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This book describes recent advances in the application of chaos theory to classical scattering and nonequilibrium statistical mechanics generally, and to transport by deterministic diffusion in particular. The author presents the basic tools of dynamical systems theory, such as dynamical instability, topological analysis, periodic-orbit methods, Liouvillian dynamics, dynamical randomness and large-deviation formalism. These tools are applied to chaotic scattering and to transport in systems near equilibrium and maintained out of equilibrium. This book will be bought by researchers interested in chaos, dynamical systems, chaotic scattering, and statistical mechanics in theoretical, computational and mathematical physics and also in theoretical chemistry.
Introduction to applications and techniques in non-equilibrium statistical mechanics of chaotic dynamics.
A valuable introduction for newcomers as well as an important reference and source of inspiration for established researchers, this book provides an up-to-date summary of central topics in the field of nonequilibrium statistical mechanics and dynamical systems theory.Understanding macroscopic properties of matter starting from microscopic chaos in the equations of motion of single atoms or molecules is a key problem in nonequilibrium statistical mechanics. Of particular interest both for theory and applications are transport processes such as diffusion, reaction, conduction and viscosity.Recent advances towards a deterministic theory of nonequilibrium statistical physics are summarized: Both Hamiltonian dynamical systems under nonequilibrium boundary conditions and non-Hamiltonian modelings of nonequilibrium steady states by using thermal reservoirs are considered. The surprising new results include transport coefficients that are fractal functions of control parameters, fundamental relations between transport coefficients and chaos quantities, and an understanding of nonequilibrium entropy production in terms of fractal measures and attractors.The theory is particularly useful for the description of many-particle systems with properties in-between conventional thermodynamics and nonlinear science, as they are frequently encountered on nanoscales.
Describes the chaos apparent in simple mechanical systems with the goal of elucidating the connections between classical and quantum mechanics. It develops the relevant ideas of the last two decades via geometric intuition rather than algebraic manipulation. The historical and cultural background against which these scientific developments have occurred is depicted, and realistic examples are discussed in detail. This book enables entry-level graduate students to tackle fresh problems in this rich field.
This book provides a coherent introduction to the manifestations of chaos in atoms and molecules.
resonances. Nonlinear resonances cause divergences in conventional perturbation expansions. This occurs because nonlinear resonances cause a topological change locally in the structure of the phase space and simple perturbation theory is not adequate to deal with such topological changes. In Sect. (2.3), we introduce the concept of integrability. A sys tem is integrable if it has as many global constants of the motion as degrees of freedom. The connection between global symmetries and global constants of motion was first proven for dynamical systems by Noether [Noether 1918]. We will give a simple derivation of Noether's theorem in Sect. (2.3). As we shall see in more detail in Chapter 5, are whole classes of systems which are now known to be inte there grable due to methods developed for soliton physics. In Sect. (2.3), we illustrate these methods for the simple three-body Toda lattice. It is usually impossible to tell if a system is integrable or not just by looking at the equations of motion. The Poincare surface of section provides a very useful numerical tool for testing for integrability and will be used throughout the remainder of this book. We will illustrate the use of the Poincare surface of section for classic model of Henon and Heiles [Henon and Heiles 1964].
A clear introduction to chaotic phenomena for undergraduate students in science, engineering, and mathematics.
Groundbreaking monograph by Nobel Prize winner for researchers and graduate students covers Liouville equation, anharmonic solids, Brownian motion, weakly coupled gases, scattering theory and short-range forces, general kinetic equations, more. 1962 edition.
This book provides a comprehensive and self-contained overview of recent progress in nonequilibrium statistical mechanics, in particular, the discovery of fluctuation relations and other time-reversal symmetry relations. The significance of these advances is that nonequilibrium statistical physics is no longer restricted to the linear regimes close to equilibrium, but extends to fully nonlinear regimes. These important new results have inspired the development of a unifying framework for describing both the microscopic dynamics of collections of particles, and the macroscopic hydrodynamics and thermodynamics of matter itself. The book discusses the significance of this theoretical framework in relation to a broad range of nonequilibrium processes, from the nanoscale to the macroscale, and is essential reading for researchers and graduate students in statistical physics, theoretical chemistry and biological physics.
Based on courses given at the universities of Texas and California, this book treats an active field of research that touches upon the foundations of physics and chemistry. It presents, in as simple a manner as possible, the basic mechanisms that determine the dynamical evolution of both classical and quantum systems in sufficient generality to include quantum phenomena. The book begins with a discussion of Noether's theorem, integrability, KAM theory, and a definition of chaotic behavior; continues with a detailed discussion of area-preserving maps, integrable quantum systems, spectral properties, path integrals, and periodically driven systems; and concludes by showing how to apply the ideas to stochastic systems. The presentation is complete and self-contained; appendices provide much of the needed mathematical background, and there are extensive references to the current literature; while problems at the ends of chapters help students clarify their understanding. This new edition has an updated presentation throughout, and a new chapter on open quantum systems.