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We are proud to celebrate the 50th anniversary of the calixarenes. In 1944, Zinke and Ziegler proposed a cyclotetrameric structure for an oligomer extracted from the condensation product mixture obtained by reacting p-tert-butyl phenol with formaldehyde in the presence of sodium hydroxide. Fifty years on, calixarenes are the basis of many different areas of chemical research, with development occurring at an increasing pace over the past decade in particular. The present volume does not provide an overview of all these developments, but is rather a celebration of some of the highlights. This presentation of the intricate mosaic of diversity that characterizes calixarene chemistry will stimulate further developments in this fascinating field.
with contributions by numerous experts
Calixarene chemistry, at the turn of the millennium, is a field approaching true maturity. In many areas, applications are real and important, and the arsenal of structures based on calixarenes provides tools effective in numerous areas of supramolecular chemistry. In this book, chapters contributed by a broad spectrum of international authors provide a variety of perspectives upon the progress and future of calixarene chemistry. Issues covered in depth include: Calixarene synthesis, with all its subtleties and sophistication. Forces at play in the inclusion of neutral and charged molecules by calixarenes. Theoretical analyses of calixarene properties. Dynamics and thermodynamics of calixarenes and their complexes. Nanocomposite construction based on calixarene aggregates. Calixarenes on surfaces. Analytical applications of calixarenes. Catalysis by calixarenes and their complexes. Resource recovery and waste treatment with calixarenes. New directions in calixarene chemistry. Hetero- and homo-calixarenes. Bioactive calixarenes. Coordination chemistry of calixarenes. Calixarenes in the solid state.
This volume presents articles on the developing field of molecular interactions, molecular recognition, crystal engineering, and structural determination of complex molecular systems. The approaches described are interdisciplinary in nature, reflecting the concept of the ISMRI series of symposia.
Proceedings of the NATO Advanced Research Workshop, Miami, U.S.A., January 7-10, 1996