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Direct Liquid Fuel Cells is a comprehensive overview of the fundamentals and specificities of the use of methanol, ethanol, glycerol, formic acid and formate, dimethyl ether, borohydride, hydrazine and other promising liquid fuels in fuel cells. Each chapter covers a different liquid fuel-based fuel cell such as: Anode catalysts of direct methanol fuel cells (DMFCs), future system designs and future trends for direct ethanol fuel cells (DEFCs), development of catalysts for direct glycerol fuel cells (DGFCs), the mechanisms of the reactions taking place at the anode and cathode electrodes, and the reported anode catalysts for direct formic acid fuel cell (DFAFC) and direct formate fuel cell (DFFC), characteristics of direct dimethyl ether fuel cell (DDMEFC), including its electrochemical and operating systems and design, the developments in direct borohydride fuel cells, the development of catalysts for direct hydrazine fuel cells (DHFCs), and also the uncommonly used liquids that have a potential for fuel cell applications including 2-propanol, ethylene glycol, ascorbic acid and ascorbate studied in the literature as well as utilization of some blended fuels. In each part, the most recent literature is reviewed and the state of the art is presented. It also includes examples of practical problems with solutions and a summarized comparison of performance, advantages, and limitations of each type of fuel cell discussed. Direct Liquid Fuel Cells is not a typical textbook but rather designed as a reference book of which any level of students (undergraduate or graduate), instructors, field specialists, industry and general audience, who benefit from current and complete understanding of the many aspects involved in the development and operation of these types of fuel cells, could make use of any chapter when necessary. Presents information on different types of direct liquid fuel cells. Explores information under each section, for specific fuel-based fuel cells in more detail in terms of the materials used. Covers three main sections: direct alcohol, organic fuel-based and inorganic fuel-based fuel cells
This book presents a state-of-the-art review on recent advances in nanocatalysts and electrocatalysis in DOFCs.
Direct Alcohol Fuel Cells: Materials, Performance, Durability and Applications begins with an introductory overview of direct alcohol fuel cells (DAFC); it focuses on the main goals and challenges in the areas of materials development, performance, and commercialization. The preparation and the properties of the anodic catalysts used for the oxidation of methanol, higher alcohols, and alcohol tolerant cathodes are then described. The membranes used as proton conductors in DAFC are examined, as well as alkaline membranes, focusing on the electrical conductivity and alcohol permeability. The use of different kinds of carbon materials as catalyst supports, gas diffusion layers, and current collectors in DAFC is also discussed. State of the art of the modeling is used to estimate performance and durability. The closing chapter reviews the use of DAFC in portable equipment and mobile devices and features a detailed discussion on the mechanisms of component degradation which limits their durability. This book is written to facilitate the understanding of DAFC technology, applications, and future challenges. It is an excellent introduction for electrochemical and material engineers interested in small fuel cells as portable energy sources, scientists focused on materials science for energy production and storage, as well as policy-makers in the area of renewable energies.
Nanomaterials for Direct Alcohol Fuel Cells explains nanomaterials and nanocomposites as well as the characterization, manufacturing, and design of alcohol fuel cell applications. The advantages of direct alcohol fuel cells (DAFCs) are significant for reliable and long-lasting portable power sources used in devices such as mobile phones and computers. Even though substantial improvements have been made in DAFC systems over the last decade, more effort is needed to commercialize DAFCs by producing durable, low-cost, and smaller-sized devices. Nanomaterials have an important role to play in achieving this aim. The use of nanotechnology in DAFCs is vital due to their role in the synthesis of nanocatalysts within the manufacturing process. Lately, nanocatalysts containing carbon such as graphene, carbon nanotubes, and carbon nanocoils have also attracted much attention. When compared to traditional materials, carbon-based materials have unique advantages, such as high corrosion resistance, better electrical conductivity, and less catalyst poisoning. This book also covers different aspects of nanocomposites fabrication, including their preparation, design, and characterization techniques for their fuel cell applications. This book is an important reference source for materials scientists, engineers, energy scientists, and electrochemists who are seeking to improve their understanding of how nanomaterials are being used to enhance the efficiency and lower the cost of DAFCs. Shows how nanomaterials are being used for the design and manufacture of DAFCs Explores how nanotechnology is being used to enhance the synthesis and catalysis processes to create the next generation of fuel cells Assesses the major challenges of producing nanomaterial-based DAFCs on an industrial scale
Meeting the need for a text on solutions to conditions which have so far been a drawback for this important and trend-setting technology, this monograph places special emphasis on novel, alternative catalysts of low temperature fuel cells. Comprehensive in its coverage, the text discusses not only the electrochemical, mechanistic, and material scientific background, but also provides extensive chapters on the design and fabrication of electrocatalysts. A valuable resource aimed at multidisciplinary audiences in the fields of academia and industry.
Fuel cells are one of the most promising clean energy conversion devices that can solve the environmental and energy problems in our society. However, the high platinum loading of fuel cells - and thus their high cost - prevents their commercialization. Non- or low- platinum electrocatalysts are needed to lower the fuel cell cost. Electrocatalysis in Fuel Cells: A Non and Low Platinum Approach is a comprehensive book summarizing recent advances of electrocatalysis in oxygen reduction and alcohol oxidation, with a particular focus on non- and low-Pt electrocatalysts. All twenty four chapters were written by worldwide experts in their fields. The fundamentals and applications of novel electrocatalysts are discussed thoroughly in the book. The book is geared toward researchers in the field, postgraduate students and lecturers, and scientists and engineers at fuel cell and automotive companies. It can even be a reference book for those who are interested in this area.
Nanocatalysis is a topical area of research that has huge potential. It attempts to merge the advantages of heterogeneous and homogeneous catalysis. The collection of articles in this book treats the topics of specificity, activity, reusability, and stability of the catalyst and presents a compilation of articles that focuses on different aspects of these issues.
This book provides a review of the latest advances in anion exchange membrane fuel cells. Starting with an introduction to the field, it then examines the chemistry and catalysis involved in this energy technology. It also includes an introduction to the mathematical modelling of these fuel cells before discussing the system design and performance of real-world systems. Anion exchange membrane fuel cells are an emerging energy technology that has the potential to overcome many of the obstacles of proton exchange membrane fuel cells in terms of the cost, stability, and durability of materials. The book is an essential reference resource for professionals, researchers, and policymakers around the globe working in academia, industry, and government.
New and Future Developments in Catalysis is a package of seven books that compile the latest ideas concerning alternate and renewable energy sources and the role that catalysis plays in converting new renewable feedstock into biofuels and biochemicals. Both homogeneous and heterogeneous catalysts and catalytic processes will be discussed in a unified and comprehensive approach. There will be extensive cross-referencing within all volumes.Batteries and fuel cells are considered to be environmentally friendly devices for storage and production of electricity, and they are gaining considerable attention. The preparation of the feed for fuel cells (fuel) as well as the catalysts and the various conversion processes taking place in these devices are covered in this volume, together with the catalytic processes for hydrogen generation and storage. An economic analysis of the various processes is also part of this volume and enables an informed choice of the most suitable process. - Offers in-depth coverage of all catalytic topics of current interest and outlines future challenges and research areas - A clear and visual description of all parameters and conditions, enabling the reader to draw conclusions for a particular case - Outlines the catalytic processes applicable to energy generation and design of green processes
Alcohol fuel cells are very attractive as power sources for mobile and portable applications. As they convert the chemical energy of fuels into electricity, much recent research is directed at developing suitable and efficient catalysts for the process. The present book focuses on pertinent types of nanomaterial-based catalysts, membranes and supports.