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This book addresses electrocatalysis based on chalcogenides, particularly in the nanoscale domain. Special attention is paid to the hydrogen evolution reaction (HER) and the oxygen reduction reaction (ORR). The book provides an introduction to materials synthesis; the basic principles of electrocatalysis; related precious metal versus non-precious metal catalytic center chalcogenides as well as supports; and the role of such supports in stabilizing the catalytic centers. In short: pursuing a bottom-up approach, it covers the properties of this class of electrocatalysts and examines their applications in low-temperature fuel systems such as microfluidic fuel cells for portable devices. Accordingly, it is ideally suited for all professionals and researchers interested in electrochemistry, renewable energy and electrocatalysis, and non-precious metal centers for chemical energy conversion.
Emerging Materials for Energy Conversion and Storage presents the state-of-art of emerging materials for energy conversion technologies (solar cells and fuel cells) and energy storage technologies (batteries, supercapacitors and hydrogen storage). The book is organized into five primary sections, each with three chapters authored by worldwide experts in the fields of materials science, physics, chemistry and engineering. It covers the fundamentals, functionalities, challenges and prospects of different classes of emerging materials, such as wide bandgap semiconductors, oxides, carbon-based nanostructures, advanced ceramics, chalcogenide nanostructures, and flexible organic electronics nanomaterials. The book is an important reference for students and researchers (from academics, but also industry) interested in understanding the properties of emerging materials. - Explores the fundamentals, challenges and prospects for the application of emerging materials in the development of energy conversion and storage devices - Presents a discussion of solar cell and photovoltaic, fuel cell, battery electrode, supercapacitor and hydrogen storage applications - Includes notable examples of energy devices based on emerging materials to illustrate recent advances in this field
The author provides a unified account of the electrochemical material science of metal chalcogenide (MCh) compounds and alloys with regard to their synthesis, processing and applications. Starting with the chemical fundamentals of the chalcogens and their major compounds, the initial part of the book includes a systematic description of the MCh solids on the basis of the Periodic Table in terms of their structures and key properties. This is followed by a general discussion on the electrochemistry of chalcogen species, and the principles underlying the electrochemical formation of inorganic compounds/alloys. The core of the book offers an insight into available experimental results and inferences regarding the electrochemical preparation and microstructural control of conventional and novel MCh structures. It also aims to survey their photoelectrochemistry, both from a material-oriented point of view and as connected to specific processes such as photocatalysis and solar energy conversion. Finally, the book illustrates the relevance of MCh materials to various applications of electrochemical interest such as (electro)catalysis in fuel cells, energy storage with intercalation electrodes, and ion sensing.
This first ever reference book that focuses on metal chalcogenide semiconductor nanostructures for renewable energy applications encapsulates the state-of-the-art in multidisciplinary research on the metal chalcogenide semiconductor nanostructures (nanocrystals, nanoparticles, nanorods, nanowires, nanobelts, nanoflowers, nanoribbons and more). The properties and synthesis of a class of nanomaterials is essential to renewable energy manufacturing and this book focuses on the synthesis of metal chalcogendie nanostructures, their growth mechanism, optical, electrical, and other important properties and their applications in different diverging fields like photovoltaics, hydrogen production, theromelectrics, lithium battery, energy storage, photocatalysis, sensors. An important reference source for students, scientists, engineers, researchers and industrialists working on nanomaterials-based energy aspects associated with chemistry, physics, materials science, electrical engineering, energy science and technology, and environmental science.
Sustainable Materials and Green Processing for Energy Conversion provides a concise reference on green processing and synthesis of materials required for the next generation of devices used in renewable energy conversion and storage. The book covers the processing of bio-organic materials, environmentally-friendly organic and inorganic sources of materials, synthetic green chemistry, bioresorbable and transient properties of functional materials, and the concept of sustainable material design. The book features chapters by worldwide experts and is an important reference for students, researchers, and engineers interested in gaining extensive knowledge concerning green processing of sustainable, green functional materials for next generation energy devices. Additionally, functional materials used in energy devices must also be able to degrade and decompose with minimum energy after being disposed of at their end-of-life. Environmental pollution is one of the global crises that endangers the life cycles of living things. There are multiple root causes of this pollution, including industrialization that demands a huge supply of raw materials for the production of products related to meeting the demands of the Internet-of-Things. As a result, improvement of material and product life cycles by incorporation of green, sustainable principles is essential to address this challenging issue. Offers a resourceful reference for readers interested in green processing of environmentally-friendly and sustainable materials for energy conversion and storage devices Focuses on designing of materials through green-processing concepts Highlights challenges and opportunities in green processing of renewable materials for energy devices
Chalcogenide-Based Nanomaterials as Photocatalysts deals with the different types of chalcogenide-based photocatalytic reactions, covering the fundamental concepts of photocatalytic reactions involving chalcogenides for a range of energy and environmental applications. Sections focus on nanostructure control, synthesis methods, activity enhancement strategies, environmental applications, and perspectives of chalcogenide-based nanomaterials. The book offers guidelines for designing new chalcogenide-based nanoscale photocatalysts at low cost and high efficiency for efficient utilization of solar energy in the areas of energy production and environment remediation. - Provides information on the development of novel chalcogenide-based nanomaterials - Outlines the fundamentals of chalcogenides-based photocatalysis - Includes techniques for heterogeneous catalysis based on chalcogenide-based nanomaterials
Chalcogenide: From 3D to 2D and Beyond reviews graphene-like 2D chalcogenide systems that include topological insulators, interesting thermoelectric structures, and structures that exhibit a host of spin phenomena that are unique to 2D and lower-dimensional geometries. The book describes state-of-the-art materials in growth and fabrication, magnetic, electronic and optical characterization, as well as the experimental and theoretical aspects of this family of materials. Bulk chalcogenides, chalcogenide films, their heterostructures and low-dimensional chalcogenide-based quantum structures are discussed. Particular attention is paid to findings that are relevant to the continued search for new physical phenomena and new functionalities. Finally, the book covers the enormous opportunities that have emerged as it has become possible to achieve lower-dimensional chalcogenide structures by epitaxial techniques. - Provides readers with foundational information on the materials growth, fabrication, magnetic, electronic and optical characterization of chalcogenide materials - Discusses not only bulk chalcogenides and chalcogenide thin films, but also two-dimensional chalcogenide materials systems - Reviews the most important applications in optoelectronics, photovoltaics and thermoelectrics
This first comprehensive description of the most important material properties and device aspects closes the gap between general books on solar cells and journal articles on chalcogenide-based photovoltaics. Written by two very renowned authors with years of practical experience in the field, the book covers II-VI and I-III-VI2 materials as well as energy conversion at heterojunctions. It also discusses the latest semiconductor heterojunction models and presents modern analysis concepts. Thin film technology is explained with an emphasis on current and future techniques for mass production, and the book closes with a compendium of failure analysis in photovoltaic thin film modules. With its overview of the semiconductor physics and technology needed, this practical book is ideal for students, researchers, and manufacturers, as well as for the growing number of engineers and researchers working in companies and institutes on chalcogenide photovoltaics.
An international group of leading scientists from the field has contributed to the 12th volume in this series, covering a range of different types of solar cells and including a critical comparison of the different techniques available for manufacturing the semiconductors needed. The result is an expert insight the central questions surrounding photovoltaic materials and systems, reflecting the latest developments in this hot and timely green topic.
The papers included in this issue of ECS Transactions were originally presented in the symposium ¿Electrochemistry of Novel Electrode Materials for Energy Conversion and Storage¿, held during the 211th meeting of The Electrochemical Society, in Chicago, IL, from May 6 to 11, 2007.