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This report presents a cost analysis of bio-based Acrylic Acid production from raw sugar using a fermentation process. The process examined is similar to the speculative process proposed by the Delft University of Technology. In this process, a biological agent is able to convert raw sugar (sucrose) to acrylic acid through an anaerobic metabolic pathway. The final product obtained in the process is Glacial Acrylic Acid. This report was developed based essentially on the following reference(s): Straathof, A. et al., "Feasibility of Acrylic Acid Production by Fermentation", Applied Microbiology Biotechnology, 2005, 67:727-734 Keywords: Bioacrylic Acid, Propenoic Acid, Anaerobic Fermentation, Unsaturated Carboxylic Acid, Green Acrylic Acid, Renewable Feedstock
This report presents a cost analysis of bio-based Acrylic Acid production from raw sugar using a fermentation process. The process examined is similar to Cargill process. In this process, raw sugar (sucrose) is diluted and sucrose is hydrolyzed into glucose and fructose (invert sugars). The invert sugars are then fermented to produce 3-hydroxypropionic acid (3-HPA), which is dehydrated to produce Acrylic Acid. The final product obtained is Glacial Acrylic Acid. This report was developed based essentially on the following reference(s): US Patent 20140364643, issued to Cargill in 2014 Keywords: Dextrose, Anaerobic Fermentation, Salt-Splitting, Tridecylamine, Propenoic Acid
This report presents a cost analysis of bio-based Acrylic Acid production from glucose syrup using a fermentation process In the process examined, glucose is fermented to produce 3-hydroxypropionic acid (3-HPA), which is dehydrated to produce Acrylic Acid. The process uses a 70 wt% glucose-water syrup as raw material and the final product obtained is Glacial Acrylic Acid. This report was developed based essentially on the following reference(s): (1) US Patent 9428778, issued to Cargill in 2016 (2) US Patent 7186856, issued to Cargill in 2007 Keywords: Dextrose, Fermentation, Salt-Splitting, 3-HP, Dehydration, Glacial Acrylic Acid
This report presents a cost analysis of bio-based Acrylic Acid production from glucose syrup using a direct fermentation process. The process examined is similar to the speculative process proposed by the Delft University of Technology. In this process, a biological agent is able to directly convert glucose to Acrylic Acid through an anaerobic metabolic pathway. The process uses a 70 wt% glucose-water syrup as raw material and the final product obtained is Glacial Acrylic Acid. This report was developed based essentially on the following reference(s): Straathof, A. et al., "Feasibility of Acrylic Acid Production by Fermentation", Applied Microbiology Biotechnology, 2005, 67:727-734 Keywords: Bioacrylic Acid, Anaerobic Fermentation, Dextrose, Propenoic Acid, Unsaturated Carboxylic Acid, Green Acrylic Acid, Renewable Feedstock
This report presents a cost analysis of 3-Hydroxypropionic Acid (3-HP) production from raw sugar using a fermentation process. The process examined is similar to Cargill process. In this process, raw sugar (sucrose) is diluted and sucrose is hydrolyzed into glucose and fructose (invert sugars). The invert sugars are then fermented to produce 3-HP. This report was developed based essentially on the following reference(s): (1) US Patent 7186856, issued to Cargill in 2007 (2) US Patent 8883464, issued to Opx Biotechnologies in 2014 Keywords: Dextrose, Anaerobic Fermentation, Salt-Splitting, Acrylic Acid, Tridecylamine
This report presents a cost analysis of Glacial Acrylic Acid production from crude acrylic acid. The process examined consists of a typical distillation/purification process. This report was developed based essentially on the following reference(s): "Acrylic Acid and Derivatives", Kirk-Othmer Encyclopedia of Chemical Technology, 5th edition Keywords: Propenoic Acid, Commercial Grade Acrylic Acid, Propylene Oxidation, Rohm and Haas, Dow, Flocculant Grade, GAA-FG
This report presents a cost analysis of Lactic Acid production from raw sugar using a low pH fermentation process. The process examined is similar to Cargill process. In this process, raw sugar (sucrose) is diluted and sucrose is hydrolyzed into glucose and fructose (invert sugars). The invert sugars are then fermented to produce lactic acid. The process generates an 88 wt% lactic acid solution in water as final product. This report was developed based essentially on the following reference(s): (1) US Patent 20060094093, issued to Cargill in 2006 (2) US Patent 7736514, issued to BASF in 2010 Keywords: Dextrose, 2-Hydroxypropanoic Acid, Anaerobic Fermentation, Cell Recycle, Acid Tolerant Bacteria
This report presents a cost analysis of Ester-Grade Acrylic Acid (EAA) production from propane The process examined is a novel process for propane oxidation. In this process, propane is fed to an oxydehydrogenation reactor in the presence of steam to form propylene. The propylene-containing gas passes through a two-stage vapor phase oxidation to generate an acrylic acid-containing gas, from which acrylic acid is recovered via absorption in water. The aqueous acrylic acid solution is purified via light solvent extraction to Ester-grade Acrylic Acid (EAA). This report was developed based essentially on the following reference(s): (1) "Acrylic Acid and Derivatives", Kirk-Othmer Encyclopedia of Chemical Technology, 5th edition (2) US Patent 6492548, issued to Union Carbide in 2002 Keywords: Propene, Air Oxidation, Propenoic Acid, Nippon Shokubai, Rohm & Haas, Dow
This report presents a cost analysis of bio-based Succinic Acid production from raw sugar using a fermentation process. The process examined is similar to Korea Advanced Institute of Science & Technology (KAIST) process. In this process, raw sugar (sucrose) is diluted and sucrose is hydrolyzed into glucose and fructose (invert sugars). The invert sugars are then fermented to produce Succinic Acid. This report examines one-time costs associated with the construction of a Germany-based plant and the continuing costs associated with the daily operation of such a plant. More specifically, it discusses: * Capital Investment, broken down by: - Total fixed capital required, divided in production unit (ISBL); infrastructure (OSBL) and contingency - Alternative perspective on the total fixed capital, divided in direct costs, indirect costs and contingency - Working capital and costs incurred during industrial plant commissioning and start-up * Production cost, broken down by: - Manufacturing variable costs (raw materials, utilities) - Manufacturing fixed costs (maintenance costs, operating charges, plant overhead, local taxes and insurance) - Depreciation and corporate overhead costs * Raw materials consumption, products generation and labor requirements * Process block flow diagram and description of industrial site installations (production unit and infrastructure) This report was developed based essentially on the following reference(s): WO Patent 2009082050, issued to Korea Advanced Institute of Science & Technology (KAIST) in 2009 Keywords: Butanedioic Acid, Dicarboxylic Acid
This report presents a cost analysis of Ester-Grade Acrylic Acid (EAA) production from acetylene and carbon monoxide. The process examined involves the addition of carbon monoxide to acetylene using a nickel carbonyl catalyst. This report was developed based essentially on the following reference(s): Keywords: BASF, Reppe Reaction, CO, Ni(CO)4