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The continued and evolving significance of boron chemistry to the wider chemical community is demonstrated by the international and interdisciplinary nature of the research reported in this book. Contemporary Boron Chemistry encompasses inorganic and organic compounds as well as polymers, solid-state materials, medicinal aspects and theoretical studies. Covering many areas of chemistry with boron at its centre, topics include applications to polyolefin catalysis, medicine, materials and polymers; boron cluster chemistry, including carboranes and metal-containing clusters; organic and inorganic chemistry of species containing only 1 or 2 boron atoms; and theoretical studies of boron-containing compounds. New materials with novel optical and electronic properties are also discussed. Comprehensive and up to date, graduates and researchers in a wide range of fields, particularly those in organometallic and organic chemistry and materials science, will welcome this book.
Although the chemistry of boron is still relatively young, it is developing at a pace where even specific areas of research are difficult to compile into a monograph. Besides the boron hydrides, boron-nitrogen compounds are among the most fascinating derivatives of boron. Nitrogen compounds exist in a wide variety of molecular structures and display many interesting properties. The combination of nitrogen and boron, however, has some unusual features that are hard to match in any other combination of elements. This situation was first recognized by ALFRED STOCK and it seems proper to pay tribute to his outstanding work in the area of boron chemistry. One should realize that about forty years ago, STOCK and his coworkers had to develop completely new experimental techniq'\les and that no guidance for the interpreta tion of their rather unusual data had been advanced by theoretical chemists. In this monograph an attempt has been made to explore the general characteristics of structure and the principles involved in the preparation and reactions of boron-nitroge~ compounds. It was a somewhat difficult task to select that information which appears to be of the most interest to "inorganic and general chemistry" since the electronic relationship between a boron-nitrogen and a carbon-carbon grouping is reflected in the "organic" character of many of the reactions and compounds.
The first modernized overview of chemical valency and bonding theory, based on current computational technology.
Many important industrial chemical processes rely heavily on catalysis and so researchers are always on the lookout for alternative catalytic materials that may improve existing processes or lead to new ones. Families of alternative catalytic materials currently being investigated include the carbides, nitrides and phosphides as well as amorphous boron catalysts. The addition of carbon, nitrogen or phosphorous to transition metals and the creation of boron-transition metal alloys leads to catalytic materials that have interesting properties, with applications in a range of different reactions, including electrocatalysis. This book provides a comprehensive account of the preparation, characterisation and application of these catalytic materials. It is an important reference for researchers and industrialists working in heterogeneous catalysis and materials chemistry.
Boron Nitride Nanotubes in Nanomedicine compiles, for the first time in a single volume, all the information needed by researchers interested in this promising type of smart nanoparticles and their applications in biomedicine. Boron nitride nanotubes (BNNTs) represent an innovative and extremely intriguing class of nanomaterials. After introducing BNNTs and explaining their preparation and evaluation, the book shows how the physical, chemical, piezoelectric and biocompatibility properties of these nanotubes give rise to their potential uses in biomedicine. Evidence is offered (from both in vitro and in vivo investigations) for how BNNTs can be useful in biomedical and nanomedicine applications such as therapeutic applications, tissue regeneration, nanovectors for drug delivery, and intracellular nanotransducers. - Covers a range of promising biomedical BNNT applications - Provides great value not just to academics but also industry researchers in fields such as materials science, molecular biology, pharmacology, biomedical engineering, and biophysical sciences - Offers evidence for how BNNTs can be useful in biomedical and nanomedicine applications such as therapy, tissue regeneration, nanovectors for drug delivery, and intracellular nanotransducers - Incorporates, for the first time in a single volume, all the information needed by researchers interested in this promising type of smart nanoparticles and their applications in biomedicine
Boron science features in numerous fields including organic chemistry, organometallic chemistry and medicine. Boron is unique in all aspects of science and engineering and has made a significant impact in our daily lives through its use in fertilizers, germicides, fungicides, soaps, detergents, cancer drugs as well as many household glassware utensils, ceramics and cell phone windows. These volumes bring together an array of internationally renowned scientists to discuss the very latest developments in the application of boron in a broad range of disciplines. This multi-reference work describes the topic by appointing leading researchers to write on current developments in boron science, showcasing its importance to the four separate areas described in each volume: Organometallic Chemistry, Catalysis, Materials Chemistry and Medicine.Written to cover the full range of applications and innovations in boron science, this all-encompassing work offers us a one-stop reference compiled by world-leading researchers and practitioners of the subject, making it perfect for undergraduate and graduate students of chemistry, and researchers and practitioners interested in their professional development.
