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Electroactive polymers have been the object of increasing academic and industrial interest and in the past ten to fifteen years substantial progress has been achieved in the development and the characterization of this important new class of conducting materials. These materials are usually classified in two large groups, according to the mode of their electric transport. One group includes polymers having transport almost exclusively of the ionic type and they are often called 'polymer electrolytes' or, in a broader way, 'polymer ionics'. The other group includes polymeric materials where the transport mechanism is mainly electronic in nature and which are commonly termed 'conducting polymers'. Ionically conducting polymers or polymer ionics may be typically described as polar macromolecular solids in which one or more of a wide range of salts has been dissolved. The most classic example is the combina tion of poly(ethylene oxide), PEO, and lithium salts, LiX. These PEO-LiX polymer ionics were first described and proposed for applications just over ten years ago. The practical relevance of these new materials was im mediately recognized and in the course of a few years the field expanded tremendously with the involvement of many academic and industrial lab oratories. Following this diversified research activity, the ionic transport mechanism in polymer ionics was soon established and this has led to the development of new host polymers of various types, new salts and advanced polymer architectures which have enabled room temperature conductivity to be raised by several orders of magnitude.
This book covers the fundamental properties, modeling, and demonstration of Electroactive polymers in robotic applications. It particularly details artificial muscles and sensors. In addition, the book discusses the properties and uses in robotics applications of ionic polymer–metal composite actuators and dielectric elastomers.
Giving fundamental information on one of the most promising families of smart materials, electroactive polymers (EAP) this exciting new titles focuses on the several biomedical applications made possible by these types of materials and their related actuation technologies. Each chapter provides a description of the specific EAP material and device configuration used, material processing, device assembling and testing, along with a description of the biomedical application. Edited by well-respected academics in the field of electroactive polymers with contributions from renowned international experts, this is an excellent resource for industrial and academic research scientists, engineers, technicians and graduate students working with polymer actuators or in the fields of polymer science.
The book focuses on the development of high performance, high efficiency electroactive polymers (EAPs), and electromechanically active polymers by controlling molecular chemical structure and morphology for all applications. This book is ideal for academicians and researchers in polymer and materials science.
Covers the field of EAP with attention to all aspects and full infrastructure, including the available materials, analytical models, processing techniques, and characterization methods. This second edition covers advances in EAP in electric EAP, electroactive polymer gels, ionomeric polymer-metal composites, and carbon nanotube actuators.
Dielectric Elastomers as Electromechanical Transducers provides a comprehensive and updated insight into dielectric elastomers; one of the most promising classes of polymer-based smart materials and technologies. This technology can be used in a very broad range of applications, from robotics and automation to the biomedical field. The need for improved transducer performance has resulted in considerable efforts towards the development of devices relying on materials with intrinsic transduction properties. These materials, often termed as “smart or “intelligent , include improved piezoelectrics and magnetostrictive or shape-memory materials. Emerging electromechanical transduction technologies, based on so-called ElectroActive Polymers (EAP), have gained considerable attention. EAP offer the potential for performance exceeding other smart materials, while retaining the cost and versatility inherent to polymer materials. Within the EAP family, “dielectric elastomers , are of particular interest as they show good overall performance, simplicity of structure and robustness. Dielectric elastomer transducers are rapidly emerging as high-performance “pseudo-muscular actuators, useful for different kinds of tasks. Further, in addition to actuation, dielectric elastomers have also been shown to offer unique possibilities for improved generator and sensing devices. Dielectric elastomer transduction is enabling an enormous range of new applications that were precluded to any other EAP or smart-material technology until recently. This book provides a comprehensive and updated insight into dielectric elastomer transduction, covering all its fundamental aspects. The book deals with transduction principles, basic materials properties, design of efficient device architectures, material and device modelling, along with applications. Concise and comprehensive treatment for practitioners and academics Guides the reader through the latest developments in electroactive-polymer-based technology Designed for ease of use with sections on fundamentals, materials, devices, models and applications
From the authors' preface: "As we enter the era of intelligent materials and embark upon a new approach to material design, synthesis, and system integration, certain groups of materials will emerge as champions." Standing high among these champions are conductive electroactive polymers (CEPs), which appear destined to play a central ro
The explores the cutting-edge technology of polymer coatings. It discusses fundamentals, fabrication strategies, characterization techniques, and allied applications in fields such as corrosion, food, pharmaceutical, biomedical systems and electronics. It also discusses a few new innovative self-healing, antimicrobial and superhydrophobic polymer coatings. Current industrial applications and possible potential activities are also discussed.
Electroactive polymers are smart materials that can undergo size or shape structural deformations in the presence of an electrical field. These lightweight polymeric materials possess properties such as flexibility, cost-effectiveness, rapid response time, easy controllability (especially physical to electrical), and low power consumption. Electroactive Polymeric Materials examines the history, progress, synthesis, and characterization of electroactive polymers and then details their application and potential in fields including biomedical science, environmental remediation, renewable energy, robotics, sensors and textiles. Highlighting the flexibility, lightweight, cost-effective, rapid response time, easy controllability, and low power consumption characteristics of electroactive polymers, respected authors in the field explore their use in sensors, actuators, MEMS, biomedical apparatus, energy storage, packaging, textiles, and corrosion protection to provide readers with a powerhouse of a reference to use for their own endeavors. Features: Explores the most recent advances in all categories of ionic/electroactive polymer composite materials Includes basic science, addresses novel topics, and covers multifunctional applications in one resource Suitable for newcomers, academicians, scientists and R&D industrial experts working in polymer technologies .
'A comprehensive review of the current state of the theoretical development in this important area of potential application of conducting polymers, and is very timely...The editor-author is to be congratulated for his marathon efforts and the production of a significant contribution to the literature.' -TRIP This three-part series provides undergraduate and graduate students in electrochemistry and materials science with a broad understanding of electroactive polymers. In Part I, renowned scientists examine the fundamental principles underlying electrochemical behavior of electroactive polymer materials. Contributors focus on the fundamentals of charge percolation and conductivity behavior associated with the membrane properties of electroactive polymer films. Part I also includes coverage of the phenomenon of heterogeneous redox catalysis at electroactive polymer modified electrodes.