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Excluding the biological polymers proteins, lipids and nucleic acids, modified tetrapyrroles are the biological molecules that have had the greatest impact on the evolution of life over the past 4 billion years. They are involved in a wide variety of fundamental processes that underpin central primary metabolism in all kingdoms of life, from photosynthesis to methanogenesis. Moreover, they bring colour into the world and it is for this reason that these compounds have been appropriately dubbed the ‘pigments of life’. To understand how and why these molecules have been so universally integrated into the life processes one has to appreciate the chemical properties of the tetrapyrrole scaffold and, where appropriate, the chemical characteristics of the centrally chelated metal ion. This book addresses why these molecules are employed in Nature, how they are made and what happens to them after they have finished their usefulness.
The study of the structure and function of tetrapyrrolic compounds has excited the interests of organic chemists, biochemists, botanists and biologists for more than a hundred years. Scientific analysis began with the first descriptions of naturally occurring porphyrins, and progress was made towards understanding the structure of chlorophyll. This was followed by the use of newly available isotopes of carbon and nitrogen to investigate the formation of porphyrins in biological systems. Further discoveries led to the elucidation of the atoms in protoporphyrin IX, made possible by the application of physical methods, such as NMR spectroscopy and recombinant DNA technology. The present volume discusses many more exciting and unexpected developments which have been made in the field over the last ten to fifteen years. While not all questions have yet been answered, the forum is set for a great scope of further research in the study of tetrapyrroles.• Of interest to biochemists, organic chemists and plant scientists• The book focusses on the exciting and unexpected developments in the field of tetrapyrolles over the last ten years• It paves the way for future research in this area
The Proceedings of the 14th International Congress on Photosynthesis is a record of the most recent advances and emerging themes in the discipline. This volume contains over 350 contributions from some 800 participants attending the meeting in Glasgow, UK in July 2007. These range from summary overview presentations from plenary speakers to expanded content of posters presented by students and their supervisors featuring the most recent achievements in photosynthesis research. In the words of Professor Eva-Mari Aro, President of the international Society of Photosynthesis Research 2004-7, “Having been taken for granted for centuries, research in photosynthesis has now become a matter of utmost importance for the future of planet Earth...Major initiatives are underway that will use research into natural and artificial photosynthesis for sustainable energy production....”. These volumes thus provide a glimpse of the future, from the molecule to the biosphere
Here is a comprehensive survey of all aspects of these fascinating bacteria, metabolically the most versatile organisms on Earth. It compiles 48 chapters written by leading experts, who highlight the huge progress made in studies of these bacteria since 1995.
The importance of metals in biology, the environment and medicine has become increasingly evident over the last twenty five years. The study of the multiple roles of metal ions in biological systems, the rapidly expanding interface between inorganic chemistry and biology constitutes the subject called Biological Inorganic Chemistry. The present text, written by a biochemist, with a long career experience in the field (particularly iron and copper) presents an introduction to this exciting and dynamic field. The book begins with introductory chapters, which together constitute an overview of the concepts, both chemical and biological, which are required to equip the reader for the detailed analysis which follows. Pathways of metal assimilation, storage and transport, as well as metal homeostasis are dealt with next. Thereafter, individual chapters discuss the roles of sodium and potassium, magnesium, calcium, zinc, iron, copper, nickel and cobalt, manganese, and finally molybdenum, vanadium, tungsten and chromium. The final three chapters provide a tantalising view of the roles of metals in brain function, biomineralization and a brief illustration of their importance in both medicine and the environment.Relaxed and agreeable writing style. The reader will not only fiind the book easy to read, the fascinating anecdotes and footnotes will give him pegs to hang important ideas on.Written by a biochemist. Will enable the reader to more readily grasp the biological and clinical relevance of the subject.Many colour illustrations. Enables easier visualization of molecular mechanismsWritten by a single author. Ensures homgeneity of style and effective cross referencing between chapters
Extensive and up-to-date review of key metabolic processes in bacteria and archaea and how metabolism is regulated under various conditions.
The first dedicated new work since 1991, this book reviews recent progress and current studies in the chemistry, metabolism and spectroscopy of chlorophylls, bacteriochlorophylls and their protein complexes. Also discussed is progress on the applications of chlorophylls as photosensitizers in photodynamic therapy of cancerous tumours, and as molecular probes in biochemistry, medicine, plant physiology, ecology and geochemistry. Each section offers an introductory overview followed by concise, focused and fully-referenced chapters written by experts.
“Photosynthesis: Plastid Biology, Energy Conversion and Carbon Assimilation” was conceived as a comprehensive treatment touching on most of the processes important for photosynthesis. Most of the chapters provide a broad coverage that, it is hoped, will be accessible to advanced undergraduates, graduate students, and researchers looking to broaden their knowledge of photosynthesis. For biologists, biochemists, and biophysicists, this volume will provide quick background understanding for the breadth of issues in photosynthesis that are important in research and instructional settings. This volume will be of interest to advanced undergraduates in plant biology, and plant biochemistry and to graduate students and instructors wanting a single reference volume on the latest understanding of the critical components of photosynthesis.
The Porphyrin Handbook, Volume 19: Applications of Phthalocyanines provides information pertinent to every aspect of the chemistry, synthesis, spectroscopy, and structure of phthalocyanines. This book examines the biology and medical implications of porphyrin systems. Organized into five chapters, this volume begins with an overview of the basic photobiology of phthalocyanines, their structure-activity relationships, mechanisms of action in a variety of biological systems, and their potential applications for various medical purposes. This text then examines the type of organization of the molecules in the solid state and the intensity of the intermolecular interactions. Other chapters consider the applications of phthalocyanines as decorative and functional materials, with emphasis on properties and structures of phthalocyanines with industrial relevance. This book discusses as well the enzyme-like catalytic functions of metal complexes derivatives and their practical applications as odor-removing systems and bacterial systems based on their effective catalytic activities. This book is a valuable resource for research scientists, engineers, and clinicians.