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A brand-new conceptual look at dynamical thermodynamics This book merges the two universalisms of thermodynamics and dynamical systems theory in a single compendium, with the latter providing an ideal language for the former, to develop a new and unique framework for dynamical thermodynamics. In particular, the book uses system-theoretic ideas to bring coherence, clarity, and precision to an important and poorly understood classical area of science. The dynamical systems formalism captures all of the key aspects of thermodynamics, including its fundamental laws, while providing a mathematically rigorous formulation for thermodynamical systems out of equilibrium by unifying the theory of mechanics with that of classical thermodynamics. This book includes topics on nonequilibrium irreversible thermodynamics, Boltzmann thermodynamics, mass-action kinetics and chemical reactions, finite-time thermodynamics, thermodynamic critical phenomena with continuous and discontinuous phase transitions, information theory, continuum and stochastic thermodynamics, and relativistic thermodynamics. A Dynamical Systems Theory of Thermodynamics develops a postmodern theory of thermodynamics as part of mathematical dynamical systems theory. The book establishes a clear nexus between thermodynamic irreversibility, the second law of thermodynamics, and the arrow of time to further unify discreteness and continuity, indeterminism and determinism, and quantum mechanics and general relativity in the pursuit of understanding the most fundamental property of the universe—the entropic arrow of time.
A brand-new conceptual look at dynamical thermodynamics This book merges the two universalisms of thermodynamics and dynamical systems theory in a single compendium, with the latter providing an ideal language for the former, to develop a new and unique framework for dynamical thermodynamics. In particular, the book uses system-theoretic ideas to bring coherence, clarity, and precision to an important and poorly understood classical area of science. The dynamical systems formalism captures all of the key aspects of thermodynamics, including its fundamental laws, while providing a mathematically rigorous formulation for thermodynamical systems out of equilibrium by unifying the theory of mechanics with that of classical thermodynamics. This book includes topics on nonequilibrium irreversible thermodynamics, Boltzmann thermodynamics, mass-action kinetics and chemical reactions, finite-time thermodynamics, thermodynamic critical phenomena with continuous and discontinuous phase transitions, information theory, continuum and stochastic thermodynamics, and relativistic thermodynamics. A Dynamical Systems Theory of Thermodynamics develops a postmodern theory of thermodynamics as part of mathematical dynamical systems theory. The book establishes a clear nexus between thermodynamic irreversibility, the second law of thermodynamics, and the arrow of time to further unify discreteness and continuity, indeterminism and determinism, and quantum mechanics and general relativity in the pursuit of understanding the most fundamental property of the universe—the entropic arrow of time.
The first complete proof of Arnold diffusion—one of the most important problems in dynamical systems and mathematical physics Arnold diffusion, which concerns the appearance of chaos in classical mechanics, is one of the most important problems in the fields of dynamical systems and mathematical physics. Since it was discovered by Vladimir Arnold in 1963, it has attracted the efforts of some of the most prominent researchers in mathematics. The question is whether a typical perturbation of a particular system will result in chaotic or unstable dynamical phenomena. In this groundbreaking book, Vadim Kaloshin and Ke Zhang provide the first complete proof of Arnold diffusion, demonstrating that that there is topological instability for typical perturbations of five-dimensional integrable systems (two and a half degrees of freedom). This proof realizes a plan John Mather announced in 2003 but was unable to complete before his death. Kaloshin and Zhang follow Mather's strategy but emphasize a more Hamiltonian approach, tying together normal forms theory, hyperbolic theory, Mather theory, and weak KAM theory. Offering a complete, clean, and modern explanation of the steps involved in the proof, and a clear account of background material, this book is designed to be accessible to students as well as researchers. The result is a critical contribution to mathematical physics and dynamical systems, especially Hamiltonian systems.
This self-contained monograph presents a unified exposition of the thermodynamic formalism and some of its main extensions, with emphasis on the relation to dimension theory and multifractal analysis of dynamical systems. In particular, the book considers three different flavors of the thermodynamic formalism, namely nonadditive, subadditive, and almost additive, and provides a detailed discussion of some of the most significant results in the area, some of them quite recent. It also includes a discussion of the most substantial applications of these flavors of the thermodynamic formalism to dimension theory and multifractal analysis of dynamical systems.
Properties of systems with long range interactions are still poorly understood despite being of importance in most areas of physics. The present volume introduces and reviews the effort of constructing a coherent thermodynamic treatment of such systems by combining tools from statistical mechanics with concepts and methods from dynamical systems. Analogies and differences between various systems are examined by considering a large range of applications, with emphasis on Bose--Einstein condensates. Written as a set of tutorial reviews, the book will be useful for both the experienced researcher as well as the nonexpert scientist or postgraduate student.
