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The field of petrochemicals started some years ago with the simple addition reaction of water to propylene for the production of isopropyl alcohol. Currently, the petrochemical industry has become a multi-billion dollar enterprise which encompasses a wide field of chemical products. Almost all the basic organic reactions such as hydrogenation, alkylation, substitution, polymerization, etc. are utilized for the production of these chemicals. It may not, however, have been possible to establish this huge industry without the use of different catalysts. In other words, the great advancements in the catalytic area have supported the vast developments in the petrochemical field. In this book, we have adopted the idea of discussing the petrochemical industry from the point of view of reactants' activities and susceptibilities toward different catalysts. The book is thus classified according to the reaction type. This will eriable students and other users of the book to base their understanding of the petrochemical field on the fundamental principles learned in chemistry. How ever, the first chapter is aimed at establishing some basic facts on the petro chemical industry and its major uses. It discusses, without going into details, the raw materials used, the intermediates and the downstream products. The next eight chapters discuss in some detail the main reactions and the catalysts used for the production of chemicals and polymers from petroleum. The last chapter is devoted to a discussion of some of the practical techniques used in the catalytic field.
Petroleum refining and the petrochemical industry play an important role in the current world economy. They provide the platform to convert basic raw materials into many essential products, ranging from transportation fuels (such as gasoline, jet fuel, diesel, and gas oil) to basic and intermediate materials for petrochemical industries and many other valuable chemical products. Advanced Catalysis Processes in Petrochemicals and Petroleum Refining: Emerging Research and Opportunities is an essential comprehensive research publication that provides knowledge on refining processes that could be integrated by the petrochemical industry and discusses how to integrate refining products with petrochemical industries through the use of new technologies. Featuring a range of topics such as biofuel production, environmental sustainability, and biorefineries, this book is ideal for engineers, chemists, industry professionals, policymakers, researchers, academicians, and petrochemical companies.
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In Chemistry of Petrochemical Processes, readers find a handy and valuable source of information containing insights into petrochemical reactions and products, process technology, and polymer synthesis. The book reviews and describes the reactions and processes involved in transforming petroleum-based hydrocarbons into the chemicals that form the basis of the multi-billion dollar petrochemical industry. In addition, the book includes information on new process developments for the production of raw materials and intermediates for petrochemicals that have surfaced since the book's first edition. - Provides a quick understanding of the chemical reactions associated with oil and gas processing - Contains insights into petrochemical reactions and products, process technology, and polymer synthesis
The field of petrochemicals started some years ago with the simple addition reaction of water to propylene for the production of isopropyl alcohol. Currently, the petrochemical industry has become a multi-billion dollar enterprise which encompasses a wide field of chemical products. Almost all the basic organic reactions such as hydrogenation, alkylation, substitution, polymerization, etc. are utilized for the production of these chemicals. It may not, however, have been possible to establish this huge industry without the use of different catalysts. In other words, the great advancements in the catalytic area have supported the vast developments in the petrochemical field. In this book, we have adopted the idea of discussing the petrochemical industry from the point of view of reactants' activities and susceptibilities toward different catalysts. The book is thus classified according to the reaction type. This will eriable students and other users of the book to base their understanding of the petrochemical field on the fundamental principles learned in chemistry. How ever, the first chapter is aimed at establishing some basic facts on the petro chemical industry and its major uses. It discusses, without going into details, the raw materials used, the intermediates and the downstream products. The next eight chapters discuss in some detail the main reactions and the catalysts used for the production of chemicals and polymers from petroleum. The last chapter is devoted to a discussion of some of the practical techniques used in the catalytic field.
Catalysis plays an increasingly critical role in modern petroleum refining and basic petrochemical industries as market demands for and specifications of petroleum and petrochemical products are continuously changing. As we enter the 21st century, new challenges for catalysis science and technology are anticipated in almost every field. Particularly, better utilization of petroleum resources and demands for cleaner transportation fuels are major items. It was against this background that the 2nd International Conference on Catalysts in Petroleum Refining and Petrochemical Industries was organized. The conference was attended by around 300 specialists in the catalysis field from both academia and industry from over 30 countries. It provided a forum for the exchange of ideas between scientists and engineers from the region with their counterparts from industrialized countries.The papers from the conference, which were carefully selected from around 100 submissions, were refereed in terms of scientific and technical content and format in accordance with internationally accepted standards. They comprise a mix of reviews providing an overview of selected areas, original fundamental research results, and industrial experiences.
