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to arrive at some temporary consensus model or models; and to present reliable physical data pertaining to water under a range of conditions, i.e., "Dorsey revisited," albeit on a less ambitious scale. I should like to acknowledge a debt of gratitude to several of my col leagues, to Prof. D. J. G. Ives and Prof. Robert L. Kay for valuable guidance and active encouragement, to the contributors to this volume for their willing cooperation, and to my wife and daughters for the understanding shown to a husband and father who hid in his study for many an evening. My very special thanks go to Mrs. Joyce Johnson, who did all the cor respondence and much of the arduous editorial work with her usual cheerful efficiency. F. FRANKS Biophysics Division Unilever Research Laboratory ColworthjWelwyn Colworth House, Sharnbrook, Bedford March 1972 Contents Chapter 1 Introduction-Water, the Unique Chemical F. Franks I. lntroduction ........................................ . 2. The Occurrence and Distribution of Water on the Earth 2 3. Water and Life ...................................... 4 4. The Scientific Study of Water-A Short History ........ 8 5. The Place of Water among Liquids . . . . . . . . . . . . . . . 13 . . . . . Chapter 2 The Water Moleeule C. W. Kern and M. Karplus 1. Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21 . . . . . . . . . . 2. Principles of Structure and Spectra: The Born-Oppenheimer Separation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22 . . . . . . . . . . . . 3. The Electronic Motion ............................... 26 3.1. The Ground Electronic State of Water ............ 31 3.2. The Excited Electronic States of Water ........... 50 4. The Nuclear Motion ................................. 52 5. External-Field Effects ................................. 70 5.1. Perturbed Hartree-Fock Method . . . . . . . . . . . . . . . 74 . . .
V.4 Aqueous solutions of amphiphiles and macromolecules. Author, subject and compound indexes.
‹";Progress in Physical Chemistry"; is a collection of recent ";Review Articles"; published in the ";Zeitschrift für Physikalische Chemie";. The aim of a ";Review Article"; is to give a profound survey on a special topic outlining the history, development, state of the art and future research. Collecting these Reviews the Editor(s) of Zeitschrift für Physikalische Chemie intend to counteract the expanding flood of papers and thereby to give students and researchers a means to obtain fundamental knowledge on their special interests. The first volume of Progress in Physical Chemistry is mainly focussed on intermolecular interaction, also glancing at topics that are marginally touched. Contents •Martina Havenith*, Gerhard W. Schwaab, Attacking a Small Beast: Ar-Co, a Proto-type for Intermolecular Forces •Otto Dopfer, IR Spectroscopy of Microsolvated Aromatic Cluster Ions: Ionization-Induced Switch in Aromatic Molecule-Solvent Recognition •Clemens F. Kaminski, Fluorescence Imaging of Reactive Processes •T. Stangler, R. Hartmann, D.Willbold, B.W. König*, Modern high resolution NMR fort he study of structure, dynamics and interactions of biological macromolecules •Markus Drescher, Time-Resolved ESCA: a Novel Probe for Chemical Dynamics •Constanze Donner, Kinetics of Electrochemical Phase Formation in Two-Dimensional Systems •Claus Czeslik, Factors Ruling Protein Adsorption •Thomas Koop, Homogeneous Ice Nucleation in Water and Aqueous Solutions.
Physical Chemistry: An Advanced Treatise, Volume IV: Molecular Properties provides the aspects of the properties of single molecules and physical methods available for their determination. This book discusses linear polyatomic molecules, quantum-mechanical theory of vibrations, spectra of organic molecules, production and detection of free radicals, and force constants and molecular structure. The Hund's coupling cases for diatomic molecules, methods of measuring dipole moments, NMR spectra, and ESR spectra of organic species are also elaborated. This publication likewise covers the applications of the Mössbauer effect, electric deflection experiments, and effects of intramolecular motions on diffraction patterns. This volume is intended for graduate and physical chemistry students interested in molecular properties.
This book consists of two parts, theory and applications. Part I introduces the kinetic theory of gases with relevance to molecular energies and intermolecular forces. Part II focuses on how these theories are used to explain real techniques and phenomena involving gases. By stressing the practical implications, the book explains the theory of gas dynamics in a highly readable and comprehensive manner.
Textbook on modern theoretical chemistry suitable for advanced undergraduate or graduate students.
A practical guide for graduate students and researchers on all aspects of x-ray scattering experiments on liquid surfaces and interfaces.