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This report presents a cost analysis of Powdered Activated Carbon production from coconut shell. In the process examined, the coconut shells are crushed and then carbonized into a charcoal, which is activated by steam at high temperatures. The Activated Carbon is cooled and ground into powder of specified mesh size. This report was developed based essentially on the following reference(s): (1) "Carbon, Activated", Kirk-Othmer Encyclopedia of Chemical Technology, 5th edition (2) "Carbon, 5. Activated Carbon", Ullmann's Encyclopedia of Industrial Chemistry, 2010 Keywords: Steam Activated Process, Carbonization, Activated Charcoal, Activated Coal, Carbo Activatus
This report presents a cost analysis of Hydrogen Peroxide production from hydrogen. The process examined is a conventional anthraquinone auto-oxidation (AO) process. In this process, 2-ethyl anthraquinone is sequentially hydrogenated and oxidized generating Hydrogen Peroxide. This report was developed based essentially on the following reference(s): (1) "Hydrogen Peroxyde", Ullmann's Encyclopedia of Industrial Chemistry, 7th edition (2) "Hydrogen Peroxyde", McKetta, J., Inorganic Chemicals Handbook. Vol. 2 (3) US Patent 7238335, issued to Degussa in 2007(assigned to Evonik Degussa in 2010) Keywords: H2O2, AO Process, Riedl-Pfleiderer, EAQ, Evonik, Degussa, BASF, Dow, Solvay, Alkyanthraquinone
This report presents a cost analysis of Paracetamol production from 4-nitrochlorobenzene, sodium hydroxide, hydrogen and acetic anhydride. In the process, 4-nitrochlorobenzene reacts with sodium hydroxide producing para nitrol phenol (PNP). The PNP is then subjected to reduction, producing para amino phenol (PAP). The PAP is then acetylated to produce crude Paracetamol, which is further purified. This report was developed based essentially on the following reference(s): (1) US Patent 2008/0045756, issued to Rhodia Chimie in 2008 (2) US Patent 3079435 issued to Abbott Laboratories in 1963 Keywords: Acetaminophen, APAP, Acamol, Abensanil, para Nitrochlorobenzene, PNCB
This report presents a cost analysis of Propylene Oxide (PO) production from chemical grade (CG) propylene and chlorine. The process examined is a typical chlorohydrin process. In this process, propylene and chlorine first react to produce propylene chlorohydrin intermediate. Then, the chlorohydrin intermediate is dehydrochlorinated to Propylene Oxide. Dichloropropane is generated as by-product in the process. This report was developed based essentially on the following reference(s): "Propylene Oxide", Ullmann's Encyclopedia of Industrial Chemistry, 7th edition Keywords: Chlorohydrination, Saponification, Calcium Oxide, CaO, Calcium Hydroxide, CHPO
This report presents a cost analysis of Carbon Monoxide (CO) production from synthesis gas. The process examined is a typical cryogenic partial condensation process. This report was developed based essentially on the following reference(s): (1) "Cryogenic Technology", Ullmann's Encyclopedia of Industrial Chemistry, 2013; (2) Industrial Gases in Petrochemical Processing, 1998 Keywords: Cryogenic separation, partial condensation
This report presents a cost analysis of Methyl Ester Sulfonate (MES) production from palm oil. The process examined consists of two steps: a transesterification step similar to Lurgi Transesterification process and a sulfonation step similar to Chemithon process. In this process, palm oil and methanol are reacted forming methyl ester, which is then sulfonated to Methyl Ester Sulfonate. This report was developed based essentially on the following reference(s): (1) US Patent 8288574, issued to Lurgi in 2012 (2) Handbook of Detergents, Part F: Production Keywords: Methyl Alcohol, Sulfur Burning, Air/SO3 Sulfonation
This report presents a cost analysis of Carbon Fiber production from polyacrylonitrile (PAN) fiber. In this process, PAN fiber is first stabilized. The stabilized PAN passes then through carbonization, surface treatment and sizing, before being winded. This report was developed based essentially on the following reference(s): (1) "Fibers, 5. Synthetic Inorganic", Ullmann's Encyclopedia of Industrial Chemistry, 7th edition (2) US Patent 8137810, issued to Toray in 2012; Keywords: Polyacrylonitrile, carbon fiber, acrylic fiber, PAN
This report presents a cost analysis of Dimethyl Carbonate (DMC) production from methanol. The process examined is a typical oxidative carbonylation process. This process is a non-phosgene alternative for DMC production, in which CO, O2 and methanol react in the presence of copper chloride (CuCI) catalyst. Although reaction occurs in the liquid phase, a heterogeneous-phase mixture forms and the product stream is withdrawn from the reactor in vapor phase. The vapor is partially condensed, treated for recovery of catalyst and then subjected to distillation operations. Unreacted methanol is recovered and recycled to the reactor. Purified Dimethyl Carbonate is obtained after separation of side-product water. This report was developed based essentially on the following reference(s): (1) US Patent 20030236428, issued to General Electric Company (2) US Patent 5685957, issued to Enichem Synthesis in 1997 Keywords: Non-Phosgene Process, Phosgene-Free, Oxidative Carbonylation, Enichem, Eni
This report presents a cost analysis of a typical Ammonia production process from synthesis gas. In this process, hydrogen, recovered from syngas feedstock, and nitrogen, recovered from air, react producing Ammonia. This report was developed based essentially on the following reference(s): "Ammonia", Kirk-Othmer Encyclopedia of Chemical Technology, 4th edition; Keywords: Haber-Bosch, Haldor Topsoe, Uhde GmbH, Ammonia Casale and KBR
This report presents a cost analysis of Polyhydroxybutyrate (PHB) production from switchgrass. In this process, switchgrass is gasified to synthesis gas (syngas), which is fermented to PHB. Hydrogen is generated as by-product. This report was developed based essentially on the following reference(s): “A Techno-economic Analysis of Polyhydroxyalkanoate and Hydrogen Production from Syngas Fermentation of Gasified Biomass” Keywords: Polyhydroxyalcanoate, PHA, Gasification, Fermentation