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The past decade has witnessed major advances in our understanding of the chemical composition, structure, and reactivity of the complex organic-rich fossil matter known as "coal. " Nevertheless, important scientific questions concerning molecular weight distributions, degree of crosslinking, typical duster sizes, type of interconnecting bridges, the possible role of a "mobile phase," and the nature of organic sulfur forms remain topics of heated debate. Moreover, there appears to be a notable lack of consensus regarding the overall direction and goals of structural elucidation work. Is it worthwhile to study whole coal samples, or should we separate out the various, more or less well-defined, maceral and mineral constituents before attempting to describe the structural and compositional features of coal at the molecular Ievel? Second, should there be more emphasis on key structural features and average statistical parameters, or is it necessary to identify individual chemical structures in considerable detail? From the developments of the past decade it is clear that advanced spectroscopic techniques are playing an increasingly important role in resolving difficult questions with regard to the chemical structure and composition of coal. Moreover, it has become equally clear that no single spectroscopic approach can provide all the answers but multiple techniques need to be used in a highly integrated and synergistic manner.
Updating content from the author’s 2001 book Coal Desulfurization, this new title focuses on CO2 sequestration and utilization. It includes information on the theory and practical approaches to CO2 capture and recent advances in the use of sequestered CO2. Avoiding these pollutants requires either forgetting about the 250 billion tons of coal reserves the United States possesses or capturing and utilizing the pollutants in a profitable and environmentally responsible fashion. The book covers postcombustion and precombustion capture approaches for coal, and postcombustion capture can be generalized to many other fuels. Recent practical implementations at full-scale power facilities around the world are discussed. The book covers sequestering CO2 via underground, oceanic, biological, and other long-term CO2 storage methods. It also includes recent advances in utilizing CO2 for enhanced oil recovery, advances in storage with depleted oil and gas reservoirs and deep saline aquifers, and additional topics. The book also examines specific applications of pure CO2 and covers chemical conversion of CO2 to useful compounds. It answers questions like "Can we create methanol from coal?" or "Can we create ethanol from coal?" It is found that methanol and ethanol cannot be sustainably produced from coal power alone. However, oxalic acid can be created at a much lower energy cost than methanol or ethanol. Oxalic acid can be used to extract rare earths, which are not currently produced anywhere in the United States, but are typically concentrated in coal ash. Aimed at researchers and industry professionals in chemical, environmental, and energy engineering, this book provides insight and inspiration into capturing CO2 not merely as a response to regulatory pressure and climate change but as an inherently profitable and valuable venture.
All the guidance needed to test coal and analyze the results With the skyrocketing costs of most fuel sources, government, industry, and consumers are taking a greater interest in coal, an abundant and inexpensive alternative, which has been made more environmentally friendly through new technology. Published in response to this renewed interest, Handbook of Coal Analysis provides readers with everything they need to know about testing and analyzing coal. Moreover, it explains the meaning of test results and how these results can predict coal behavior and its corresponding environmental impact during use. The thorough coverage of coal analysis includes: * Detailed presentation of necessary standard tests and procedures * Explanation of coal behavior relative to its usage alongside the corresponding environmental issues * Coverage of nomenclature, terminology, sampling, and accuracy and precision of analysis * Step-by-step test method protocols for proximate analysis, ultimate analysis, mineral matter, physical and electrical properties, thermal properties, mechanical properties, spectroscopic properties, and solvent properties * Emphasis on relevant American Society for Testing and Materials (ASTM) standards and test methods, including corresponding International Organization for Standardization (ISO) and British Standards Institution (BSI) test method numbers To assist readers in understanding the material, a glossary of terms is provided. Each term is defined in straightforward language that enables readers to better grasp complex concepts and theory. References at the end of each chapter lead readers to more in-depth discussions of specialized topics. This is an essential reference for analytical chemists, process chemists, and engineers in the coal industry as well as other professionals and researchers who are looking to coal as a means to decrease dependence on foreign oil sources and devise more efficient, cleaner methods of energy production.
Over the past decade, extensive research has been conducted on the subject of coal as one of the world's leading energy sources. The current and future status of this resource is a topic of considerable interest to the largest world economies, including the US, Japan, China and Europe. Advances in the Science of Victorian Brown Coal provides critical reviews of the information and research published over this time, giving the reader an authoritative overview of the science surrounding this important topic. - Critical review of recent research surrounding the utilization of brown coal. Key issues addressed include maximized efficiency and minimized environmental impacts - Focuses on Victorian Brown Coal within the context of biomass and bituminous coal - A critical thermodynamic overview of various advanced power generation technologies
This book describes advances in both experimental and theoretical treatments in the field of energy transfer processes that are relevant to various fields, such as spectroscopy, laser technology, phosphors, artificial solar energy conversion, and photobiology. It presents the principles and available techniques through specific examples. In addition, it examines current and possible applications, including the most recent developments, and projects future advances and research possibilities in the field. Contents: Fundamental Interactions Leading to Energy Transfer (B Di Bartolo); Energy Transfer Processes in Atoms and Molecules (W DemtrAder et al.); Advances in the Techniques for the Study of Energy Transfer (D Hulin); Upconversion Phenomena with Laser Applications (X Chen); New Applications of Ultrafast Spectroscopy (J M Hvam); Efficient Solid State Lasers (N P Barnes); Emission Efficiency and Energy Transfer in Color Centers at High Concentrations (G Baldacchini); Four-Wave Mixing Studies of Energy Transfer Processes (G Boulon); Upconventional Light Emissions in Rare-Earth Doped Solids (F Auzel); Photonic Molecular and Supramolecular Devices (J M Lehn); Reflections on the Theory of Everything (G Costa); Earthquakes, Measurements, and Mitigation of Seismic Risk (R Console); Site Selectivity of Defects in IIIOCoV Compounds by Local Mode Spectroscopy and Model Calculations (D N Talwar); The General Non-Radiative Energy Transfer Master Equations for Crystalline Materials, the Exact Solution and Current Modeling (L A D az-Torres et al.); and other papers. Readership: Researchers and graduate students in the fields of lasers and optics."
Selected, peer reviewed papers from the 4th International Conference on Chemical Engineering and Advanced Materials (CEAM 2014), August 9-10, 2014, Shenzhen, China