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This report presents a cost analysis of 1,3-Butadiene production from a crude C4s stream. The process examined is similar to UOP KLP process. In this process, crude C4 stream is initially subjected to a selective hydrogenation step for conversion of acetylenes to their corresponding diene or olefin. Then, extractive distillation is used for Butadiene separation. This report was developed based essentially on the following reference(s): Keywords: Extractive Distillation, Crude C4s, C4 Acetylene, Dow
This report presents a cost analysis of 1,3-Butadiene production from a crude C4s stream using an extraction process. The process examined is similar to Nippon Zeon's crude C4 extractive distillation process. In this process, dimethyl-formamide is used as a solvent in order to extract 1,3-Butadiene from the crude C4 stream, also producing fuel byproduct. This report was developed based essentially on the following reference(s): Keywords: Extractive Distillation, Crude C4s, dimethyl-formamide, C4 Acetylene
This report presents a cost analysis of 1,3-Butadiene production from a crude C4s stream using an extraction process. The process examined is similar to BASF NMP process. In this process, raffinate-1 is generated as by-product. This report examines one-time costs associated with the construction of a United States-based plant and the continuing costs associated with the daily operation of such a plant. More specifically, it discusses: * Capital Investment, broken down by: - Total fixed capital required, divided in production unit (ISBL); infrastructure (OSBL) and contingency - Alternative perspective on the total fixed capital, divided in direct costs, indirect costs and contingency - Working capital and costs incurred during industrial plant commissioning and start-up * Production cost, broken down by: - Manufacturing variable costs (raw materials, utilities) - Manufacturing fixed costs (maintenance costs, operating charges, plant overhead, local taxes and insurance) - Depreciation and corporate overhead costs * Raw materials consumption, products generation and labor requirements * Process block flow diagram and description of industrial site installations (production unit and infrastructure) This report was developed based essentially on the following reference(s): "Butadiene", Ullmann's Encyclopedia of Industrial Chemistry, 7th edition Keywords: Extractive Distillation, Crude C4s, N-methylpyrrolidone, C4 Acetylene
This handbook provides a wide overview of the field, fundamental understanding of the synthetic methods and structure/property correlation, as well as studies related to applications in a wide range of subjects. The handbook also provides 1H and 13C NMR spectra, FTIR spectra, DSC and TGA thermograms to aid in research activities. Additional tables on key NMR and FTIR frequencies unique to benzoxazine, heat of polymerization, Tg, and char yield will greatly aid in the choice of proper benzoxazine for a specific application. - Provides thorough coverage of the chemistry and applications of benzoxazine resins with an evidence-based approach to enable chemists, engineers and material scientists to evaluate effectiveness - Features spectra, which allow researchers to compare results, avoid repetition and save time as well as tables on key NMR frequency, IR frequency, heat of polymerization, of many benzoxazine resins to aid them in selection of materials - Written by the foremost experts in the field
This report presents a cost analysis of 1,3-Butadiene (BD) production from n-butane using a dehydrogenation process. The process examined is similar to CB&I Lummus Catadiene process. In the process, n-butane undergoes a dehydrogenation reaction generating a C4s stream containing 1,3-Butadiene. High purity 1,3-Butadiene is obtained after conventional separation steps and an extractive distillation, using n-methylpyrrolidone (NMP) as solvent. Unreacted butane and butenes recovered are recycled to the dehydrogenation. This report was developed based essentially on the following reference(s): (1) "Butadiene," Ullmann's Encyclopedia of Industrial Chemistry, 7th edition (2) "Butadiene, General," Encyclopedia of Chemical Processing and Design Keywords: Houdry Catadiene, Sud-Chemie, Catalytic Dehydrogenation, BD, Fixed-Bed Reactor, BASF, NMP extraction
Molecular clusters, in the broad sense that the term is commonly understood, today comprise an enormous class of species extending into virtually every important area of chemistry: "naked" metal clusters, transition metal carbonyl clusters, hydrocarbon cages such as cubane (C H ) and dodecahedrane (C H ), 8 8 20 20 organometallic cluster complexes, enzymes containing Fe S or MoFe S 4 4 3 4 cores, high polymers based on carborane units, and, of course, the many kinds of polyhedral borane species. So large is the area spanned by these diverse classes that any attempt to deal with them comprehensively in one volume would, to say the least, be ambitious-and also premature. We are presently at a stage where intriguing relationships between the various cluster families are becoming apparent (particularly in terms of bonding descriptions), and despite large dif ferences in their chemistry an underlying unity is gradually developing in the field. For example, structural changes occurring in Fe S cores as electrons are 4 4 pumped in and out, in some measure resemble those observed in boranes and carboranes. The cleavage of alkynes via incorporation into carborane cages and subsequent cage rearrangement, a sequence familiar to boron chemists, is a thermodynamically favored process which may be related to the behavior of unsaturated hydrocarbons on metal surfaces; analogies of this sort have drawn attention from theorists and experimentalists.
This report presents a cost analysis of 1,3-Butadiene (BD) production from mixed butenes using an oxidative dehydrogenation process. The process examined is similar to TPC/UOP Oxo-D process. In this process, butenes are catalytically dehydrogenated to produce a crude butadiene stream which is further purified to the final Butadiene product. In the purification step, raffinate is obtained as by-product. This report examines one-time costs associated with the construction of a United States-based plant and the continuing costs associated with the daily operation of such a plant. More specifically, it discusses: * Capital Investment, broken down by: - Total fixed capital required, divided in production unit (ISBL); infrastructure (OSBL) and contingency - Alternative perspective on the total fixed capital, divided in direct costs, indirect costs and contingency - Working capital and costs incurred during industrial plant commissioning and start-up * Production cost, broken down by: - Manufacturing variable costs (raw materials, utilities) - Manufacturing fixed costs (maintenance costs, operating charges, plant overhead, local taxes and insurance) - Depreciation and corporate overhead costs * Raw materials consumption, products generation and labor requirements * Process block flow diagram and description of industrial site installations (production unit and infrastructure) This report was developed based essentially on the following reference(s): "Butadiene", Ullmann's Encyclopedia of Industrial Chemistry, 7th edition Keywords: Petrotex, Oxidative Dehydrogenation, BD, Fixed-Bed Reactor, BASF, NMP extraction
Features surveys of all areas of organic, inorganic, physical and biological photochemistry. The text serves as a source of scientific findings pertinent to chemistry and biochemistry. It addresses the state of developments in the field, employing reviews of active research, including recent innovations, techniques and applications.
How can a scientist or engineer synthesize and utilize polymers to solve our daily problems? This introductory text, aimed at the advanced undergraduate or graduate student, provides future scientists and engineers with the fundamental knowledge of polymer design and synthesis to achieve specific properties required in everyday applications. In the first five chapters, this book discusses the properties and characterization of polymers, since designing a polymer initially requires us to understand the effects of chemical structure on physical and chemical characteristics. Six further chapters discuss the principles of polymerization reactions including step, radical chain, ionic chain, chain copolymerization, coordination and ring opening. Finally, material is also included on how commonly known polymers are synthesized in a laboratory and a factory. This book is suitable for a one semester course in polymer chemistry and does not demand prior knowledge of polymer science.