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Although the basic theories of thermodynamics are adequately covered by a number of existing texts, there is little literature that addresses more advanced topics. In this comprehensive work the author redresses this balance, drawing on his twenty-five years of experience of teaching thermodynamics at undergraduate and postgraduate level, to produce a definitive text to cover thoroughly, advanced syllabuses. The book introduces the basic concepts which apply over the whole range of new technologies, considering: a new approach to cycles, enabling their irreversibility to be taken into account; a detailed study of combustion to show how the chemical energy in a fuel is converted into thermal energy and emissions; an analysis of fuel cells to give an understanding of the direct conversion of chemical energy to electrical power; a detailed study of property relationships to enable more sophisticated analyses to be made of both high and low temperature plant and irreversible thermodynamics, whose principles might hold a key to new ways of efficiently covering energy to power (e.g. solar energy, fuel cells). Worked examples are included in most of the chapters, followed by exercises with solutions. By developing thermodynamics from an explicitly equilibrium perspective, showing how all systems attempt to reach a state of equilibrium, and the effects of these systems when they cannot, the result is an unparalleled insight into the more advanced considerations when converting any form of energy into power, that will prove invaluable to students and professional engineers of all disciplines.
The corresponding-states principle helps the understanding and calculating of thermodynamic, transport, and surface properties of substances in various states, required by our modern lifestyle. The Corresponding-States Principle and its Practice: Thermodynamic, Transport and Surface Properties of Fluids describes the origins and applications of the principle from a universal point of view with comparisons to experimental data where possible. It uses the universal theory to explain present theories. Emphasis is on the properties of pure systems, and the corresponding-states theory can also be extended to mixtures, which are treated as pure systems. Furthermore, the author discusses current progress, and shows technicians how to derive practical equations from molecular modeling. The Corresponding-States Principle and its Practice: Thermodynamic, Transport and Surface Properties of Fluids is the ideal handbook for those in chemical science and engineering related to energy, environment, natural gas, and petroleum. * Describes the origins and applications from a universal viewpoint* Includes experimental data for comparisons * Suitable for researchers, applied engineers, and those interested in the corresponding states theory
Flowing matter is all around us, from daily-life vital processes (breathing, blood circulation), to industrial, environmental, biological, and medical sciences. Complex states of flowing matter are equally present in fundamental physical processes, far remote from our direct senses, such as quantum-relativistic matter under ultra-high temperature conditions (quark-gluon plasmas). Capturing the complexities of such states of matter stands as one of the most prominent challenges of modern science, with multiple ramifications to physics, biology, mathematics, and computer science. As a result, mathematical and computational techniques capable of providing a quantitative account of the way that such complex states of flowing matter behave in space and time are becoming increasingly important. This book provides a unique description of a major technique, the Lattice Boltzmann method to accomplish this task. The Lattice Boltzmann method has gained a prominent role as an efficient computational tool for the numerical simulation of a wide variety of complex states of flowing matter across a broad range of scales; from fully-developed turbulence, to multiphase micro-flows, all the way down to nano-biofluidics and lately, even quantum-relativistic sub-nuclear fluids. After providing a self-contained introduction to the kinetic theory of fluids and a thorough account of its transcription to the lattice framework, this text provides a survey of the major developments which have led to the impressive growth of the Lattice Boltzmann across most walks of fluid dynamics and its interfaces with allied disciplines. Included are recent developments of Lattice Boltzmann methods for non-ideal fluids, micro- and nanofluidic flows with suspended bodies of assorted nature and extensions to strong non-equilibrium flows beyond the realm of continuum fluid mechanics. In the final part, it presents the extension of the Lattice Boltzmann method to quantum and relativistic matter, in an attempt to match the major surge of interest spurred by recent developments in the area of strongly interacting holographic fluids, such as electron flows in graphene.