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This book contains a novel combination of experimental and model-based investigations, elucidating the complex processes inside zinc air batteries. The work presented helps to answer which battery composition and which air-composition should be adjusted to maintain stable and efficient charge/discharge cycling. In detail, electrochemical investigations and X-ray transmission tomography are applied on button cell zinc air batteries and in-house set-ups. Moreover, model-based investigations of the battery anode and the impact of relative humidity, active operation, carbon dioxide and oxygen on zinc air battery operation are presented. The techniques used in this work complement each other well and yield an unprecedented understanding of zinc air batteries. The methods applied are adaptable and can potentially be applied to gain further understanding of other metal air batteries.
Zinc-air batteries (ZABs) belong to the category of metal-air batteries, with high theoretical energy density, safety, and low cost. Nevertheless, there are still many challenges that need to be solved for the practical application of ZABs, including high overpotential, poor cycle life, and so on. This article first briefly introduced the principle of ZABs, covering the key components, functions of each element, and challenges faced by the system. Subsequently, seven methods for studying ZABs in-situ or operando were introduced, including X-ray computed tomography (XCT), optical microscopy imaging (OMI), transmission electron microscopy (TEM), nuclear magnetic resonance imaging (MRI), X-ray diffraction (XRD), Raman spectroscopy, and X-ray absorption spectroscopy (XAS), accompanied by specific research examples. The future perspectives of ZAB characterization have also been discussed.
Starting from physical and electrochemical foundations, this textbook explains working principles of energy storage devices. After a history of galvanic cells, different types of primary, secondary and flow cells as well as fuel cells and supercapacitors are covered. An emphasis lies on the general setup and mechanisms behind those devices to enable easy understanding for students from all technical and natural science disciplines.
Battery technology is constantly changing, and the concepts and applications of these changes are rapidly becoming increasingly more important as more and more industries and individuals continue to make “greener” choices in their energy sources. As global dependence on fossil fuels slowly wanes, there is a heavier and heavier importance placed on cleaner power sources and methods for storing and transporting that power. Battery technology is a huge part of this global energy revolution. Zinc batteries are an advantageous choice over lithium-based batteries, which have dominated the market for years in multiple areas, most specifically in electric vehicles and other battery-powered devices. Zinc is the fourth most abundant metal in the world, which is influential in its lower cost, making it a very attractive material for use in batteries. Zinc-based batteries have been around since the 1930s, but only now are they taking center stage in the energy, automotive, and other industries. Zinc Batteries: Basics, Developments, and Applicationsis intended as a discussion of the different zinc batteries for energy storage applications. It also provides an in-depth description of various energy storage materials for Zinc (Zn) batteries. This book is an invaluable reference guide for electrochemists, chemical engineers, students, faculty, and R&D professionals in energy storage science, material science, and renewable energy.
Explores both electrochemistry fundamentals and the applications of oxygen in electrochemical systems. Much of the information is summarized in tables which are accompanied by a list of references to consult for details. Emphasizes fuel cells and metal/air batteries.
Next-Generation Batteries with Sulfur Cathodes provides a comprehensive review of a modern class of batteries with sulfur cathodes, particularly lithium-sulfur cathodes. The book covers recent trends, advantages and disadvantages in Li-S, Na-S, Al-S and Mg-S batteries and why these batteries are very promising for applications in hybrid and electric vehicles. Battery materials and modelling are also dealt with, as is their design, the physical phenomena existing in batteries, and a comparison of batteries between commonly used lithium-ion batteries and the new class of batteries with sulfur cathodes that are useful for devices like vehicles, wind power aggregates, computers and measurement units. - Provides solutions for the recycling of batteries with sulfur cathodes - Includes the effects of analysis and pro and cons of Li-S, Na-S, Al-S, Mg-S and Zn-S batteries - Describes state-of-the-art technological developments and possible applications
Electricity from renewable sources of energy is plagued by fluctuations (due to variations in wind strength or the intensity of insolation) resulting in a lack of stability if the energy supplied from such sources is used in 'real time'. An important solution to this problem is to store the energy electrochemically (in a secondary battery or in hydrogen and its derivatives) and to make use of it in a controlled fashion at some time after it has been initially gathered and stored. Electrochemical battery storage systems are the major technologies for decentralized storage systems and hydrogen is the only solution for long-term storage systems to provide energy during extended periods of low wind speeds or solar insolation. Future electricity grid design has to include storage systems as a major component for grid stability and for security of supply. The technology of systems designed to achieve this regulation of the supply of renewable energy, and a survey of the markets that they will serve, is the subject of this book. It includes economic aspects to guide the development of technology in the right direction. - Provides state-of-the-art information on all of the storage systems together with an assessment of competing technologies - Features detailed technical, economic and environmental impact information of different storage systems - Contains information about the challenges that must be faced for batteries and hydrogen-storage to be used in conjunction with a fluctuating (renewable energy) power supply
Discover the physical chemistry of charge carriers in the second edition of this popular textbook Ionic and electronic charge carriers are critical to the kinetic and electrochemical properties of ionic solids. These charge carriers are point defects and are decisive for electrical conductivity, mass transport, and storage phenomena. Generally, defects are deviations from the perfect structure, and if higher-dimensional, also crucial for the mechanical properties. The study of materials science and energy research therefore requires a thorough understanding of defects, in particular the charged point defects, their mobilities, and formation mechanisms. Physical Chemistry of Ionic Materials is a comprehensive introduction to these charge carrier particles and the processes that produce, move, and activate them. Covering both core principles and practical applications, it discusses subjects ranging from chemical bonding and thermodynamics to solid-state kinetics and electrochemical techniques. Now in an updated edition with numerous added features, it promises to be the essential textbook on this subject for a new generation of materials scientists. Readers of the 2nd Edition of Physical Chemistry of Ionic Materials will also find: Two new chapters on solid state electrochemistry and another on nanoionics Novel brief sections on photoelectrochemistry, bioelectrochemistry, and atomistic modelling put the treatment into a broader context Discussion of the working principles required to understand electrochemical devices like sensors, batteries, and fuel cells Real laboratory measurements to ground basic principles in practical experimentation Physical Chemistry of Ionic Materials is a valuable reference for chemists, physicists, and any working researchers or advanced students in the materials sciences.