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The optical properties of carbon nanotubes and graphene make them potentially suitable for a variety of photonic applications. Carbon nanotubes and graphene for photonic applications explores the properties of these exciting materials and their use across a variety of applications.Part one introduces the fundamental optical properties of carbon nanotubes and graphene before exploring how carbon nanotubes and graphene are synthesised. A further chapter focusses on nonlinearity enhancement and novel preparation approaches for carbon nanotube and graphene photonic devices. Chapters in part two discuss carbon nanotubes and graphene for laser applications and highlight optical gain and lasing in carbon nanotubes, carbon nanotube and graphene-based fiber lasers, carbon-nanotube-based bulk solid-state lasers, electromagnetic nonlinearities in graphene, and carbon nanotube-based nonlinear photonic devices. Finally, part three focusses on carbon-based optoelectronics and includes chapters on carbon nanotube solar cells, a carbon nanotube-based optical platform for biomolecular detection, hybrid carbon nanotube-liquid crystal nanophotonic devices, and quantum light sources based on individual carbon nanotubes.Carbon nanotubes and graphene for photonic applications is a technical resource for materials scientists, electrical engineers working in the photonics and optoelectronics industry and academics and researchers interested in the field. - Covers the properties and fabrication of carbon nanotubes and graphene for photonic applications - Considers the uses of carbon nanotubes and graphene for laser applications - Explores numerous carbon-based light emitters and detectors
This chapter discusses the background knowledge and provides a literature review of carbon-nanotubes-based metamaterials and other nanophotonic devices we present in the chapter. The materials properties of carbon nanotubes are discussed, along with their possible application in producing metamaterials which display artificial optical properties. A detailed analysis of different types of metamaterials is presented, along with their theory and applications. The utilization of silicon nanopillars for producing photonic crystals and the enhanced reflection effects are discussed. Lastly, the theoretical background and designing of carbon nanotube forests-based Fresnel lenses are presented.
With their nano-scaled dimensions and extremely elevated optical nonlinearity, carbon nanostructures including single-walled carbon nanotubes and graphene have played a critical role in generating ultrafast optical pulses. The pulsation relies on passive mode-locking of the nanostructures, and has been enhanced by employing an evanescent field interaction scheme that guarantees the all-fiber high-power operation. Preparation schemes for pulsating devices have been evolving via the development of elegant processes such as optical deposition, electrospray, and aerosol deposition of carbon nanostructures, ensuring the dramatic increase of process efficiency. In this chapter, details of the technical achievements are addressed.
Carbon nanotubes have been explored in light-harvesting and photovoltaic devices because of their unique optoelectronic properties. This chapter provides a brief description of the optoelectronic properties of carbon nanotubes, particularly single-wall carbon nanotubes (SWCNTs), and their implication in various solar cell applications including donor–acceptor solar cells, polymer solar cells, and dye-sensitized solar cells, where carbon nanotubes are utilized as photoactive materials. Carbon-nanotube-based electrodes in photovoltaic devices are also introduced. Carbon-nanotube-based light-harvesting devices are reviewed in terms of fabrication and material processing as well as performance. Finally, advanced emerging methods and the future outlook for carbon-nanotube-based solar cells are discussed.
This chapter describes how the semiconducting-single-wall nanotube (SWNT) extraction affects their luminescence properties and how such properties can be exploited to fabricate optical sources emitting in near-infrared wavelengths ranging from 1 to 2μm. The main applications of carbon nanotube (CNT) lasers are aimed at optical interconnects and biophotonics. We review recent achievements in obtaining optical gain in thin films doped with CNTs. Techniques for determining optical gain in CNTs are considered with particular focus on the variable strip length (VSL) method and choices to integrate nanotubes in the optical waveguide are discussed.
This chapter provides an overview of methods used to synthesize single-walled carbon nanotubes (SWNTs) and graphene. Synthesis methods of commercially available SWNTs are reviewed first, followed by common in-house methods. Historically important approaches are discussed but the focus is on tailored synthesis by chemical vapor deposition (CVD). Primary routes for graphene synthesis are described next, in addition to background regarding the discovery of this two-dimensional material. Exfoliation of graphite into single-layer graphene is described, followed by synthesis routes involving reduction of graphene oxide and epitaxial growth from carbides. The chapter ends with an overview of CVD synthesis of graphene on metal substrates.
