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This report presents a cost analysis of Caprolactam production from butadiene, carbon monoxide, hydrogen, and ammonia. In the process, the product from the reaction of carbon monoxide with butadiene is first hydrocarbonylated. The following steps are amination and cyclization reactions, producing Caprolactam. This report was developed based essentially on the following reference(s): Keywords: BD, DuPont, DSM, BASF, Carbonylation, Esterification, Hydroformylation, Reductive Amination, Cyclization
This report presents a cost analysis of Caprolactam production from benzene The process examined involves the following steps: benzene is hydrogenated to cyclohexane; cyclohexane is oxidized to a mixture of cyclohexanol and cyclohexanone; cyclohexanol is dehydrogenated to cyclohexanone; cyclohexanone undergoes an oximation reaction with hydroxilamine; and the oxime produced is rearranged to Caprolactam. Ammonium sulfate is also generated as by-product. This report was developed based essentially on the following reference(s): (1) "Caprolactam", Ullmann's Encyclopedia of Industrial Chemistry, 7th edition (2) "Cyclohexane", Ullmann's Encyclopedia of Industrial Chemistry, 7th edition Keywords: Cyclohexanone, Cyclohexanol, Lactam Synthesis, Lactam Purification, Ammonium Sulfate Crystallization