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The first edition of this book (1958) described an analytical situation which had existed for a number of years for maintaining quality control on vulcanizates of natural rubber although the situation had recently been disturbed by the introduction of a range of synthetic rubbers which required identification and quantitative estimation. For the former purpose 'wet' chemistry, based on various imperfectly understood organic reactions, was pressed into service. Alongside this was the first introduction of instrumental analysis, using the infrared spectra of either the polymers or, more usually, their pyrolytic products to 'fingerprint' the material. The identification of a range of organic accelerators, antioxidants and their derivatives which had been intro duced during the 1920s and 30s was, in the first edition, dealt with by a combination of column chromatography and infrared spectroscopy or by paper chromatography. Quantitative procedures were, however, still classical in the tradition of gravimetric or volumetric assays with an initially weighed sample yielding, after chemical manipulation, a carefully precipitated, dried and weighed end product, or a solution of known composition whose weight or titre, as a percentage of the initial sample, quantified the function being determined. The second edition of this work (1968) consolidated the newer techni ques which had been introduced in the first without adding to them although, in other applications of analytical chemistry, instrumental analysis had already brought about a transformation in laboratory practice.
The Science and Technology of Rubber, Third Edition provides a broad survey of elastomers with special emphasis on materials with a rubber-like elasticity. As in the 2nd edition, the emphasis remains on a unified treatment of the material; exploring topics from the chemical aspects such as elastomer synthesis and curing, through recent theoretical developments and characterization of equilibrium and dynamic properties, to the final applications of rubber, including tire engineering and manufacturing. Many advances have been made in polymer and elastomers research over the past ten years since the 2nd edition was published. Updated material stresses the continuous relationship between the ongoing research in synthesis, physics, structure and mechanics of rubber technology and industrial applications. Special attention is paid to recent advances in rubber-like elasticity theory and new processing techniques for elastomers. This new edition is comprised of 20% new material, including a new chapter on environmental issues and tire recycling.
Rubber analysis plays a vital part in ensuring that manufactured products are fit for purpose. This comprehensive, application-based book with up-to-date referencing covers all important applications and subject area associated with the analysis of rubber compounds and rubber products. Includes characterization of rubber polymers, rubber fumes, identification of extractables and leachables, as well as reverse engineering on compounded products.
This review outlines each technique used in rubber analysis and then illustrates which methods are applied to determine which facts. This d104 is a good introduction to a very complex subject area and will enable the reader to understand the basic concepts of rubber analysis. Around 350 abstracts from the Rapra Polymer Library database accompany this review, to facilitate further reading. These include core original references together with abstracts from some of the latest papers on rubber analysis.
Fibres, Films, Plastics and Rubbers: A Handbook of Common Polymers focuses on polymeric materials. The book first discusses a list of sections on individual polymers. Topics include olefin and vinyl-type, carbohydrate-type, synthetic condensation-type, organo-silicon, and inorganic polymers, as well as proteins. The text also looks at list of sections on specific properties and related information. The book then discusses polyethylenes, polypropylene, and polytetrafluoroethylene. The text also examines polystyrene. Concerns include the structure, chemistry, physics, fabrication, serviceability, and utilization of these materials. The text also focuses on indene and coumarone/indene resins; polyvinyl acetate and alcohol; polyvinyl formal, acetal, and butyral; and polyacrylates and polymethacrylates. The book then examines the structure, chemistry, physics, fabrication, serviceability, and utilization of polyvinyl chloride, polyvinylidene chloride, cellulose, and cellulose acetate. The book also discusses the structure, chemistry, physics, fabrication, serviceability, and utilization of cellulose nitrate, cellulose ethers, starch, and regenerated proteins. Same type of evaluation is also done to polyamides, epoxy resins, polyformaldehyde, natural rubber, and nitrile rubbers. The text is a valuable source of information for readers interested in polymeric materials.
This industrially relevant resource covers all established and emerging analytical methods for the deformulation of polymeric materials, with emphasis on the non-polymeric components. Each technique is evaluated on its technical and industrial merits. Emphasis is on understanding (principles and characteristics) and industrial applicability. Extensively illustrated throughout with over 200 figures, 400 tables, and 3,000 references.
Recycling of rubber materials is necessary from both an environmental and economic perspective. This book describes everything from the world market to the many novel technologies and processes developed for the re-use and recycling of our common rubber materials. Devulcanization, production of rubber crumbs, reprocessing and manufacture of new materials are thoroughly described and discussed.