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This report presents a cost analysis of n-Butanol production from ethanol. In this process, ethanol is dimerized into n-Butanol via the Guerbet reaction. This report was developed based essentially on the following reference(s): (1) US Patent 20160326075A1, issued to Abengoa Bionergia Nuevas Tecnlogias SA in 2016 (2) US Patent 9018426, issued to Celanese International Corporation in 2015 (3) US Patent 8318990, issued to Mitsubishi Chemcal Corporation in 2012 Keywords: Dimerization, Mitsubishi Chemical Corporation, Dimeric Alcohol
This report presents a cost analysis of Propylene Oxide (PO) production from chemical grade (CG) propylene and ethylbenzene. The process examined is similar to LyondellBasell process. In this process, ethylbenzene is oxidized to produce ethylbenzene hydroperoxide, which reacts with propylene to produce Propylene Oxide. Styrene is generated as by-product in the process. This report was developed based essentially on the following reference(s): "Propylene Oxide", Ullmann's Encyclopedia of Industrial Chemistry, 7th edition Keywords: Propene, Ethylbenzol, Oxidation, Epoxidation, EBHP, Phenylethene, POSM
Like genomics, which defines genes in a genome irrespective of functionality, metabolomics profiles all metabolites in a biological sample irrespective of the chemical and physical properties of these molecules. Metabolomics can potentially define cellular processes by providing a measure of the ultimate phenotype of an organism, characterized by the collage of small molecules whose levels of accumulation is altered in response to genetic and environmentally induced changes in gene expression.
A multidisciplinary overview of bio-derived solvent applications, life cycle analysis, and strategies required for industrial commercialization This book provides the first and only comprehensive review of the state-of-the-science in bio-derived solvents. Drawing on their own pioneering work in the field, as well as an exhaustive survey of the world literature on the subject, the authors cover all the bases—from bio-derived solvent applications to life cycle analysis to strategies for industrial commercialization—for researchers and professional chemists working across a range of industries. In the increasingly critical area of sustainable chemistry, the search for new and better green solvents has become a top priority. Thanks to their renewability, biodegradability and low toxicity, as well as their potential to promote advantageous organic reactions, green solvents offer the promise of significantly reducing the pernicious effects of chemical processes on human health and the environment. Following an overview of the current solvents markets and the challenges and opportunities presented by bio-derived solvents, a series of dedicated chapters cover all significant classes of solvent arranged by origin and/or chemical structure. Throughout, real-world examples are used to help demonstrate the various advantages, drawbacks, and limitations of each class of solvent. Topics covered include: The commercial potential of various renewably sourced solvents, such as glycerol The various advantages and disadvantages of bio-derived versus petroleum-based solvents Renewably-sourced and waste-derived solvents in the design of eco-efficient processes Life cycle assessment and predictive methods for bio-based solvents Industrial and commercial viability of bio-based solvents now and in the years ahead Potential and limitations of methodologies involving bio-derived solvents New developments and emerging trends in the field and the shape of things to come Considering the vast potential for new and better products suggested by recent developments in this exciting field, Bio-Based Solvents will be a welcome resource among students and researchers in catalysis, organic synthesis, electrochemistry, and pharmaceuticals, as well as industrial chemists involved in manufacturing processes and formulation, and policy makers.
This report presents a cost analysis of bio-based Butanol production from corn. The process examined is a typical Acetone-Butanol-Ethanol (ABE) fermentation process. In this process, acetone and ethanol are generated as by-products. This report was developed based essentially on the following reference(s): Tao, L., et al., "Comparative techno-economic analysis and reviews of n-butanol production from corn grain and corn stover", Biofuels, Bioprod. Bioref. 8:342–361, 2014 Keywords: Butyl Alcohol, Biomass, Biofuel, Milling
This report presents a cost analysis of n-Butanol production from propylene and syngas. The process examined is similar to the technology jointly developed by Rhodia (former Rhône-Poulenc) and Ruhrchemie. This process relies on a water-soluble rhodium catalyst for the hydroformylation of propylene to form n-butyraldehyde and isobutyraldehyde. The isobutyraldehyde is separated as a by-product and the n-butyraldehyde is hydrogenated to form n-Butanol as the final product. This report was developed based essentially on the following reference(s): Keywords: Oxo Alcohol, Butyl Alcohol, n-Butanol, Rhodia, Rhône-Poulenc, Ruhrchemie
This report presents a cost analysis of bio-based Butanol production from raw sugar. The process examined is a typical Acetone-Butanol-Ethanol (ABE) fermentation process. In this process, acetone and ethanol are generated as by-products. This report was developed based essentially on the following reference(s): Keywords: Butyl Alcohol, Biomass, Biofuel
This report presents a cost analysis of n-Butanol production from propylene and syngas. The process examined is similar to the LP OXO technology jointly licensed by JM Davy and Dow, employing Selector 30 catalyst. In this process, the production ratio of n- to iso-butyraldehyde in the oxo reaction is about 30. The isobutyraldehyde is separated as a by-product and the n-butyraldehyde is hydrogenated to form n-Butanol as the final product. This report examines one-time costs associated with the construction of a United States-based plant and the continuing costs associated with the daily operation of such a plant. More specifically, it discusses: * Capital Investment, broken down by: - Total fixed capital required, divided in production unit (ISBL); infrastructure (OSBL) and contingency - Alternative perspective on the total fixed capital, divided in direct costs, indirect costs and contingency - Working capital and costs incurred during industrial plant commissioning and start-up * Production cost, broken down by: - Manufacturing variable costs (raw materials, utilities) - Manufacturing fixed costs (maintenance costs, operating charges, plant overhead, local taxes and insurance) - Depreciation and corporate overhead costs * Raw materials consumption, products generation and labor requirements * Process block flow diagram and description of industrial site installations (production unit and infrastructure) Keywords: Oxo Alcohol, Butyl Alcohol, n-Butanol, Johnson Matthey, Dow, LP Oxo, SELECTOR
This report presents a cost analysis of n-Butanol production from propylene and syngas. The process examined is similar to the LP OXO technology jointly developed by JM Davy and Union Carbide, employing Selector 10 catalyst. In this process, the production ratio of n- to iso-butyraldehyde in the oxo reaction is about 10. The isobutyraldehyde is separated as a by-product and the n-butyraldehyde is hydrogenated to form n-Butanol as the final product. This report was developed based essentially on the following reference(s): Keywords: Oxo Alcohol, Butyl Alcohol, n-Butanol, Johnson Matthey, Dow, LP Oxo, SELECTOR