The Role of Catalysis for the Sustainable Production of Bio-fuels and Bio-chemicals describes the importance of catalysis for the sustainable production of biofuels and biochemicals, focused primarily on the state-of-the-art catalysts and catalytic processes expected to play a decisive role in the "green" production of fuels and chemicals from biomass. In addition, the book includes general elements regarding the entire chain of biomass production, conversion, environment, economy, and life-cycle assessment. Very few books are available on catalysis in production schemes using biomass or its primary conversion products, such as bio-oil and lignin. This book fills that gap with detailed discussions of: - Catalytic pyrolysis of lignocellulosic biomass - Hybrid biogasoline by co-processing in FCC units - Fischer-Tropsch synthesis to biofuels (biomass-to-liquid process) - Steam reforming of bio-oils to hydrogen With energy prices rapidly rising, environmental concerns growing, and regulatory apparatus evolving, this book is a resource with tutorial, research, and technological value for chemists, chemical engineers, policymakers, and students. - Includes catalytic reaction mechanism schemes and gives a clear understanding of catalytic processes - Includes flow diagrams of bench-, pilot- and industrial-scale catalytic processing units and demonstrates the various process technologies involved, enabling easy selection of the best process - Incorporates many tables, enabling easy comparison of data based on a critical review of the available literature
This book explores a balance between energy and material, applied to chemical reactors with catalysis, to achieve a given purpose. It includes the fundamentals of chemical reaction engineering and explains reactor design fundamentals. The book spans the full range-from the fundamentals of kinetics and heterogeneous catalysis via modern experimental and theoretical results of model studies-to their equivalent large-scale industrial production processes. It also includes significant developments, with recent research case studies and literature.
This book is part of a two-volume work that offers a unique blend of information on realistic evaluations of catalyst-based synthesis processes using green chemistry principles and the environmental sustainability applications of such processes for biomass conversion, refining, and petrochemical production. The volumes provide a comprehensive resource of state-of-the-art technologies and green chemistry methodologies from researchers, academics, and chemical and manufacturing industrial scientists. The work will be of interest to professors, researchers, and practitioners in clean energy catalysis, green chemistry, chemical engineering and manufacturing, and environmental sustainability. This volume focuses on catalyst synthesis and green chemistry applications for petrochemical and refining processes. While most books on the subject focus on catalyst use for conventional crude, fuel-oriented refineries, this book emphasizes recent transitions to petrochemical refineries with the goal of evaluating how green chemistry applications can produce clean energy through petrochemical industrial means. The majority of the chapters are contributed by industrial researchers and technicians and address various petrochemical processes, including hydrotreating, hydrocracking, flue gas treatment and isomerization catalysts.
Heterogeneous catalysis is among the major solutions for cost-effective and sustainable industrial application and processing. The design and development of highly efficient and stable heterogeneous catalysts represent an emergent frontier for overcoming energy and environmental challenges. Many industrial petrochemical and oil refining processes are faced with new challenges that can be solved using heterogeneous catalysts. This book covers the most recent progress and advances in the field of heterogeneous catalysts based on mesoporous composites with embedded halloysite nanotubes covered with ruthenium nanoparticles for exhaustive aromatics hydrogenation, generated in situ and supported on zeolites' transition metal sulfides for the hydrocracking of the pyrolysis fuel oil and n-alkanes isomerization. This book also includes investigations of novel rhodium systems supported on FeCrAl composite for the coupling of pre-reforming and partial oxidation to liquefied petroleum gas processing into syngas. We have collected works devoted to the palladium catalysts based on porous aromatic frameworks and alumina for the hydrogenation of unsaturated compounds (alkynes, alkenes and dienes) and for the selective removal of acetylene from ethane-ethylene fractions.