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Environmental Chemistry is a relatively young science. Interestin this subject, however, is growing very rapidly and, although no agreement has been reached as yet about the exact content and Iimits of this interdisciplinary discipline, there appears to be increasing interest in seeing environmental topics which are based on chemistry embodied in this subject. One of the first objectives ofEnvironmental Chemistry must be the study ofthe environment and of natural chemical processes which occur in the environment. A major purpose of this series on Environmental Chemistry, therefore, is to present a reasonably uniform view of various aspects of the chemistry of the environ ment and chemical reactions occurring in the environment. The industrial activities of man have given a new dimension to Environ mental Chemistry. Wehave now synthesized and described over five million chemical compounds and chemical industry produces about hundred and fifty million tons of synthetic chemieals annually. We ship billions of tons of oil per year and through mining operations and other geophysical modifications, large quantities of inorganic and organic materials are released from their natural deposits. Cities and metropolitan areas ofup to 15 million inhabitants produce large quantities ofwaste in relatively small and confined areas. Much of the chemical products and waste products of modern society are released into the environment either during production, storage, transport, use or ultimate disposal. These released materials participate in natural cycles and reactions and frequently Iead to interference and disturbance of natural systems.
Environmental Chemistry is a relatively young science. Interest in this subject, however, is growing very rapidly and, although no agreement has been reached as yet about the exact content and limits of this interdisciplinary discipline, there appears to be increasing interest in seeing environmental topics which are based on chemistry embodied in this subject. One of the first objectives of Environmental Chemistry must be the study of the environment and of natural chemical processes which occur in the environment. A major purpose of this series on Environmental Chemistry, therefore, is to present a reasonably uniform view of various aspects of the chemistry of the environment and chemical reactions occurring in the environment. The industrial activities of man have given a new dimension to Environmental Chemistry. We have now synthesized and described over five million chemical compounds and chemical industry produces about hundred and fifty million tons of synthetic chemicals annually. We ship billions of tons of oil per year and through mining operations and other geophysical modifications, large quantities of inorganic and organic materials are released from their natural deposits. Cities and metropolitan areas of up to 15 million inhabitants produce large quantities of waste in relatively small and confined areas. Much of the chemical products and waste products of modern society are released into the environment either during production, storage, transport, use or ultimate disposal. These released materials participate in natural cycles and reactions and frequently lead to interference and disturbance of natural systems.
Every day, large quantities of volatile organic compounds (VOCs) are emitted into the atmosphere from both anthropogenic and natural sources. The formation of gaseous and particulate secondary products caused by oxidation of VOCs is one of the largest unknowns in the quantitative prediction of the earth’s climate on a regional and global scale, and on the understanding of local air quality. To be able to model and control their impact, it is essential to understand the sources of VOCs, their distribution in the atmosphere and the chemical transformations which remove these compounds from the atmosphere. In recent years techniques for the analysis of organic compounds in the atmosphere have been developed to increase the spectrum of detectable compounds and their detection limits. New methods have been introduced to increase the time resolution of those measurements and to resolve more complex mixtures of organic compounds. Volatile Organic Compounds in the Atmosphere describes the current state of knowledge of the chemistry of VOCs as well as the methods and techniques to analyse gaseous and particulate organic compounds in the atmosphere. The aim is to provide an authoritative review to address the needs of both graduate students and active researchers in the field of atmospheric chemistry research.
This volume addresses a broad spectrum of the environmental issues surrounding organic bromine and iodine compounds. It covers their partition among the environmental compartments and the potential for their long-range dissemination. The important issue of their atmospheric chemistry is discussed in detail in the context of ozone depletion and global warming, and the significant difference between the reactions of methyl bromide and methyl iodide are underscored. The mammalian toxicity is discussed and the mechanisms of the degradation and transformation of organic bromine and iodine compounds addressed. There has been considerable interest in naturally occurring metabolites in the current debate on the fate and partition of methyl bromide that is an important fungicide and is produced in substantial quantities as a metabolite of marine algae. The possible natural occurrence of diphenyl ethers that are used as flame retardants have also been raised. A discussion is given on plausible mechanisms for the biosynthesis of representative organic bromine and organic iodine metabolites. Reaction pathways are illustrated throughout and comprehensive references are given.
Environmental Chemistry is a relatively young science. Interest in this subject, however, is growing very rapidly and, although no agreement has been reached as yet about the exact content and limits of this interdisciplinary subject, there appears to be increasing interest in seeing environmental topics which are based on chemistry embodied in this subject. One of the first objectives of Environ mental Chemistry must be the study of the environment and of natural chemical processes which occur in the environment. A major purpose of this series on Environmental Chemistry, therefore, is to present a reasonably uniform view of various aspects of the chemistry of the environment and chemical reactions occuring in the environment. The industrial activities of man have given a new dimension to Environ mental Chemistry. We have now synthesized and described over five million chemical compounds and chemical industry produces about one hundred and fifty million tons of synthetic chemicals annually. We ship billions of tons of oil per year and through mining operations and other geophysical modifications, large quantities of inorganic and organic materials are released from their natural deposits. Cities and metropolitan areas of up to 15 million inhabitants produce large quantities ofwaste in relatively small and confined areas. Much of the chemical products and was te products of modern society are released into the environment either during production, storage, transport, use or ultimate disposal. These released materials participate in natural cycles and reactions and frequently lead to interference and disturbance of natural systems.
The vast family of volatile organic compounds plays a central role in the chemistry of the Earth's atmosphere. Reactive Hydrocarbons in the Atmosphere provides comprehensive and up-to-date reviews covering all aspects of the behavior, sources, occurrence, and chemistry of these compounds. The book considers both biogenic and anthropogenic sources, plus their effects in the atmosphere at local, regional, and global scales. - Covers a major component of atmospheric chemistry and air pollution - Considers both natural background chemistry and pollution processes - Provides authoritative reviews for a wide range of audiences
Since the mid 1990s, legal action to eliminate persistent organic pollutants (POPs) has started resulting in a global Convention on POPs, the Stockholm Convention, and a regional Protocol under the Convention on Long-Range Transboundary Air Pollution (UN-ECE LRTAP Convention). POPs are characterized by long half-lives, persistence in the environment, they undergo long-range transport, accumulate in the environment and in biota, and they are toxic. The combination of these characteristics makes them a threat at the global level. This book makes the reader familiar with the goals of these two conventions, lays out characteristics of these compounds, presents results from case studies and addresses inventories, levels in humans and the environment as well as technologies to destroy them.
Reviews the evidence underpinning the Anthropocene as a geological epoch written by the Anthropocene Working Group investigating it. The book discusses ongoing changes to the Earth system within the context of deep geological time, allowing a comparison between the global transition taking place today with major transitions in Earth history.
Fatty alcohols are mainly used in the production of detergents and surfactants. This book provides new information regarding products containing fatty alcohol derivatives, the fate of these down-the-drain products in wastewater systems and the use of compound specific stable isotope methods.