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Catalyst Deactivation 1994 was an expansion of earlier, highly successful symposia. The objective of the symposium was to promote a scientific approach of the phenomenon of catalyst deactivation which will contribute to the development of catalysts which are less subject to structural transformations and more resistant to poisons and coke formation. These aspects are dealt with in 12 plenary lectures, 48 oral presentations and 35 poster papers, which were critically selected from an impressive response from some 30 countries. Both fundamental and applied aspects were covered. The deactivation of catalysts in important industrial processes like fluid bed catalytic cracking hydrotreatment, hydrodesulfurization, catalytic reforming, hydrodenitrogenation, steam reforming, hydrodemetallization, hydrocracking, Fischer-Tropsch synthesis, propane dehydrogenation, phthalic anhydride synthesis received considerable attention. Mechanisms of poisoning, sintering and coking were further investigated and modelled and new experimental techniques for the characterization and the quantification of deactivation were also introduced.
Catalyst Deactivation 1994 was an expansion of earlier, highly successful symposia. The objective of the symposium was to promote a scientific approach of the phenomenon of catalyst deactivation which will contribute to the development of catalysts which are less subject to structural transformations and more resistant to poisons and coke formation. These aspects are dealt with in 12 plenary lectures, 48 oral presentations and 35 poster papers, which were critically selected from an impressive response from some 30 countries. Both fundamental and applied aspects were covered. The deactivation of catalysts in important industrial processes like fluid bed catalytic cracking hydrotreatment, hydrodesulfurization, catalytic reforming, hydrodenitrogenation, steam reforming, hydrodemetallization, hydrocracking, Fischer-Tropsch synthesis, propane dehydrogenation, phthalic anhydride synthesis received considerable attention. Mechanisms of poisoning, sintering and coking were further investigated and modelled and new experimental techniques for the characterization and the quantification of deactivation were also introduced.--[Source inconnue].
Deactivation and Poisoning of Catalysts presents the most current research in the area of heterogeneous catalysis. It focuses on the chemically induced effects associated with bonded surface species that cause catalyst activity decline -- and in some cases a change in catalyst specificity. In addition, this volume examines poisoning of dispersed metal catalysts ... the thermodynamics of sulfur-metal and carbon-metal interactions ... model poisoning reactions on single crystals ... deactivation in petroleum refining and petrochemical processes ... coking of metal catalysts ... and more. The new approaches and solutions to catalyst deactivation and poisoning presented in this guide are invaluable to all heterogeneous catalysis specialists, including chemical and petroleum engineers, and surface, synthetic, physical, and industrial chemists. Book jacket.
Catalyst lifetime represents one of the most crucial economic aspects in industrial catalytic processes, due to costly shutdowns, catalyst replacements, and proper disposal of spent materials. Not surprisingly, there is considerable motivation to understand and treat catalyst deactivation, poisoning, and regeneration, which causes this research topic to continue to grow. The complexity of catalyst poisoning obviously increases along with the increasing use of biomass/waste-derived/residual feedstocks and with requirements for cleaner and novel sustainable processes. This book collects 15 research papers providing insights into several scientific and technical aspects of catalyst poisoning and deactivation, proposing more tolerant catalyst formulations, and exploring possible regeneration strategies.
Catalyst Deactivation 1991 was an expanded version of earlier, highly successful symposia. The symposium featured invited and solicited papers including 4 plenary lectures, 78 oral presentations and 23 poster papers. Most of the papers are contained in this volume. The eight main topics emphasised at this most recent symposium were: deactivation mechanisms/phenomena (carbon deposition, poisoning, and sintering), methods (modeling and techniques), and important catalysts (hydrotreating, oxides, and zeolites). All of these areas were well represented as attested by the substantial number of papers contained in these proceedings. Four review papers based on the plenary lectures provide state-of-the-art perspectives on new thrusts in deactivation research and development.
Written by a team of internationally recognized experts, this book addresses the most important types of catalytic reactions and catalysts as used in industrial practice. Both applied aspects and the essential scientific principles are described. The main topics can be summarized as follows: heterogeneous, homogeneous and biocatalysis, catalyst preparation and characterization, catalytic reaction engineering and kinetics, catalyst deactivation and industrial perspective.
Most catalysts used in the chemical and petrochemical indus tries are strongly affected by one or another form of deactivation, leading to poor performances and reduced life. The increasing num ber of scientific communications devoted to the subject in recent years, and culminating with an International Symposium held in Antwerp in October 1980, is a measure of the interest it arouses in both the industrial and academic communities. A stage has been reached whereby it was thought that a NATO Advanced Study Institute on "Catalyst Deactivation" might be fruit ful in establishing the state of the art and in stimulating a more systematic research on the phenomenon. Such a meeting was held ~n Lagos, Portugal, from 18 to 29 May 1981. The purpose of the Institute was to present and discuss in a didatic and systematic way the various processes that lead to cata lyst deactivation, namely coking, poisoning and solid state trans formations, and at the same time to promote the exchange of ideas and experiences among the participants, drawn from industry and uni versity. The lectures presented at the Institute are collected in this volume with the exception of Dr. L.L.Hegedus "Catalyst Poisoning", which has been previously published (Catalysis Reviews, Science md Engineering, 23, 377-476, 1981).