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This is one of the first volumes to be published in the series of Chapman and Hall Chemistry Source books which provides carefully tailored information to workers in specialized areas of chemistry. The information contained in this book is derived from the Dictionary of Organometallic Compounds, published in November 1984. Organoruthenium and -osmium compounds constitute an important group of organometallics. They display a fascinating array of structural types, including a variety of cluster compounds, and they have uses as catalysts and reagents. Organoruthenium compounds in particular are widely used in catalytic processes. The varied properties of these compounds will ensure that this particular compendium will reach a wide readership. The databank on the properties of organometallic compounds, which is represented in its current form by the Dictionary of Organometallic Compounds and its subset publications such as this volume, will be kept continuously up-to-date. Supplements to the main Dictionary will appear annually and revised editions of this Sourcebook will be published from time to time as demands permits. G.R.Knox vii Introduction 1. Using the Sourcebook (2) Any compound with an established use, such as in catalysis, as a synthetic reagent or starting material. The Sourcebook is divided into element sections: (3) Other compounds of particular chemical, within each section the arrangement of entries is in structural, biological or historical interest, especially order of molecular formula according to the Hill those thought to exhibit unusual bonding characteris convention (i.e. C, then H, then other elements in tics.
In this comprehensive book, one of the leading experts, Shun-Ichi Murahashi, presents all the important facets of modern synthetic chemistry using Ruthenium, ranging from hydrogenation to metathesis. In 14 contributions, written by an international authorship, readers will find all the information they need about this fascinating and extraordinary chemistry. The result is a high quality information source and a indispensable reading for everyone working in organometallic chemistry. From the contents: Introduction (S.-I. Murahashi) Hydrogenation and Transfer Hydrogenation (M. Kitamura and R. Noyori) Oxidations (S.-I. Murahashi and N. Komiya) Carbon-Carbon Bond Formations via Ruthenacycle Intermediates (K. Itoh) Carbon-Carbon Bond Formation via pi-Allylruthenium Intermediates (T. Mitsudo) Olefin Metathesis (R. H. Grubbs) Cyclopropanation (H. Nishiyama) Nucleophilic Addition to Alkynes and Reactions via Vinylidene Intermediates (P. Dixneuf) Reactions via C-H Activation (N. Chatani) Lewis Acid Reactions (E. P. Kundig) Reactions with CO and CO2 (T. Mitsudo) Isomerization of Organic Substrates Catalyzed by Ruthenium Complexes (H. Suzuki) Radical Reactions (H. Nagashima) Bond Cleavage Reactions (S. Komiya)
The section devoted to iron in this volume reflects the tremendous progress in the area. Specifically cluster chemistry, ligand transformations and detailed structural results are more prominent in COMC II. The organic chemistry of ruthenium and osmium is an area which has burgeoned during the period since the publication of COMC. This is especially true for the cluster chemistry of these elements, which have provided most of the advances in this important field. Consequently, this volume will include an update (1981-1993) of the chemistry of mono- and bi-nuclear complexes of ruthenium and osmium, with a rather more extensive treatment of tri- and tetra-nuclear complexes. This is because many of the early results in ruthenium and osmium cluster chemistry described in COMC are now much better understood and can thus be placed in a more general context. In the case of complexes containing clusters with five or more metal atoms, the coverage is essentially complete, again because this chemistry has developed during the 1980s.