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This report presents a cost analysis of Benzene production from light oil using a hydrodealkylation process. The process examined is similar to CB&I Lummus Litol process. In this process, the light oil feedstock is a by-product from the cooking of coal. This report was developed based essentially on the following reference(s): (1) "DETOL®, LITOL®, and PYROTOL® Hydrodealkylation", Tech Sheet, CB&I Lummus Technology (2) "Benzene", Ullmann's Encyclopedia of Industrial Chemistry, 7th edition Keywords: Coke Oven Light Oil, COLO, Aromatics, BTX, Dealkylation, Houdry Division of Air Products, Bethlehem Steel
This report presents a cost analysis of Benzene production from reformate. The process examined is a typical sulfolane liquid-liquid extraction process. In this process, sulfolane is the solvent used in the extraction process. Toluene and mixed xylenes are generated as by-products. This report was developed based essentially on the following reference(s): "Benzene", Ullmann's Encyclopedia of Industrial Chemistry, 7th edition Keywords: Shell, UOP, Axens, Liquid-Liquid Solvent Extraction, BTX Distillation, Aromatics, Tetramethylene Sulfone, Tetrahydrothiophene-1,1-Dioxide, LLE
This report presents a cost analysis of Benzene production from toluene. The process examined is similar to CB&I Lummus Detol process for toluene hydrodealkylation. In this process, toluene is converted into benzene and mixed xylenes. A mixed xylenes stream is generated as a by-product of this process. This report was developed based essentially on the following reference(s): (1) "DETOL®, LITOL®, and PYROTOL® Hydrodealkylation", Tech Sheet, CB&I Lummus Technology (2) "Benzene", Ullmann's Encyclopedia of Industrial Chemistry, 7th edition Keywords: On-Purpose Benzene Production, Houdry, Aromatics, BTX, Catalytic Dealkylation
This report presents a cost analysis of Benzene production from toluene. The process examined is a typical selective toluene disproportionation process (STDP). In the STDP, toluene is converted into benzene and xylenes (mainly, p-xylene). Benzene is recovered from the reactor output via distillation and p-Xylene is separated as a by-product using a crystallization unit. This report was developed based essentially on the following reference(s): (1) US Patent 7230152, issued to UOP in 2007 (2) US Patent 4097543, issued to ExxonMobil in 1978 Keywords: Aromatics, BTX, ExxonMobil PxMax, UOP Px Plus, GTC GT-STDP
This report presents a cost analysis of Adipic Acid production from benzene using a two-stage oxidation process. The process examined is similar to Invista process. The Adipic Acid plant is integrated upstream with a plant for cyclohexane production from benzene and a plant for nitric acid production. A mixture of Adipic, glutaric, and succinic acids is generated as by-product. This report was developed based essentially on the following reference(s): US Patent 20040054235, issued to DuPont in 2004 (assigned to Invista in 2004) Keywords: Hexanedioic Acid, Boric Acid, Ketone/Alcohol Oil, KA Oil, Cyclohexanone, Cyclohexanol
This report presents a cost analysis of Benzene production from toluene and heavy aromatics. The process examined is a typical transalkylation process. In this process, mixed xylenes are generated as by-product. This report was developed based essentially on the following reference(s): (1) US Patent 9006125, issued to Exxonmobil in 2015 (2) US Patent 5942651, issued to Mobil Oil in 1999 Keywords: TA, BTX, Aromatics, UOP Tatoray, Toray, ExxonMobil TransPlus, Chinese Petroleum Corporation, CPC, Axens, KBR ATA, Advanced TransAlkylation, GTC GT-TransAlk
This report presents a cost analysis of Benzene and p-Xylene production from straight-run naphtha. The process examined is an integrated aromatics complex. The industrial complex includes the following units: a naphtha hydrotreater, a Continuous Catalyst Regeneration (CCR) Reformer, a sulfolane liquid-liquid extraction, a BTX distillation train, a toluene disproportionation process (TDP) and a Parex/Isomar system. This report was developed based essentially on the following reference(s): "Benzene", Ullmann's Encyclopedia of Industrial Chemistry, 7th edition Keywords: Aromatics Complex, BTX, UOP Tatoray, CCR Platformer, Parex, Isomar
This report presents a cost analysis of Benzene production from toluene. The process examined is similar to UOP hydrodealkylation (THDA) process. In this process, fuel is generated as by-product. This report was developed based essentially on the following reference(s): (1) US Reissued Patent RE38532, reissued to Chevron Phillips in 2004 (2) US Patent 4058452, issued to UOP in 1977 Keywords: On-Purpose Benzene Production, UOP, Aromatics, BTX, Thermal Dealkylation
This report presents a cost analysis of Benzene production from toluene. The process examined is a typical toluene disproportionation process (TDP). In this process, mixed xylenes are generated as by-product. This report was developed based essentially on the following reference(s): "Benzene", Ullmann's Encyclopedia of Industrial Chemistry, 7th edition Keywords: Aromatics, BTX, ExxonMobil MDTP-3, UOP Tatoray, Toray