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Dr Palmer examines the chronological stages to the development of the concept of valency up to 1930.
Valency patterns and valency orientation have been frequent topics of research under different perspectives, often poorly connected. Diachronic studies on these topics is even less systematic than synchronic ones. The papers in this book bring together two strands of research on valency, i.e. the description of valency patterns as worked out in the Leipzig Valency Classes Project (ValPaL), and the assessment of a language's basic valency and its possible orientation. Notably, the ValPaL does not provide diachronic information concerning the valency patterns investigated: one of the aims of the book is to supplement the available data with data from historical stages of languages, in order to make it profitably exploitable for diachronic research. In addition, new research on the diachrony of basic valency and valency alternations can deepen our understanding of mechanisms of language change and of the propensity of languages or language families to exploit different constructional patterns related to transitivity.
This classic exposition explores the origins of chemistry, alchemy, early medical chemistry, nature of atmosphere, theory of valency, laws and structure of atomic theory, and much more.
Orbital Symmetry: A Problem-Solving Approach was born of the necessity to present to students Woodward and Hoffmann's approach to pericyclic reactions. Hence the tone is introductory, and the book is addressed primarily to an audience of advanced undergraduate and beginning graduate students. The text seeks to familiarize the readers with several of the more often encountered methods of analyzing pericyclic reactions, and these methods should enable the analysis of virtually all of them. Problem solving is the foundation of the approach. Both the introductory and theory sections include problems to prepare the reader for the more extensive chapters of problems that follow. All problems (except those in Chapter VII) are answered in the text and are fully referenced where appropriate. Many of the problems require the use of molecular models if they are to be appreciated. Prentice-Hall's ""Framework Molecular Models"" and Benjamin's ""Maruzen Models"" are best suited for the construction of the highly strained molecules often encountered in the problems, and their use is recommended.
Both a history and a metahistory, Representing Electrons focuses on the development of various theoretical representations of electrons from the late 1890s to 1925 and the methodological problems associated with writing about unobservable scientific entities. Using the electron—or rather its representation—as a historical actor, Theodore Arabatzis illustrates the emergence and gradual consolidation of its representation in physics, its career throughout old quantum theory, and its appropriation and reinterpretation by chemists. As Arabatzis develops this novel biographical approach, he portrays scientific representations as partly autonomous agents with lives of their own. Furthermore, he argues that the considerable variance in the representation of the electron does not undermine its stable identity or existence. Raising philosophical issues of contentious debate in the history and philosophy of science—namely, scientific realism and meaning change—Arabatzis addresses the history of the electron across disciplines, integrating historical narrative with philosophical analysis in a book that will be a touchstone for historians and philosophers of science and scientists alike.
The first scientific biography of Edward Frankland, the most eminent chemist of nineteenth-century Britain.
The history of science is articulated by moments of discovery. Yet, these 'moments' are not simple or isolated events in science. Just as a scientific discovery illuminates our understanding of nature or of society, and reveals new connections among phenomena, so too does the history of scientific activity and the analysis of scientific reasoning illuminate the processes which give rise to moments of discovery and the complex network of consequences which follow upon such moments. Understanding discovery has not been, until recently, a major concern of modem philosophy of science. Whether the act of discoyery was regarded as mysterious and inexplicable, or obvious and in no need of explanation, modem philosophy of science in effect bracketed the question. It concentrated instead on the logic of scientific explanation or on the issues of validation or justification of scientific theories or laws. The recent revival of interest in the context of discovery, indeed in the acts of discovery, on the part of philosophers and historians of science, represents no one particular method'ological or philosophical orientation. It proceeds as much from an empiricist and analytical approach as from a sociological or historical one; from considerations of the logic of science as much as from the alogical or extralogical contexts of scientific tho'¢tt and practice. But, in general, this new interest focuses sharply on the actual historical and contem porary cases of scientific discovery, and on an examination of the act or moment of discovery in situ.
The correlation of spectroscopic and chemical investigations in recent years has been highly beneficial of many reasons. Around 1950, no valid explanation was available of the colours of compounds of the five tran sition groups. Later, it was possible to identify the excited levels with those expected for an electron configuration with adefinite number of electrons in the partly filled shell. I t is not generally recognized that this is equivalent to determining spectroscopic oxidation states related to the preponderant electron configuration and not to estimates of the fractional atomic charges. This brings in an entirely different type of description than the formal oxidation numbers used for characterizing compounds and reaction schemes. However, it must be realized that collectively oxidized ligands, formation of cluster-complexes and catenation may prevent the oxidation state from being well-defined. The writer would like to express his gratitude to many, but first of all to DR. CLAUS SCHÄFFER, University of Copenhagen, who is the most efficient group-theoretical engineer known to the writer; his comments and discussions have been highly valuable. The writer's colleague, Pro fessor FAUSTO CALDERAZZO (now going to the University of Pisa) has been most helpful in metallo-organic questions. Thanks are also due to Professors E. RANcKE-MADsEN and K. A. JENSEN for correspondence and conversations about formal oxidation numbers.