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Authored by a top-level team of both academic and industrial researchers in the field, this is an up-to-date review of mesoporous zeolites. The leading experts cover novel preparation methods that allow for a purpose-oriented fine-tuning of zeolite properties, as well as the related materials, discussing the specific characterization methods and the applications in close relation to each individual preparation approach. The result is a self-contained treatment of the different classes of mesoporous zeolites. With its academic insights and practical relevance this is a comprehensive handbook for researchers in the field and related areas, as well as for developers from the chemical industry.
The MRS Symposium Proceeding series is an internationally recognised reference suitable for researchers and practitioners.
Due to their unique porous properties, zeolites (also referred to as molecular sieves) are used in a variety of applications - major uses are in petrochemical cracking, ion-exchange (water softening and purification), and in the separation and removal of gases and solvents. Molecular Sieves: From Basic Research to Industrial Applications, Volume 158 A,B presents over 265 worldwide contributions on the latest developments in zeolitic research. Readers will find this book, which is divided into five sections: Synthesis, Characterization, Adsorption, Catalysis, and Novel applications, ideal for staying up to date on current research on porous materials.* Comprehensive overview of current research on porous materials* Contains experimental as well as theoretical input, reflecting the increasing overlap between theory and experiment* Contributions from the world's leading authorities
Widely used in adsorption, catalysis and ion exchange, the family of molecular sieves such as zeolites has been greatly extended and many advances have recently been achieved in the field of molecular sieves synthesis and related porous materials. Chemistry of Zeolites and Related Porous Materials focuses on the synthetic and structural chemistry of the major types of molecular sieves. It offers a systematic introduction to and an in-depth discussion of microporous, mesoporous, and macroporous materials and also includes metal-organic frameworks. Provides focused coverage of the key aspects of molecular sieves Features two frontier subjects: molecular engineering and host-guest advanced materials Comprehensively covers both theory and application with particular emphasis on industrial uses This book is essential reading for researches in the chemical and materials industries and research institutions. The book is also indispensable for researches and engineers in R&D (for catalysis) divisions of companies in petroleum refining and the petrochemical and fine chemical industries.
Zeolites and Zeolite-like Materials offers a comprehensive and up-to-date review of the important areas of zeolite synthesis, characterization, and applications. Its chapters are written in an educational, easy-to-understand format for a generation of young zeolite chemists, especially those who are just starting research on the topic and need a reference that not only reflects the current state of zeolite research, but also identifies gaps and opportunities. The book demonstrates various applications of zeolites in heterogeneous catalysis and biomass conversion and identifies the endless possibilities that exist for this class of materials, their structures, functions, and future applications. In addition, it demonstrates that zeolite-like materials should be regarded as a living body developing towards new modern applications, thereby responding to the needs of modern technology challenges, including biomass conversion, medicine, laser techniques, and nanomaterial design, etc. The book will be of interest not only to zeolite-focused researchers, but also to a broad scientific and non-scientific audience. - Provides a comprehensive review of the literature pertaining to zeolites and zeolite-like materials since 2000 - Covers the chemistry of novel zeolite-like materials such as Metal-Organic Frameworks (MOFs), Covalent Organic Frameworks (COFs), hierarchical zeolite materials, new mesoporous and composite zeolite-like micro/mesoporous materials - Presents essential information of the new zeolite-like structures, with a balanced coverage of the most important areas of the zeolite research (synthesis, characterization, adsorption, catalysis, new applications of zeolites and zeolite-like materials) - Contains chapters prepared by known specialists who are members of the International Zeolite Association
Fast pyrolysis and related catalytic pyrolysis are of increasing interest as pathways to advanced biofuels that closely mimic traditional petroleum products. Research has moved from empirical investigations to more fundamental studies of pyrolysis mechanisms. Theories on the chemical and physical pathways from plant polymers to pyrolysis products have proliferated as a result. This book brings together the latest developments in pyrolysis science and technology. It examines, reviews and challenges the unresolved and sometimes controversial questions about pyrolysis, helping advance the understanding of this important technology and stimulating discussion on the various competing theories of thermal deconstruction of plant polymers. Beginning with an introduction to the biomass-to-biofuels process via fast pyrolysis and catalytic pyrolysis, chapters address prominent questions such as whether free radicals or concerted reactions dominate deconstruction reactions. Finally, the book concludes with an economic analysis of fast pyrolysis versus catalytic pyrolysis. This book will be of interest to advanced students and researchers interested in the science behind renewable fuel technology, and particularly the thermochemical processing of biomass.
