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This report presents a cost analysis of Caprolactam production from benzene The process examined involves the following steps: benzene is hydrogenated to cyclohexane; cyclohexane is oxidized to a mixture of cyclohexanol and cyclohexanone; cyclohexanol is dehydrogenated to cyclohexanone; cyclohexanone undergoes an oximation reaction with hydroxilamine; and the oxime produced is rearranged to Caprolactam. Ammonium sulfate is also generated as by-product. This report was developed based essentially on the following reference(s): (1) "Caprolactam", Ullmann's Encyclopedia of Industrial Chemistry, 7th edition (2) "Cyclohexane", Ullmann's Encyclopedia of Industrial Chemistry, 7th edition Keywords: Cyclohexanone, Cyclohexanol, Lactam Synthesis, Lactam Purification, Ammonium Sulfate Crystallization
This report presents a cost analysis of Cyclohexane from benzene and hydrogen. The process examined is a liquid phase hydrogenation process. In this process, benzene is hydrogenated in a liquid-phase reactor in the presence of a nickel-based catalyst. The reactor's overhead is sent to a second reactor to convert the non-reacted benzene. This report was developed based essentially on the following reference(s): US Patent 5,668,293, issued to Institut Francais du Petrole in 1997 Keywords: Benzene Hexahydride, Cycloalkane, Liquid-Phase Reaction, Hydrogenation Reaction, IFP
This report presents a cost analysis of Linear Low Density Polyethylene (LLDPE) production from polymer grade (PG) ethylene and 1-octene using a solution process. The process under analysis is similar to NOVA Chemicals SCLAIRTECH process. This report was developed based essentially on the following reference(s): EP Patent 0527144, issued to DuPont in 1996 Keywords: Ethene, DuPont Canada, Cyclohexane, Stirred-Reactor, Swing Technology, Multi-Reactor
This report presents a cost analysis of Adipic Acid production from cyclohexane. The process examined is a two-stage oxidation process, similar to the Invista technology. In this process, cyclohexane is initially oxidized with air to produce KA oil (mixture of cyclohexanone and cyclohexanol). Subsequently, the KA oil is oxidized with nitric acid to produce Adipic Acid. A mixture of adipic, glutaric, and succinic acids is generated as by-product. GGKEY:YEUZ5NEBS2C This report was developed based essentially on the following reference(s): (1) US Patent 20040054235, issued to DuPont in 2004 (assigned to Invista in 2004) (2) "Adipic Acid," Kirk-Othmer Encyclopedia of Chemical Technology, 5th edition Keywords: Hexanedioic Acid, DuPont, Ketone/Alcohol Oil, Air Oxidation, Nitric Acid Oxidation, Boric Acid
Long-Term Durability of Polymeric Matrix Composites presents a comprehensive knowledge-set of matrix, fiber and interphase behavior under long-term aging conditions, theoretical modeling and experimental methods. This book covers long-term constituent behavior, predictive methodologies, experimental validation and design practice. Readers will also find a discussion of various applications, including aging air craft structures, aging civil infrastructure, in addition to engines and high temperature applications.
This book provides tabular and text data relating to normal and diseased tissue materials and materials used in medical devices. Comprehensive and practical for students, researchers, engineers, and practicing physicians who use implants, this book considers the materials aspects of both implantable materials and natural tissues and fluids. Examples of materials and topics covered include titanium, elastomers, degradable biomaterials, composites, scaffold materials for tissue engineering, dental implants, sterilization effects on material properties, metallic alloys, and much more. Each chapter author considers the intrinsic and interactive properties of biomaterials, as well as their appropriate applications and historical contexts. Now in an updated second edition, this book also contains two new chapters on the cornea and on vocal folds, as well as updated insights, data, and citations for several chapters.
