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This reference offers an overview of the bulk and surface properties of perovskite-like structures, and provides the latest discussions on the applications of these materials and processes. It also introduces ceramic methods for the processing of perovskite-derived high Tc cuprates.;Examining every available procedure for synthesizing high-surface-area perovskite oxides, this book: delineates processing techniques for preparing perovskite-derived high-critical-temperature superconductors; illustrates the relevance of physiochemical methods to investigate bulk and surface structures of perovskite compounds; explicates the importance of surface composition in the context of catalytic behaviour; summarizes methods of changing stoichiometry; shows how to design perovskite oxides for a given purpose; reviews key solid-state properties; and presents the major applications.
The current book brings together cutting-edge research in the area of heterogeneous catalytic redox processes. The first part of the book covers the catalytic properties of transition metal oxides and the techniques for catalysts preparation, such as mechanochemistry, plasmochemistry, hydrothermal treatment, etc. Further the authors focus on mechanisms of heterogeneous redox reactions followed by the overview of industrial applications.
Most of the papers contained in this volume are based on pres entations made at the symposium on Catalytic Conversions of Synthesis Gas and Alcohols to Chemicals, which was held at the 17th Middle At lantic Regional Meeting of the American Chemical Society, April 6-8, 1983, in the setting of the Pocono Hershey Resort, White Haven, PA. I thank Dr. Ned D. Heindel, General Chairman, and Dr. Natalie Foster, Program Chairman, both of Lehigh University, for the invitation to organize the symposium. Financial support was received from Air Products and Chemicals, Inc. for the organization of the symposium, and acknowledgement is made to Air Products and Chemicals, Inc. and to the Donors of the Petroleum Research Fund, administered by the American Chemical Society, for partial support of the conduct of the symposium. The theme of this volume is the recent progress made in devel oping and understanding viable catalytic syntheses of chemicals di rectly from synthesis gas (CO + H2) or indirectly via alcohols. An aim of the symposium and of this volume is to provide a meaningful blend of applied and basic science and of the chemistry and engineer ing of processes that are, or hold promise to be, economically and industrially feasible. The topics demonstrate the increasing impor tance of synthesis gas as a versatile feedstock and emphasize the central role that alcohols, such as methanol, can playas chemical intermediates.
It is estimated that a large fraction of natural gas reserves are found in locations from where transport is not economical. If these isolated natural gas reserves could be converted to synthetic fuels, they would generate around 250 billion barrels of synthetic oil-a quantity equal to one-third of the Middle East's proven oil reserves. Small-Scale