Combustion Thermodynamics and Dynamics builds on a foundation of thermal science, chemistry, and applied mathematics that will be familiar to most undergraduate aerospace, mechanical, and chemical engineers to give a first-year graduate-level exposition of the thermodynamics, physical chemistry, and dynamics of advection-reaction-diffusion. Special effort is made to link notions of time-independent classical thermodynamics with time-dependent reactive fluid dynamics. In particular, concepts of classical thermochemical equilibrium and stability are discussed in the context of modern nonlinear dynamical systems theory. The first half focuses on time-dependent spatially homogeneous reaction, while the second half considers effects of spatially inhomogeneous advection and diffusion on the reaction dynamics. Attention is focused on systems with realistic detailed chemical kinetics as well as simplified kinetics. Many mathematical details are presented, and several quantitative examples are given. Topics include foundations of thermochemistry, reduced kinetics, reactive Navier–Stokes equations, reaction-diffusion systems, laminar flame, oscillatory combustion, and detonation.
Printed Edition of the Special Issue Published in Entropy
Nonlinear Dynamical Systems and Control presents and develops an extensive treatment of stability analysis and control design of nonlinear dynamical systems, with an emphasis on Lyapunov-based methods. Dynamical system theory lies at the heart of mathematical sciences and engineering. The application of dynamical systems has crossed interdisciplinary boundaries from chemistry to biochemistry to chemical kinetics, from medicine to biology to population genetics, from economics to sociology to psychology, and from physics to mechanics to engineering. The increasingly complex nature of engineering systems requiring feedback control to obtain a desired system behavior also gives rise to dynamical systems. Wassim Haddad and VijaySekhar Chellaboina provide an exhaustive treatment of nonlinear systems theory and control using the highest standards of exposition and rigor. This graduate-level textbook goes well beyond standard treatments by developing Lyapunov stability theory, partial stability, boundedness, input-to-state stability, input-output stability, finite-time stability, semistability, stability of sets and periodic orbits, and stability theorems via vector Lyapunov functions. A complete and thorough treatment of dissipativity theory, absolute stability theory, stability of feedback systems, optimal control, disturbance rejection control, and robust control for nonlinear dynamical systems is also given. This book is an indispensable resource for applied mathematicians, dynamical systems theorists, control theorists, and engineers.
This book deals with the various thermodynamic concepts used for the analysis of nonlinear dynamical systems. The most important invariants used to characterize chaotic systems are introduced in a way that stresses the interconnections with thermodynamics and statistical mechanics. Among the subjects treated are probabilistic aspects of chaotic dynamics, the symbolic dynamics technique, information measures, the maximum entropy principle, general thermodynamic relations, spin systems, fractals and multifractals, expansion rate and information loss, the topological pressure, transfer operator methods, repellers and escape. The more advanced chapters deal with the thermodynamic formalism for expanding maps, thermodynamic analysis of chaotic systems with several intensive parameters, and phase transitions in nonlinear dynamics.
The first comprehensive graduate-level introduction to stochastic thermodynamics Stochastic thermodynamics is a well-defined subfield of statistical physics that aims to interpret thermodynamic concepts for systems ranging in size from a few to hundreds of nanometers, the behavior of which is inherently random due to thermal fluctuations. This growing field therefore describes the nonequilibrium dynamics of small systems, such as artificial nanodevices and biological molecular machines, which are of increasing scientific and technological relevance. This textbook provides an up-to-date pedagogical introduction to stochastic thermodynamics, guiding readers from basic concepts in statistical physics, probability theory, and thermodynamics to the most recent developments in the field. Gradually building up to more advanced material, the authors consistently prioritize simplicity and clarity over exhaustiveness and focus on the development of readers’ physical insight over mathematical formalism. This approach allows the reader to grow as the book proceeds, helping interested young scientists to enter the field with less effort and to contribute to its ongoing vibrant development. Chapters provide exercises to complement and reinforce learning. Appropriate for graduate students in physics and biophysics, as well as researchers, Stochastic Thermodynamics serves as an excellent initiation to this rapidly evolving field. Emphasizes a pedagogical approach to the subject Highlights connections with the thermodynamics of information Pays special attention to molecular biophysics applications Privileges physical intuition over mathematical formalism Solutions manual available on request for instructors adopting the book in a course