Introduction to Graphene: Chemical and Biochemical Applications addresses a broad range of graphene research, including the prehistory and background of graphene, synthetic approaches, characterization techniques, composites/derivatives, inorganic graphene analogues, and applications of graphene. The book's special emphasis on solution chemistry and graphene sets it apart from less practical titles in that its concepts are immediately implementable in the laboratories of chemists and biochemists. The book presents a variety of experimental approaches from the authors' research laboratories and others around the world for graphene preparation in the solution phase, especially under aqueous conditions or in animal serum—the most practical kind of graphene for chemists and biochemists. The book is ideally suited for a broad range of readers, including advanced undergraduates, graduate research students and professionals in state-of-the-art research labs who want to use graphene to develop novel applications. - Features reviews of the most recent advances in graphene research across chemistry and biochemistry - Emphasizes chemical and biological applications for specialists, aiding more multi-disciplinary research - Presents a variety of experimental approaches for graphene preparation in the solution phase, especially under aqueous conditions or even in animal serum
Das führende Referenzwerk für die bororganische Chemie Professor Mark Gandelman und seine Kollegen tauchen tief in die Theorie, Struktur, Analyse, Synthese und Reaktionen der bororganischen Chemie ein. Bororganische Verbindungen kommen als hocheffiziente Reagenzien bei vielen Reaktionen zum Einsatz, darunter bei Kreuzkupplungen und Radikal-Reaktionen. Die renommierten Autoren führen ihr Wissen der organischen und physikalischen Chemie in einem Werk zusammen. In der Regel stammen diese Informationen aus unterschiedlichen Quellen. Dieses Buch konzentriert sich auf vollständig biologisch abbaubare Reagenzien als Gegenpart zu umweltschädlichen Schwermetallkatalysatoren. The Chemistry of Organoboron Compounds bietet umfassende und ausführliche Informationen zu - dem Verhalten bororganischer Verbindungen, - dem Einsatz bororganischer Verbindungen in der organischen Synthese, - kommerziellen Anwendungen bororganischer Verbindungen. The Chemistry of Organoboron Compounds aus der gefeierten Reihe Patai's Chemistry of Functional Groups bietet alle Merkmale, die Leser von der Reihe gewohnt sind, auch ein ausführliches Stichwortverzeichnis.
V. I. MATKOVICH During the meeting of the International Symposium on Boron held in October, 1972 in Tbilisi, U.S.S.R., the idea was proposed to assemble a review of boron and refractory borides by the specialists present. The advantages of such a work were immediately apparent. Such diverse applications of borides as in protective armor, nuclear reactors, coat ings, reinforcement, etc. can hardly all be presented in sufficient detail by a single author. On the other hand it was also recognized that with so much specialization, some areas of interest may not be covered. Within the last decade or two a number of areas have been developed in which the use of refractory borides is growing and improvements are being actively explored. Thus, a number of borides have considerable potential as reinforcing material for plastics or light metals, though only boron fibers have been firmly established up to the present. Ap plication of flakes and films for two-dimensional reinforcement appears attractive, although the high cost of materials and development repre sents a considerable barrier. A number of borides have been used to manufacture lightweight protec tive armor. In this area relatively fast changes seem to be taking place as improvements in performance and weight are made. Boron carbide has found considerable use in this application and new developments exploit the light weight of beryllium borides.