The Role of Catalysis for the Sustainable Production of Bio-fuels and Bio-chemicals describes the importance of catalysis for the sustainable production of biofuels and biochemicals, focused primarily on the state-of-the-art catalysts and catalytic processes expected to play a decisive role in the "green" production of fuels and chemicals from biomass. In addition, the book includes general elements regarding the entire chain of biomass production, conversion, environment, economy, and life-cycle assessment. Very few books are available on catalysis in production schemes using biomass or its primary conversion products, such as bio-oil and lignin. This book fills that gap with detailed discussions of: - Catalytic pyrolysis of lignocellulosic biomass - Hybrid biogasoline by co-processing in FCC units - Fischer-Tropsch synthesis to biofuels (biomass-to-liquid process) - Steam reforming of bio-oils to hydrogen With energy prices rapidly rising, environmental concerns growing, and regulatory apparatus evolving, this book is a resource with tutorial, research, and technological value for chemists, chemical engineers, policymakers, and students. - Includes catalytic reaction mechanism schemes and gives a clear understanding of catalytic processes - Includes flow diagrams of bench-, pilot- and industrial-scale catalytic processing units and demonstrates the various process technologies involved, enabling easy selection of the best process - Incorporates many tables, enabling easy comparison of data based on a critical review of the available literature
As the annual production of carbon Dioxide (CO2) reaches 30 billion tones, the growing issue of the greenhouse effect has triggered the development of technologies for CO2 sequestration, storage and use as a reactant. Collecting together the reports of the Congress at University of Rome (Campus Bio-medico) held 16th April 2012, CO2: A Valuable Source of Carbon presents and discusses promising technologies for the industrial exploitation of CO2. Divided into two parts, the current technology is evaluated and summarized before European and national projects are presented. The focus on CO2 recovery, particularly in value-added production, proposes applicable methods to develop sustainable practices and even to mitigate greenhouse gas emission from large-scale fossil fuels usage. Including current data and real-world examples, CO2: A valuable source of carbon provides students, engineers, researchers and industry professional with up-to-date material and potential areas for development and research.
This book provides a unified and insightful treatment of deterministic global optimization. It introduces theoretical and algorithmic advances that address the computation and characterization of global optima, determine valid lower and upper bounds on the global minima and maxima, and enclose all solutions of nonlinear constrained systems of equations. Among its special features, the book: Introduces the fundamentals of deterministic global optimization; Provides a thorough treatment of decomposition-based global optimization approaches for biconvex and bilinear problems; Covers global optimization methods for generalized geometric programming problems Presents in-depth global optimization algorithms for general twice continuously differentiable nonlinear problems; Provides a detailed treatment of global optimization methods for mixed-integer nonlinear problems; Develops global optimization approaches for the enclosure of all solutions of nonlinear constrained systems of equations; Includes many important applications from process design, synthesis, control, and operations, phase equilibrium, design under uncertainty, parameter estimation, azeotrope prediction, structure prediction in clusters and molecules, protein folding, and peptide docking. Audience: This book can be used as a textbook in graduate-level courses and as a desk reference for researchers in all branches of engineering and applied science, applied mathematics, industrial engineering, operations research, computer science, economics, computational chemistry and molecular biology.