustrates how to use the RxpsG software to perform specific key operations, with figures and examples which readers can reproduce themselves. The book contains a list of theoretical sections explaining the appearance of the various spectral features (core‐lines, Auger components, valence bands, loss features, etc.). They are accompanied by practical steps, so readers can learn how to analyze specific spectral features using the various functions of the RxpsG software. This book is a useful guide for researchers in physics, chemistry, and material science who are looking to begin using XPS, in addition to experienced researchers who want to learn how to use RxpsG. In the digital format, the spectral data and step-by-step indications are provided to reproduce the examples given in the textbook. RxpsG is a free software for the spectral analysis. Readers can find the installation information and download the package from https://github.com/GSperanza/ website. RxpsG was developed mainly by Giorgio Speranza with the help of his colleague dr. Roberto Canteri working at Fondazione Bruno Kessler. Key Features: Simplifies the use of RxpsG, how it works, and its applications. Demonstrates RxpsG using a reproduction of the graphical interface of RxpsG, showing the steps needed to perform a specific task and the effect on the XPS spectra. Accessible to readers without any prior experience using the RxpsG software. Giorgio Speranza is Senior Researcher at Fondazione Bruno Kessler – Trento Italy, Associate Member of the Italian National Council of Research, and Associate Member of the Department of Industrial Engineering at the University of Trento, Italy.
Following in the lineage of Adsorption by Carbons (Bottani & Tascon, 2008), this work explores current research within contemporary novel carbon adsorbents. Both basic and applied aspects are discussed for this important class of materials. The first section of the book introduces physical adsorption and carbonaceous materials, and is followed by a section concerning the fundamentals of adsorption by carbons. This leads to development of a series of theoretical concepts that serve as an introduction to the following section in which adsorption is mainly envisaged as a tool to characterize the porous texture and surface chemistry of carbons. Particular attention is paid to novel nanocarbons, and the electrochemistry of adsorption by carbons is also addressed. Finally, several important technological applications of gas and liquid adsorption by carbons in areas such as environmental protection and energy storage constitute the last section of the book. Encompasses fundamental science of adsorption by carbons, in one location, supporting current R&D without extensive literature review Describes adsorption as it is currently applied to major novel types of carbon materials, including carbon gels, carbide-derived carbons, zeolite-templated carbvons, hydrothermal carbons, carbon nanohorns and graphene Specific discussion of fuel storage, environmental remediation and biomedical applications, of contemporary interest to many surface chemists and applications-focused researchers
There has been tremendous development in the science of carbon in past years. First came the development of the chemical vapor deposition of diamond, followed by the discovery of a new class of molecules - the fullerenes. Carbon nanotubes were discovered and techniques were developed to deposit new phases of amorphous carbon containing mainly sp3 bonding. This book brings together scientists and engineers from all areas of carbon research, both sp2 and sp3 bonded, from the fully amorphous to nanostructured carbon, to the highly ordered nanotubes. It covers a range of subjects including the synthesis and properties of nanotubes, as well as diamond-like carbon deposition and properties. Applications range from nanotubes for hydrogen storage, to electrochemical double-layer capacitors (supercapacitors), field emission displays, hard coatings, and carbon coatings for magnetic storage technology. The book deals with the growth, characterization, properties and applications of nanotubes and field emission from all varieties of carbon, amorphous and diamond-like carbon- growth, properties and applications. It also contains papers on diamond, silicon carbide, carbon nitride and beryllium films.