This book contains eight chapters that discuss the manufacturing methods, surface treatment, composite interfaces, microstructure-property relationships with underlying fundamental physical and mechanical principles, and applications of carbon fibers and their composites. Recently, carbon-based materials have received much attention for their many potential applications. The carbon fibers are very strong, stiff, and lightweight, enabling the carbon materials to deliver improved performance in several applications such as aerospace, sports, automotive, wind energy, oil and gas, infrastructure, defense, and semiconductors. However, the use of carbon fibers in cost-sensitive, high-volume industrial applications is limited because of their relatively high costs. However, its production is expected to increase because of its widespread use in high-volume industrial applications; therefore, the methods used for manufacturing carbon fibers and carbon-fiber-reinforced composites and their structures and characteristics need to be investigated.
Process Equipment and Plant Design: Principles and Practices takes a holistic approach towards process design in the chemical engineering industry, dealing with the design of individual process equipment and its configuration as a complete functional system. Chapters cover typical heat and mass transfer systems and equipment included in a chemical engineering curriculum, such as heat exchangers, heat exchanger networks, evaporators, distillation, absorption, adsorption, reactors and more. The authors expand on additional topics such as industrial cooling systems, extraction, and topics on process utilities, piping and hydraulics, including instrumentation and safety basics that supplement the equipment design procedure and help to arrive at a complete plant design. The chapters are arranged in sections pertaining to heat and mass transfer processes, reacting systems, plant hydraulics and process vessels, plant auxiliaries, and engineered safety as well as a separate chapter showcasing examples of process design in complete plants. This comprehensive reference bridges the gap between industry and academia, while exploring best practices in design, including relevant theories in process design making this a valuable primer for fresh graduates and professionals working on design projects in the industry. - Serves as a consolidated resource for process and plant design, including process utilities and engineered safety - Bridges the gap between industry and academia by including practices in design and summarizing relevant theories - Presents design solutions as a complete functional system and not merely the design of major equipment - Provides design procedures as pseudo-code/flow-chart, along with practical considerations
Algae Based Polymers, Blends, and Composites: Chemistry, Biotechnology and Material Sciences offers considerable detail on the origin of algae, extraction of useful metabolites and major compounds from algal bio-mass, and the production and future prospects of sustainable polymers derived from algae, blends of algae, and algae based composites. Characterization methods and processing techniques for algae-based polymers and composites are discussed in detail, enabling researchers to apply the latest techniques to their own work. The conversion of bio-mass into high value chemicals, energy, and materials has ample financial and ecological importance, particularly in the era of declining petroleum reserves and global warming. Algae are an important source of biomass since they flourish rapidly and can be cultivated almost everywhere. At present the majority of naturally produced algal biomass is an unused resource and normally is left to decompose. Similarly, the use of this enormous underexploited biomass is mainly limited to food consumption and as bio-fertilizer. However, there is an opportunity here for materials scientists to explore its potential as a feedstock for the production of sustainable materials. - Provides detailed information on the extraction of useful compounds from algal biomass - Highlights the development of a range of polymers, blends, and composites - Includes coverage of characterization and processing techniques, enabling research scientists and engineers to apply the information to their own research and development - Discusses potential applications and future prospects of algae-based biopolymers, giving the latest insight into the future of these sustainable materials
This text provides a teachable and readable approach to transport phenomena (momentum, heat, and mass transport) by providing numerous examples and applications, which are particularly important to metallurgical, ceramic, and materials engineers. Because the authors feel that it is important for students and practicing engineers to visualize the physical situations, they have attempted to lead the reader through the development and solution of the relevant differential equations by applying the familiar principles of conservation to numerous situations and by including many worked examples in each chapter. The book is organized in a manner characteristic of other texts in transport phenomena. Section I deals with the properties and mechanics of fluid motion; Section II with thermal properties and heat transfer; and Section III with diffusion and mass transfer. The authors depart from tradition by building on a presumed understanding of the relationships between the structure and properties of matter, particularly in the chapters devoted to the transport properties (viscosity, thermal conductivity, and the diffusion coefficients). In addition, generous portions of the text, numerous examples, and many problems at the ends of the chapters apply transport phenomena to materials processing.