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This book contains papers presented at the NATO Advanced Research Workshop titled "Application of Gun and Rocket Propellants in Commercial Explosives". (SST.ARW975981) The workshop was organized in collaboration with codirector Dr. Bronislav V. Matseevich (KNIIM) and held in Krasnoarmeisk, Moscow Region, Russia, October 18-21, 1999. About 70 participants from 11 different countries took part in the meeting (Russia, Belarus, Czech Republic, Germany, Belgium, China, USA, Spain, Israel, Ukraine and the Netherlands). The workshop was principally the continuation of a previous NATO workshop on Conversion Concepts for Commercial Application and Disposal Technologies of Energetic Systems" held at Moscow, Russia, May 17-19, 1994 in the specific area of the reuse of gun and rocket propellants as ingredients in commercial explosives. Oldrich Machacek Vll ACKNOWLEDGMENTS I would like to thank Dr. B.V. Matseevich, Director of the Krasnoarmeisk Scientific Research Institute of Mechanization ("KNIIM") for his extensive involvement as co-director in organizing the Advanced Research Workshop in Krasnoarmeisk, Russia. Special thanks goes to Dr. V.P. Glinskij, Dr. LV. Vasiljeva and A.I. Fedonina from KNIIM and Dr. B. Vetlicky for invaluable assistance in preparation and the smooth operation ofthe workshop.
Whereas the current plane wave, homogeneous flow detonation physics is an excellent engineering tool for numerical predictions under given conditions, the multi-hot-spot-model is an additional tool for analyzing phenomena that cannot be explained by classical calculations. The real benefit comes from being able to understand, without any artificial assumptions, the whole phenomenology of detonations and explosions. By specifying pressure generating mechanisms, one is able to see that the current treatment of the detonics of energetic materials is only a very special - but powerful - case of explosion events and hazards. It becomes clear that physical explosions must be taken into account in any safety considerations. In these terms it is easy to understand why even liquid carbon dioxide and inert silo materials can explode. A unique collection of unexpected events, which might surprise even specialists, has resulted from the evaluation of the model.-
The U.S. military has a stockpile of approximately 400,000 tons of excess, obsolete, or unserviceable munitions. About 60,000 tons are added to the stockpile each year. Munitions include projectiles, bombs, rockets, landmines, and missiles. Open burning/open detonation (OB/OD) of these munitions has been a common disposal practice for decades, although it has decreased significantly since 2011. OB/OD is relatively quick, procedurally straightforward, and inexpensive. However, the downside of OB and OD is that they release contaminants from the operation directly into the environment. Over time, a number of technology alternatives to OB/OD have become available and more are in research and development. Alternative technologies generally involve some type of contained destruction of the energetic materials, including contained burning or contained detonation as well as contained methods that forego combustion or detonation. Alternatives for the Demilitarization of Conventional Munitions reviews the current conventional munitions demilitarization stockpile and analyzes existing and emerging disposal, treatment, and reuse technologies. This report identifies and evaluates any barriers to full-scale deployment of alternatives to OB/OD or non-closed loop incineration/combustion, and provides recommendations to overcome such barriers.
A very complete survey of different approaches adopted by Eastern and Western countries for the disposal of surplus ammunition. Incineration and other techniques for the disposal of high explosives, gun and rocket propellants are introduced and discussed in relation to environmental and safety requirements. Proposals for and examples of the re-use of military explosives in commercial applications are given. Topics discussed range from the conversion of energetic systems into chemical raw materials to the new development of energetic systems with special features for commercial use (such as producing artificial diamonds by detonation, self-propagating high-temperature synthesis, fire extinguishing, etc.).
Fully revised and updated to take account of the most recent developments in the field, this useful text explains today''s explosives from simple theory to practical use and considers future developments.'
The Program Manager for Assembled Chemical Weapons Assessment (PMACWA) of the Department of Defense (DOD) requested the National Research Council (NRC) to assess the engineering design studies (EDSs) developed by Parsons/Honeywell and General Atomics for a chemical demilitarization facility to completely dispose of the assembled chemical weapons at the Pueblo Chemical Depot in Pueblo, Colorado. To accomplish the task, the NRC formed the Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons: Phase II (ACW II Committee). This report presents the results of the committee's scientific and technical assessment, which will assist the Office of the Secretary of Defense in selecting the technology package for destroying the chemical munitions at Pueblo. The committee evaluated the engineering design packages proposed by the technology providers and the associated experimental studies that were performed to validate unproven unit operations. A significant part of the testing program involved expanding the technology base for the hydrolysis of energetic materials associated with assembled weapons. This process was a concern expressed by the Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons (ACW I Committee) in its original report in 1999 (NRC, 1999). The present study took place as the experimental studies were in progress. In some cases, tests for some of the supporting unit operations were not completed in time for the committee to incorporate results into its evaluation. In those cases, the committee identified and discussed potential problem areas in these operations. Based on its expertise and its aggressive data-gathering activities, the committee was able to conduct a comprehensive review of the test data that had been completed for the overall system design. This report summarizes the study.
This edited book contains state-of-the-art information associated with energetic material combustion. There are twelve topical areas, including: Reaction Kinetics of Energetic Materials (Solid, Liquid, and Gel Propellants); Recycling of Energetic Materials; Combustion Performance of Hybrid and Solid Rocket Motors; Ignition and Combustion of Energetic Materials; Energetic Material Defects and Rocket Engine Flowfields; Metal Combustion; Pyrolysis and Combustion Processes of New Ingredients and Applications; Theoretical Modeling and Numerical Simulation of Combustion Processes of Energetic Materials; Combustion Diagnostic Techniques; Propellant and Rocket Motor Stability; Commercial Applications of Energetic Materials (Airbags, Gas Generators, etc.); and Thermal Insulation and Ablation Processes.
Propellants and explosives and contain considerable chemical energy that can be converted into rapid expansion. In contrast to the simple burning of a fuel, explosives and propellants are self-contained and do not need an external supply of oxygen via air. Since their energy content inherently creates the risk of accidental triggering of the explosive reaction, the correct synthesis, formulation, and handling during production and use are of utmost importance for safety, necessitating specialist knowledge on energetic materials, their characteristics, handling and applications.