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Although the chemistry of boron is still relatively young, it is developing at a pace where even specific areas of research are difficult to compile into a monograph. Besides the boron hydrides, boron-nitrogen compounds are among the most fascinating derivatives of boron. Nitrogen compounds exist in a wide variety of molecular structures and display many interesting properties. The combination of nitrogen and boron, however, has some unusual features that are hard to match in any other combination of elements. This situation was first recognized by ALFRED STOCK and it seems proper to pay tribute to his outstanding work in the area of boron chemistry. One should realize that about forty years ago, STOCK and his coworkers had to develop completely new experimental techniq'\les and that no guidance for the interpreta tion of their rather unusual data had been advanced by theoretical chemists. In this monograph an attempt has been made to explore the general characteristics of structure and the principles involved in the preparation and reactions of boron-nitroge~ compounds. It was a somewhat difficult task to select that information which appears to be of the most interest to "inorganic and general chemistry" since the electronic relationship between a boron-nitrogen and a carbon-carbon grouping is reflected in the "organic" character of many of the reactions and compounds.
The continued and evolving significance of boron chemistry to the wider chemical community is demonstrated by the international and interdisciplinary nature of the research reported in this book. Contemporary Boron Chemistry encompasses inorganic and organic compounds as well as polymers, solid-state materials, medicinal aspects and theoretical studies. Covering many areas of chemistry with boron at its centre, topics include applications to polyolefin catalysis, medicine, materials and polymers; boron cluster chemistry, including carboranes and metal-containing clusters; organic and inorganic chemistry of species containing only 1 or 2 boron atoms; and theoretical studies of boron-containing compounds. New materials with novel optical and electronic properties are also discussed. Comprehensive and up to date, graduates and researchers in a wide range of fields, particularly those in organometallic and organic chemistry and materials science, will welcome this book.
Progress in Boron Chemistry, Volume 3 discusses the chemistry and applications of boron and its compounds. This book offers a detailed treatment of five areas of boron chemistry. Organized into five chapters, this volume begins with an overview of the use of boric acid to favor alcohol formation in the air oxidation of hydrocarbons. This text then explains the standard procedure for hydrocarbon oxidation, which consists of passing air or a dilute oxygen in nitrogen stream via a suspension of boric acid in the heated substrate. Other chapters describe the radical-catalyzed addition of carbon tetrachloride to dibutyl vinylboronate and examine the growing interest in boron–nitrogen chemistry. This book discusses as well the polar addition of hydrogen bromide to unsaturated boronic esters. The final chapter deals with the chemical properties of organic boron–sulfur compounds. This book is a valuable resource for chemists, organic chemists, students, and research workers.
The following new organic boron-nitrogen compounds were synthesised NH-phenylene t-butylaminoboronate NH-phenylene ethylaminoboronate NH-phenylene isopropylaminoboronate NH-phenylene phenylaminoboronate NH-phenylene dimethylaminoboronate The last four compounds were all obtained as hydrolytically stable dimers. The problem of monomer = dimer, equilibrium and the influence thereon of substituents on the nitrogen atom has been studied qualitatively. 2. A preliminary study of the sulphonylamino- boron compounds compounds characterised are Bis(NH-phenylenedioxyboron) sulphamide.
Boron Compounds—Advances in Research and Application: 2013 Edition is a ScholarlyEditions™ book that delivers timely, authoritative, and comprehensive information about Boronic Acids. The editors have built Boron Compounds—Advances in Research and Application: 2013 Edition on the vast information databases of ScholarlyNews.™ You can expect the information about Boronic Acids in this book to be deeper than what you can access anywhere else, as well as consistently reliable, authoritative, informed, and relevant. The content of Boron Compounds—Advances in Research and Application: 2013 Edition has been produced by the world’s leading scientists, engineers, analysts, research institutions, and companies. All of the content is from peer-reviewed sources, and all of it is written, assembled, and edited by the editors at ScholarlyEditions™ and available exclusively from us. You now have a source you can cite with authority, confidence, and credibility. More information is available at http://www.ScholarlyEditions.com/.