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The Chemistry of Chromium, Molybdenum and Tungsten deals with the chemistry of chromium, molybdenum, and tungsten. The discovery and history, occurrence and distribution, and production of all three elements are discussed, along with their industrial uses, preparation, and allotropes; nuclear, physical, and chemical properties; biological activities; and analytical chemistry. Organized into three sections, this volume begins with an overview of the history, occurrence and distribution, and production of chromium, molybdenum, and tungsten, as well as their industrial uses, preparation, and allotropes; nuclear, physical, and chemical properties; biological activities; and analytical chemistry. The intermetallic phases in binary alloys of all three elements are also considered, along with their oxidation states and respective compounds including compounds with non-metallic elements; compounds of ?-acceptor ligands; organometallic complexes; and peroxy compounds such as peroxychromates, tetraperoxy molybdates, and peroxy tungstates. This book will be of interest to inorganic chemists as well as students and researchers in the field of inorganic chemistry.
In retrospect, it was obvious that we were both, quite inde pendently, contemplating a conference on the role of molybdenum in biology and related chemistry. At the time though, the meeting of minds on this matter was quite surprising. Although this subject has been treated in previous meetings within the overall context of, say, magnetic resonance or nitrogen fixation, it was apparent to us both that research in molybdenum-containing enzymes and molyb denum chemistry had progressed rapidly in the last several years. Jointly, we decided to organize the first meeting on Molybdenum Chemistry of Biological Significance which was held at the Hotel Lake Biwa, Shiga, Japan, on April 10-13, 1979. This volume con stitutes the Proceedings of that international conference and covers the broad spectrum of interests from enzymes to coordination chemistry. It should serve not only as a source of new information on the latest research results in this area and as a useful ref erence tool, but should also allow a newcomer or other peripherally interested researcher to become conversant very rapidly with the "state-of-the-art" in this specialized and important area of research. The conference was sponsored by the Japan Society for the Promotion of Science, the Japan World Exposition Commemerative Fund the Yamada Science Foundation, the Nissan Science Foundation, the Chemical Society of Japan (Kinki Regional Office) and the Agri cultural Chemical Society of Japan (Kansai Branch). We thank these organizations sincerely for their interest and generosity.