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Water interacts with metal ions in a variety of contexts: from aqueous solutions of inorganic salts to enzymatic catalysis. The investigation of water-metal ion interactions is conveniently performed through water 1H NMR at different magnetic field-a technique known as relaxometry. Advances in Inorganic Chemistry, Volume 57 focuses on relaxometry of water-metal ion interactions.Contributions by leading experts in the field cover important advances in inorganic and bioinorganic chemistry; another welcomed addition to the widely acclaimed series, Advances in Inorganic Chemistry. * Includes new information on the important advances in inorganic and bioinorganic chemistry * Each chapter is fully referenced * Contains comprehensive reviews written by leading experts in the field
Developments in potato chemistry, including identification and use of the functional components of potatoes, genetic improvements and modifications that increase their suitability for food and non-food applications, the use of starch chemistry in non-food industry and methods of sensory and objective measurement have led to new and important uses for this crop. Advances in Potato Chemistry and Technology presents the most current information available in one convenient resource.The expert coverage includes details on findings related to potato composition, new methods of quality determination of potato tubers, genetic and agronomic improvements, use of specific potato cultivars and their starches, flours for specific food and non-food applications, and quality measurement methods for potato products. - Covers potato chemistry in detail, providing key understanding of the role of chemical compositions on emerging uses for specific food and non-food applications - Presents coverage of developing areas, related to potato production and processing including genetic modification of potatoes, laboratory and industry scale sophistication, and modern quality measurement techniques to help producers identify appropriate varieties based on anticipated use - Explores novel application uses of potatoes and potato by-products to help producers identify potential areas for development of potato variety and structure
In this compilation, the authors begin by highlighting the recent developments in asymmetric 1,4- and 1,2- additions to α, β-unsaturated carbonyl compounds. The recent finding of Cu (I)-catalyzed asymmetric 1,2-addition of Grignard reagents to α, β-unsaturated carbonyl compounds, as well as aromatic ketones, has categorically revolutionized catalytic asymmetric reactions.This compilation also aims to use the well-known coordination preference of zinc in phthalocyanine and porphyrin ligands in correlation with supramolecular systems. The light-absorption process in dye-sensitized solar cells is studied using the time-dependent density functional theory.In recent years, a series of investigations on detonation wave formation in acetylene have been published. In these studies, it was shown that the formation of detonation proceeds entirely due to the energy released during the condensation of carbon nanoparticles during the growth of poly-aromatic hydrocarbons. The results of these studies are summarized and practical applications are discussed.The authors discuss aromatic amines, derivatives of aromatic hydrocarbons containing an amino group/an amine group/nitrogen atom in their structures. These compounds represent one of the most important classes of industrial and environmental chemicals. Three groups have been studied: monocyclic, polycyclic, and heterocyclic aromatic amines, which are used as intermediates in azo dye manufacturing, pigments, drugs, antibiotics, antidepressants, pesticides, and other industrial products.In the closing study, the GC-MS/MS method has been developed for the determination and quantification of 35 multiclass pesticide residues in chili samples. Pesticides were selected from different families including organochlorines, organophosphorus, carbamates, pyrethroids, triazines, triazoles, and pyrazoles. The QuEChERS-dSPE method was used for the extraction of pesticide residue.
The Advances in Chemical Physics series provides the chemical physics and physical chemistry fields with a forum for critical, authoritative evaluations of advances in every area of the discipline. Filled with cutting-edge research reported in a cohesive manner not found elsewhere in the literature, each volume of the Advances in Chemical Physics series serves as the perfect supplement to any advanced graduate class devoted to the study of chemical physics.
Solution chemistry deals with liquid solutions in such fields as physical chemistry, chemical physics, molecular biology, statistical mechanics, biochemistry, and biophysics. This book includes experimental investigations of the dielectric, spectroscopic, thermodynamic, transport, or relaxation properties of both electrolytes and non-electrolytes in liquid solutions. The latest research in the world has been selected, gathered and presented here.
The two-part, fifth edition of Advanced Organic Chemistry has been substantially revised and reorganized for greater clarity. The material has been updated to reflect advances in the field since the previous edition, especially in computational chemistry. Part A covers fundamental structural topics and basic mechanistic types. It can stand-alone; together, with Part B: Reaction and Synthesis, the two volumes provide a comprehensive foundation for the study in organic chemistry. Companion websites provide digital models for study of structure, reaction and selectivity for students and exercise solutions for instructors.
This book emphasises those features in solution chemistry which are difficult to measure, but essential for the understanding of both the qualitative and the quantitative aspects. Attention is paid to the mutual influences between solute and solvent, even at extremely small concentrations of the former. The described extension of the molecular concept leads to a broad view ? not by a change in paradigm ? but by finding the rules for the organizations both at the molecular and the supermolecular level of liquid and solid solutions.
The 52nd Colloid and Surface Science Symposium of the Divis ion of Colloid and Surface Chemistry of the American Chemical Society was held in Knoxville, TN, June 12-14, 1978, and one of its Sections was devoted to the topic of Solution Chemistry of Surfactants. Although it was billed as the Section on Solution Chemistry of Surfactants, but it was indeed a veritable inter national symposium on this topic as 51 papers by about 100 con tributors from 12 countries were listed in the program. The present volume and its companion volume 2 document the proceedings of the above-mentioned Section on Solution Chemistry of Surfactants. In 1976 there was held an international symposium on Micellization, Solubilization and Microemulsions in Albany, l the proceedings of which have been chronicled in two volumes. A great deal of material dealing with micelles contributed by a legion of prominent researchers constitutes these volumes but a few subtopics were not adequately covered; so it was deemed appro priate to cover these topics as well as the recent progress in the general area of aggregation of surfactants in this Section. Also as it is the amphiphilicity or amphipathicity* of a surfact ant molecule which is responsible for both adsorption at inter faces and aggregation in solution, so it was considered quite apropos to include the topic of adsorption at interfaces in this Section. Concomitantly, the present volumes not only cover the aggregation phenomena but also the adsorption at interfaces.
Advances in Chemistry Research. Volume 62 first provides information related to the synthesis, morphology, crystal structure, and porosity of bentonite and bentonite/magnetite powders. Following this, the authors discuss carbon tetrachloride, a clear, colourless, volatile and very stable chlorinated hydrocarbon with a non-polar nature, making it an excellent solvent.Recent research on the applications of hydrogen peroxide as oxidizing and reducing agent is presented, as well as its application in biocatalysis, as signaling molecule, and in nanochemistry.The mode of action hydrogen peroxide induces in yeast apoptosis is also addressed, including overexpression of apoptosis inducing factor homologue proteins.Additionally, this compilation describes the recent advances concerning the use of hydrogen peroxide in heteropolyacid-catalyzed oxidation reactions of terpenic alcohols, which are renewable origin compounds whose oxidation provides aldehydes and epoxides.Diamines, organic compounds with two amino groups, are described. In one study, different diamines are synthesized with complex formulas used in the preparation of different thermally stable polymers.A few diamines used in developing thin-film polyamide composite membranes are reviewed.The concluding study is focused on gas hydrates, mixtures of light gases such as methane, ethane or carbon dioxide, and water molecules under a special temperature and pressure condition, forming a liquid-like material.