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A thorough examination of kinetic theory and its successes in understanding and describing irreversible phenomena in physical systems.
The kinetic theory of gases as we know it dates to the paper of Boltzmann in 1872. The justification and context of this equation has been clarified over the past half century to the extent that it comprises one of the most complete examples of many-body analyses exhibiting the contraction from a microscopic to a mesoscopic description. The primary result is that the Boltzmann equation applies to dilute gases with short ranged interatomic forces, on space and time scales large compared to the corresponding atomic scales. Otherwise, there is no a priori limitation on the state of the system. This means it should be applicable even to systems driven very far from its eqUilibrium state. However, in spite of the physical simplicity of the Boltzmann equation, its mathematical complexity has masked its content except for states near eqUilibrium. While the latter are very important and the Boltzmann equation has been a resounding success in this case, the full potential of the Boltzmann equation to describe more general nonequilibrium states remains unfulfilled. An important exception was a study by Ikenberry and Truesdell in 1956 for a gas of Maxwell molecules undergoing shear flow. They provided a formally exact solution to the moment hierarchy that is valid for arbitrarily large shear rates. It was the first example of a fundamental description of rheology far from eqUilibrium, albeit for an unrealistic system. With rare exceptions, significant progress on nonequilibrium states was made only 20-30 years later.
Kinetic theory is the link between the non--equilibrium statistical mechanics of many particle systems and macroscopic or phenomenological physics. Therefore much attention is paid in this book both to the derivation of kinetic equations with their limitations and generalizations on the one hand, and to the use of kinetic theory for the description of physical phenomena and the calculation of transport coefficients on the other hand. The book is meant for researchers in the field, graduate students and advanced undergraduate students. At the end of each chapter a section of exercises is added not only for the purpose of providing the reader with the opportunity to test his understanding of the theory and his ability to apply it, but also to complete the chapter with relevant additions and examples that otherwise would have overburdened the main text of the preceding sections. The author is indebted to the physicists who taught him Statistical Mechanics, Kinetic Theory, Plasma Physics and Fluid Mechanics. I gratefully acknowledge the fact that much of the inspiration without which this book would not have been possible, originated from what I learned from several outstanding teachers. In particular I want to mention the late Prof. dr. H. C. Brinkman, who directed my first steps in the field of theoretical plasma physics, my thesis advisor Prof. dr. N. G. Van Kampen and Prof. dr. A. N. Kaufman, whose course on Non-Equilibrium Statistical Mechanics in Berkeley I remember with delight.
This introduction to the molecular theory of gases and modern transport theory includes such basic concepts as distribution function, classical theory of specific heats, binary collisions, mean free path and reaction rates, as well as topics relevant to advanced transport theory.
This book introduces physics students and teachers to the historical development of the kinetic theory of gases, by providing a collection of the most important contributions by Clausius, Maxwell and Boltzmann, with introductory surveys explaining their significance. In addition, extracts from the works of Boyle, Newton, Mayer, Joule, Helmholtz, Kelvin and others show the historical context of ideas about gases, energy and irreversibility. In addition to five thematic essays connecting the classical kinetic theory with 20th century topics such as indeterminism and interatomic forces, there is an extensive international bibliography of historical commentaries on kinetic theory, thermodynamics, etc. published in the past four decades.The book will be useful to historians of science who need primary and secondary sources to be conveniently available for their own research and interpretation, along with the bibliography which makes it easier to learn what other historians have already done on this subject.
In the present monograph, we develop the kinetic theory of transport phenomena and relaxation processes in the flows of reacting gas mixtures and discuss its applications to strongly non-equilibrium conditions. The main attention is focused on the influence of non-equilibrium kinetics on gas dynamics and transport properties. Closed systems of fluid dynamic equations are derived from the kinetic equations in different approaches. We consider the most accurate approach taking into account the state-to-state kinetics in a flow, as well as simplified multi-temperature and one-temperature models based on quasi-stationary distributions. Within these approaches, we propose the algorithms for the calculation of the transport coefficients and rate coefficients of chemical reactions and energy exchanges in non-equilibrium flows; the developed techniques are based on the fundamental kinetic theory principles. The theory is applied to the modeling of non-equilibrium flows behind strong shock waves, in the boundary layer, and in nozzles. The comparison of the results obtained within the frame of different approaches is presented, the advantages of the new state-to-state kinetic model are discussed, and the limits of validity for simplified models are established. The book can be interesting for scientists and graduate students working on physical gas dynamics, aerothermodynamics, heat and mass transfer, non-equilibrium physical-chemical kinetics, and kinetic theory of gases.
Chemical Reactor Modeling closes the gap between Chemical Reaction Engineering and Fluid Mechanics. The second edition consists of two volumes: Volume 1: Fundamentals. Volume 2: Chemical Engineering Applications In volume 1 most of the fundamental theory is presented. A few numerical model simulation application examples are given to elucidate the link between theory and applications. In volume 2 the chemical reactor equipment to be modeled are described. Several engineering models are introduced and discussed. A survey of the frequently used numerical methods, algorithms and schemes is provided. A few practical engineering applications of the modeling tools are presented and discussed. The working principles of several experimental techniques employed in order to get data for model validation are outlined. The monograph is based on lectures regularly taught in the fourth and fifth years graduate courses in transport phenomena and chemical reactor modeling and in a post graduate course in modern reactor modeling at the Norwegian University of Science and Technology, Department of Chemical Engineering, Trondheim, Norway. The objective of the book is to present the fundamentals of the single-fluid and multi-fluid models for the analysis of single and multiphase reactive flows in chemical reactors with a chemical reactor engineering rather than mathematical bias. Organized into 13 chapters, it combines theoretical aspects and practical applications and covers some of the recent research in several areas of chemical reactor engineering. This book contains a survey of the modern literature in the field of chemical reactor modeling.
This revision of an introductory text examines Newtonian liquids and polymer fluid mechanics. It begins with a review of the main ideas of fluid dynamics as well as key points of Newtonian fluids.