Single-walled carbon nanotubes (SWCNTs) have recently attracted tremendous interest as a nanomaterial for photonics and quantum photonics devices. Here we shall review recent work with a focus on quantum light properties such as blinking and spectral diffusion, and in particular, methods and techniques to suppress these detrimental effects with the goal of enhancing optical emission. Furthermore, we shall review recent work on the generation and detection of nonclassical light emissions from individual SWCNTs embedded in polymer cavities, and discuss the role of spatial exciton localization along the tube.
Because of their estimated ultra-high third-order nonlinearity, single-walled carbon nanotubes (CNTs) can be regarded as a potential new material for optical nonlinearity. The nonlinearity of CNTs is believed to originate from the inter-band transitions of the π-electrons, causing nonlinear polarization. In this respect, CNTs are similar to other organic optical materials that exhibit extremely high nonlinearity. CNT-based photonics devices offer several key advantages, including ultrafast response, robustness, tunability of wavelength, and compatibility to fibers. This chapter will describe the design and fabrication of CNT-based nonlinear photonic devices. CNTs with suitable diameters – and thus suitable operational wavelengths – are deposited or grown directly on different types of fibers or waveguides to ensure effective CNT–light interaction. Optical nonlinear effects including four-wave mixing (FWM), cross-phase modulation (XPM), and self-phase modulation (SPM) have been observed experimentally using fabricated CNT-based devices. Corresponding wavelength conversion and optical signal regeneration applications based on various nonlinear effects are discussed.
Environmental Applications of Carbon Nanomaterials-Based Devices Explore this insightful treatment of the function and fabrication of high-performance devices for environmental applications Environmental Applications of Carbon Nanomaterials-Based Devices delivers an overview of state-of-the-art technology in functionalized carbon nanomaterials-based devices for environmental applications. The book provides a powerful foundation, based in materials science, on functionalized carbon nanomaterials in general, and environmental science and device fabrication in particular. The book focuses on the chemical and physical methods of functionalization of carbon nanomaterials and the technology of device fabrication, including lab-on-a-chip approaches and applications such as wastewater purification and gas sensing. It provides readers with a thorough understanding of effective environmental remediation techniques performed with carbon nanomaterials-based devices. In addition to topics such as cross-linked graphene oxide membranes assembled with graphene oxide nanosheets, free-standing graphene oxide-chitin nanocrystal composite membranes for dye adsorption and oil/water separation, and in-situ grown covalent organic framework nanosheets on graphene for membrane-based dye/salt separation, readers will also benefit from the inclusion of: A thorough introduction to charge-gated ion transport through polyelectrolyte intercalated amine reduced graphene oxide membranes An exploration of hydrotalcite/graphene oxide hybrid nanosheets functionalized nanofiltration membrane for desalination A discussion of the incorporation of attapulgite nanorods into graphene oxide nanofiltration membranes for efficient dyes wastewater treatment An examination of attapulgite nanofibers and graphene oxide composite membranes for high-performance molecular separation Perfect for materials scientists, analytical chemists, and environmental chemists, Environmental Applications of Carbon Nanomaterials-Based Devices will also earn a place in the libraries of sensor developers seeking a one-stop resource for high-performance devices and sensors useful for environmental applications.
The fundamental electronic states and optical properties of single-walled carbon nanotubes are briefly explained in this chapter. Moreover, the novel optical properties of carbon nanotubes revealed by advanced laser spectroscopy (single-nanotube spectroscopy and time-resolved spectroscopy) are introduced. Due to the enhanced Coulomb interaction, the optically generated electron-hole pair forms a strongly bound ‘exciton’ state, analogous to the hydrogen-like state in the carbon nanotubes. The striking features of excitons in the carbon nanotube, such as singlet-dark states and triplet states, which dominate the optical properties, are described in this chapter.