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Cutting-edge research and innovative science... PROGRESS in Inorganic Chemistry Hailed by professional chemists as an index of the most influentialand current research being done in inorganic chemistry, Progress inInorganic Chemistry has also enjoyed the reputation as anindispensable working reference. Featuring the work ofinternationally renowned chemists, this newest volume provides aclear, authoritative examination of each critical new advance andinnovative development in inorganic chemistry today. "This series is distinguished not only by its scope and breadth,but also by the depth and quality of the reviews."--Journal of theAmerican Chemical Society "This series is a valuable addition to the library of thepracticing research chemist, and is a good starting point forstudents wishing to understand modern inorganicchemistry."--Canadian Chemical News "[This series] has won a deservedly honored place on the bookshelfof the chemist attempting to keep afloat in the torrent of originalpapers on inorganic chemistry."--Chemistry in Britain CONTENTS OF VOLUME 43 * Oxovanadium and Oxomolybdenum Clusters and Solids IncorporatingOxygen-Donor Ligands (M. Ishaque Kahn, Illinois Institute ofTechnology, and Jon Zubieta, Syracuse University) * The Application of Polychalcogenide Salts to the ExploratorySynthesis of Solid State Multinary Chalcogenides at IntermediateTemperatures (Mercouri G. Kanatzidis and Anthony C. Sutorik,Michigan State University) * Mechanistic and Kinetic Aspects of Transition Metal OxygenChemistry (Andreja Bakac, Iowa State University) * The Chemistry of Metal Complexes with Selenolate and TellurolateLigands (John Arnold, University of California, Berkeley) * Coordination Chemistry with Sterically Hindered Hydrotris(pyrazolyl) borate Ligands: Organometallic and BioinorganicPerspectives (Nobumasa Kitajima, Tokyo Institute of Technology, andWilliam B. Tolman, University of Minnesota) * Metal Complexes of Calixarenes (D. Max Roundhill, TulaneUniversity)
Straight from the frontier of scientific investigation . . . PROGRESS in Inorganic Chemistry Nowhere is creative scientific talent busier than in the world of inorganic chemistry. And the respected Progress in Inorganic Chemistry series has long served as an exciting showcase for new research in this area. With contributions from internationally renowned chemists, this latest volume reports the most recent advances in the field, providing a fascinating window on the emerging state of the science. "This series is distinguished not only by its scope and breadth, but also by the depth and quality of the reviews." --Journal of the American Chemical Society. "[This series] has won a deservedly honored place on the bookshelf of the chemist attempting to keep afloat in the torrent of original papers on inorganic chemistry." --Chemistry in Britain. CONTENTS OF VOLUME 47 Terminal Chalcogenido Complexes of the Transition Metals (Gerard Parkin, Columbia University) * Coordination Chemistry of Azacryptands (Jane Nelson, Vickie McKee, and Grace Morgan, The Queen's University, Northern Ireland) * Polyoxometallate Complexes in Organic Oxidation Chemistry (Ronny Neumann, Hebrew University of Jerusalem, Israel) * Metal-Phosphonate Chemistry (Abraham Clearfield, Texas A&M University) * Oxidation of Hydrazine in Aqueous Solution (David M. Stanbury, Auburn University) * Metal Ion Reconstituted Hybrid Hemoglobins (B. Venkatesh, J. M. Rifkind, and P. T. Manoharan, Sophisticated Instrumentation Centre, IIT, Madras, India) * Three-Coordinate Complexes of "Hard" Ligands: Advances in Synthesis, Structure, and Reactivity (Christopher C. Cummins, Massachusetts Institute of Technology) * Metal-Carbohydrate Complexes in Solution (Jean-Francois Verchere and Stella Chapelle, Universite de Rouen, France; Feibo Xin and Debbie C. Crans, Colorado State University).
Iron–sulfur (FeS) centers are essential protein cofactors in all forms of life. They are involved in many key biological processes. In particular, Fe-S centers not only serve as enzyme cofactors in catalysis and electron transfer, they are also indispensable for the biosynthesis of complex metal-containing cofactors. Among these cofactors are the molybdenum (Moco) and tungsten (Wco) cofactors. Both Moco/Wco biosynthesis and Fe-S cluster assembly are highly conserved among all kingdoms of life. After formation, Fe-S clusters are transferred to carrier proteins, which insert them into recipient apo-proteins. Moco/Wco cofactors are composed of a tricyclic pterin compound, with the metal coordinated to its unique dithiolene group. Moco/Wco biosynthesis starts with an Fe-S cluster-dependent step involving radical/S-adenosylmethionine (SAM) chemistry. The current lack of knowledge of the connection of the assembly/biosynthesis of complex metal-containing cofactors is due to the sheer complexity of their synthesis with regard to both the (genetic) regulation and (chemical) metal center assembly. Studies on these metal-cofactors/cofactor-containing enzymes are important for understanding fundamental cellular processes. They will also provide a comprehensive view of the complex biosynthesis and the catalytic mechanism of metalloenzymes that underlie metal-related human diseases.
This go-to text provides information and insight into physical inorganic chemistry essential to our understanding of chemical reactions on the molecular level. One of the only books in the field of inorganic physical chemistry with an emphasis on mechanisms, it features contributors at the forefront of research in their particular fields. This essential text discusses the latest developments in a number of topics currently among the most debated and researched in the world of chemistry, related to the future of solar energy, hydrogen energy, biorenewables, catalysis, environment, atmosphere, and human health.