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There are only a few discoveries and new technologies in materials science that have the potential to dramatically alter and revolutionize our material world. Discovery of two-dimensional (2D) materials, the thinnest form of materials to ever occur in nature, is one of them. After isolation of graphene from graphite in 2004, a whole other class of atomically thin materials, dominated by surface effects and showing completely unexpected and extraordinary properties, has been created. This book provides a comprehensive view and state-of-the-art knowledge about 2D materials such as graphene, hexagonal boron nitride (h-BN), transition metal dichalcogenides (TMD) and so on. It consists of 11 chapters contributed by a team of experts in this exciting field and provides latest synthesis techniques of 2D materials, characterization and their potential applications in energy conservation, electronics, optoelectronics and biotechnology.
This book aims to serve as a practical guide for novices to design and conduct measurements of thermal properties at the nanoscale using electrothermal techniques. An outgrowth of the authors’ tutorials for new graduate students in their own labs, it includes practical details on measurement design and selection, sensitivity and uncertainty analysis, and pitfalls and verifications. The information is particularly helpful for someone setting up their own experiment for the first time. The book emphasizes the integration of thermal analysis with practical experimental considerations, in order to design an experiment for best sensitivity and to configure the laboratory instruments accordingly. The focus is on the measurements of thermal conductivity, though thermal diffusivity and thermal boundary resistance (thermal contact resistance) are also briefly covered, and many of the principles can be generalized to other challenging thermal measurements.The reader is only expected to have the basic familiarity with electrical instruments typical of a university graduate in science or engineering, and an acquaintance with the elementary laws of heat transfer by conduction, convection, and radiation.
``Electron-Electron Interactions in Disordered Systems'' deals with the interplay of disorder and the Coulomb interaction. Prominent experts give state-of-the-art reviews of the theoretical and experimental work in this field and make it clear that the interplay of the two effects is essential, especially in low-dimensional systems.
This is a graduate level textbook in nanoscale heat transfer and energy conversion that can also be used as a reference for researchers in the developing field of nanoengineering. It provides a comprehensive overview of microscale heat transfer, focusing on thermal energy storage and transport. Chen broadens the readership by incorporating results from related disciplines, from the point of view of thermal energy storage and transport, and presents related topics on the transport of electrons, phonons, photons, and molecules. This book is part of the MIT-Pappalardo Series in Mechanical Engineering.
Monoelemental 2D materials called Xenes have a graphene-like structure, intra-layer covalent bond, and weak van der Waals forces between layers. Materials composed of different groups of elements have different structures and rich properties, making Xenes materials a potential candidate for the next generation of 2D materials. 2D Monoelemental Materials (Xenes) and Related Technologies: Beyond Graphene describes the structure, properties, and applications of Xenes by classification and section. The first section covers the structure and classification of single-element 2D materials, according to the different main groups of monoelemental materials of different components and includes the properties and applications with detailed description. The second section discusses the structure, properties, and applications of advanced 2D Xenes materials, which are composed of heterogeneous structures, produced by defects, and regulated by the field. Features include: Systematically detailed single element materials according to the main groups of the constituent elements Classification of the most effective and widely studied 2D Xenes materials Expounding upon changes in properties and improvements in applications by different regulation mechanisms Discussion of the significance of 2D single-element materials where structural characteristics are closely combined with different preparation methods and the relevant theoretical properties complement each other with practical applications Aimed at researchers and advanced students in materials science and engineering, this book offers a broad view of current knowledge in the emerging and promising field of 2D monoelemental materials.
Raman spectroscopy is the inelastic scattering of light by matter. Being highly sensitive to the physical and chemical properties of materials, as well as to environmental effects that change these properties, Raman spectroscopy is now evolving into one of the most important tools for nanoscience and nanotechnology. In contrast to usual microscopyrelated techniques, the advantages of using light for nanoscience relate to both experimental and fundamental aspects.
This book summarizes the basic physics of graphite and newly discovered phenomena in this material. The book contains the knowledge needed to understand novel properties of functionalized graphite demonstrating the occurrence of remarkable phenomena in disordered graphite and graphite-based heterostructures. It also discusses applications of thin graphitic samples in future electronics. Graphite consists of a stack of nearly decoupled two-dimensional graphene planes. Because of the low dimensionality and the presence of Dirac fermions, much of graphite physics resembles that of graphene. On the other hand, the multi-layered nature of the graphite structure together with structural and/or chemical disorder are responsible for phenomena that are not observed yet in graphene, such as ferromagnetic order and superconductivity. Each chapter was written by one or more experts in the field whose contributions were relevant in the (re)discovery of (un)known phenomena in graphite. The book is intended as reference for beginners and experts in the field, introducing them to many aspects of the new physics of graphite, with a fresh overview of recently found phenomena and the theoretical frames to understand them.
This book contains 35 review articles on nanoscience and nanotechnology that were first published in Nature Nanotechnology, Nature Materials and a number of other Nature journals. The articles are all written by leading authorities in their field and cover a wide range of areas in nanoscience and technology, from basic research (such as single-molecule devices and new materials) through to applications (in, for example, nanomedicine and data storage).
Defects in Two-Dimensional Materials addresses the fundamental physics and chemistry of defects in 2D materials and their effects on physical, electrical and optical properties. The book explores 2D materials such as graphene, hexagonal boron nitride (h-BN) and transition metal dichalcogenides (TMD). This knowledge will enable scientists and engineers to tune 2D materials properties to meet specific application requirements. The book reviews the techniques to characterize 2D material defects and compares the defects present in the various 2D materials (e.g. graphene, h-BN, TMDs, phosphorene, silicene, etc.). As two-dimensional materials research and development is a fast-growing field that could lead to many industrial applications, the primary objective of this book is to review, discuss and present opportunities in controlling defects in these materials to improve device performance in general or use the defects in a controlled way for novel applications. Presents the theory, physics and chemistry of 2D materials Catalogues defects of 2D materials and their impacts on materials properties and performance Reviews methods to characterize, control and engineer defects in 2D materials
Understanding non-equilibrium properties of classical and quantum many-particle systems is one of the goals of contemporary statistical mechanics. Besides its own interest for the theoretical foundations of irreversible thermodynamics(e.g. of the Fourier's law of heat conduction), this topic is also relevant to develop innovative ideas for nanoscale thermal management with possible future applications to nanotechnologies and effective energetic resources. The first part of the volume (Chapters 1-6) describes the basic models, the phenomenology and the various theoretical approaches to understand heat transport in low-dimensional lattices (1D e 2D). The methods described will include equilibrium and nonequilibrium molecular dynamics simulations, hydrodynamic and kinetic approaches and the solution of stochastic models. The second part (Chapters 7-10) deals with applications to nano and microscale heat transfer, as for instance phononic transport in carbon-based nanomaterials, including the prominent case of nanotubes and graphene. Possible future developments on heat flow control and thermoelectric energy conversion will be outlined. This volume aims at being the first step for graduate students and researchers entering the field as well as a reference for the community of scientists that, from different backgrounds (theoretical physics, mathematics, material sciences and engineering), has grown in the recent years around those themes.