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The majority of this book was written in 1983-84 while the senior author was a Visiting Scientist at Oak Ridge National Laboratory (ORNL) in Oak Ridge, Tennessee. We believe that the approach to the problem of acid deposition effects on soils and waters developed during this collaboration contains ele ments that are significantly different from most prior work in this area. Some of the material and the software used in the development of these concepts stem from earlier individual efforts of the authors. However, what we believe to be the more significant concepts concerning the processes by which alkalinity may be developed in acid soil solutions, and by which acid deposition may contrib ute to the loss of this alkalinity, were the result of this collaboration. The ultimate usefulness of these concepts in understanding and dealing with various aspects of the problems associated with acid deposition cannot be adequately gauged at the present time. They must first withstand tests of con sistency with available observation, and of direct experimentation. It is our hope that dissemination through this book will facilitate this process within the scientific community. The authors wish to thank the administration of the Environmental Science Division at ORNL, and the College of Agricultural Sciences at Colorado State University for their support in arranging this collaboration. We also wish to express our appreciation for the financial support provided by EPA. Personal thanks are due to Dr.
The causes and consequences of acid rain are subjects of widespread concern and controversy. However the effects of acid deposition on the chemistry of lakes and streams, and on the survival of fish and other aquatic life, have been greatly clarified by the results of a recent Anglo-Scandinavian surface waters research program. This book presents a concise, nonspecialist account of the results and their implications by the director of the program. Based on studies conducted throughout the United Kingdom and northern Europe, the book includes chapters on emissions, transport, and deposition of acid pollution; hydrochemical studies in catchments; catchment process studies; catchment manipulation experiments; the role of hydrology and soil chemistry; palaeolimnological studies; the toxic effects of acidification on fish and other aquatic life; and catchment modelling studies. The highly interdisciplinary nature of the research should appeal to a wide range of scientists and to policy-makers interested in acid rain and its consequences. It is also aimed at postgraduates and third-year undergraduate students in the environmental sciences.
Proceedings of the NATO Advanced Study Institute, Aussois, France, September 4-15, 1985
The Encyclopedia is a complete and authoritative reference work for this rapidly evolving field. Over 200 international scientists, each experts in their specialties, have written over 330 separate topics on different aspects of geochemistry including geochemical thermodynamics and kinetics, isotope and organic geochemistry, meteorites and cosmochemistry, the carbon cycle and climate, trace elements, geochemistry of high and low temperature processes, and ore deposition, to name just a few. The geochemical behavior of the elements is described as is the state of the art in analytical geochemistry. Each topic incorporates cross-referencing to related articles, and also has its own reference list to lead the reader to the essential articles within the published literature. The entries are arranged alphabetically, for easy access, and the subject and citation indices are comprehensive and extensive. Geochemistry applies chemical techniques and approaches to understanding the Earth and how it works. It touches upon almost every aspect of earth science, ranging from applied topics such as the search for energy and mineral resources, environmental pollution, and climate change to more basic questions such as the Earth’s origin and composition, the origin and evolution of life, rock weathering and metamorphism, and the pattern of ocean and mantle circulation. Geochemistry allows us to assign absolute ages to events in Earth’s history, to trace the flow of ocean water both now and in the past, trace sediments into subduction zones and arc volcanoes, and trace petroleum to its source rock and ultimately the environment in which it formed. The earliest of evidence of life is chemical and isotopic traces, not fossils, preserved in rocks. Geochemistry has allowed us to unravel the history of the ice ages and thereby deduce their cause. Geochemistry allows us to determine the swings in Earth’s surface temperatures during the ice ages, determine the temperatures and pressures at which rocks have been metamorphosed, and the rates at which ancient magma chambers cooled and crystallized. The field has grown rapidly more sophisticated, in both analytical techniques that can determine elemental concentrations or isotope ratios with exquisite precision and in computational modeling on scales ranging from atomic to planetary.
Processes of acidification or alkalization of soils are treated, taking the qualitative changes in soil chemistry into consideration. Following a theoretical background of ecosystem proton budgets, the application for assessing external and internal acid loads are demonstrated. The chemistry of organic matter and the oxides of aluminum, iron, and manganese are treated in the context of being sources and sinks for acid loads in soils. Special attention is payed to the assessment of solubility and reaction kinetics of aluminous minerals. The formation of toxic elements in soil solution resulting from the solubilization of inorganic oxides as well as aspects of changes in the nutrient status of soils, changes of fertility and processes leading to a transfer of acidity from soils to surface are discussed.
Ecosystem research has emerged in recent decades as a vital, successful, and sometimes controversial approach to environmental science. This book emphasizes the idea that much of the progress in ecosystem research has been driven by the emergence of new environmental problems that could not be addressed by existing approaches. By focusing on successes and limitations of ecosystems studies, the book explores avenues for future ecosystem-level research.
'Acid rain' is a broad term used to describe several ways that acids fall out of the atmosphere. A more precise term is acid deposition, which has two parts: wet and dry. Wet deposition refers to acidic rain, fog, and snow. As this acidic water flows over and through the ground, it affects a variety of plants and animals. The strength of the effects depends on many factors, including how acidic the water is, the chemistry and buffering capacity of the soils involved, and the types of fish, trees, and other living things that rely on the water. Dry deposition refers to acidic gases and particles. About half of the acidity in the atmosphere falls back to earth through dry deposition. The wind blows these acidic particles and gases onto buildings, cars, homes, and trees. Dry deposited gases and particles can also be washed from trees and other surfaces by rainstorms. When that happens, the runoff water adds those acids to the acid rain, making the combination more acidic than the falling rain alone. Prevailing winds blow the compounds that cause both wet and dry acid deposition across state and national borders, and sometimes over hundreds of miles. This new book combines an excellent background article with over 900 abstracts and book citations. Easy access is provided by title, author, and subject indexes.