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This volume provides an overview of current research and recent advances in the area of energetic materials, focusing on explosives and propellants. The contents and format reflect the fact that theory, experiment and computation are closely linked in this field. The challenge of developing energetic materials that are less sensitive to accidental stimuli continues to be of critical importance. This volume opens with discussions of some determinants of sensitivity and its correlations with various molecular and crystal properties. The next several chapters deal in considerable detail with different aspects and mechanisms of the initiation of detonation, and its quantitative description. The second half of this volume focuses upon combustion. Extensive studies model ignition and combustion, with applications to different propellants. The final chapter is an exhaustive computational treatment of the mechanism and kinetics of combustion initiation reactions of ammonium perchlorate. Overall, this volume illustrates the progress that has been made in the field of energetic materials and some of the areas of current activity. It also indicates the challenges involved in characterizing and understanding the properties and behaviour of these compounds. The work is a unique state-of-the-art treatment of the subject, written by pre-eminent researchers in the field. - Overall emphasis is on theory and computation, presented in the context of relevant experimental work - Presents a unique state-of-the-art treatment of the subject - Contributors are preeminent researchers in the field
This edited book contains state-of-the-art information associated with energetic material combustion. There are twelve topical areas, including: Reaction Kinetics of Energetic Materials (Solid, Liquid, and Gel Propellants); Recycling of Energetic Materials; Combustion Performance of Hybrid and Solid Rocket Motors; Ignition and Combustion of Energetic Materials; Energetic Material Defects and Rocket Engine Flowfields; Metal Combustion; Pyrolysis and Combustion Processes of New Ingredients and Applications; Theoretical Modeling and Numerical Simulation of Combustion Processes of Energetic Materials; Combustion Diagnostic Techniques; Propellant and Rocket Motor Stability; Commercial Applications of Energetic Materials (Airbags, Gas Generators, etc.); and Thermal Insulation and Ablation Processes.
Developed and expanded from the work presented at the New Energetic Materials and Propulsion Techniques for Space Exploration workshop in June 2014, this book contains new scientific results, up-to-date reviews, and inspiring perspectives in a number of areas related to the energetic aspects of chemical rocket propulsion. This collection covers the entire life of energetic materials from their conceptual formulation to practical manufacturing; it includes coverage of theoretical and experimental ballistics, performance properties, as well as laboratory-scale and full system-scale, handling, hazards, environment, ageing, and disposal. Chemical Rocket Propulsion is a unique work, where a selection of accomplished experts from the pioneering era of space propulsion and current technologists from the most advanced international laboratories discuss the future of chemical rocket propulsion for access to, and exploration of, space. It will be of interest to both postgraduate and final-year undergraduate students in aerospace engineering, and practicing aeronautical engineers and designers, especially those with an interest in propulsion, as well as researchers in energetic materials.
This book summarizes science and technology of a new generation of high-energy andinsensitive explosives. The objective is to provide professionals with comprehensiveinformation on the synthesis and the physicochemical and detonation properties ofthe explosives. Potential technologies applicable for treatment of contaminated wastestreams from manufacturing facilities and environmental matrices are also be included.This book provides the reader an insight into the depth and breadth of theoreticaland empirical models and experimental techniques currently being developed in thefield of energetic materials. It presents the latest research by DoD engineers andscientists, and some of DoD’s academic and industrial researcher partners. The topicsexplored and the simulations developed or modified for the purposes of energetics mayfind application in other closely related fields, such as the pharmaceutical industry.One of the key features of the book is the treatment of wastewaters generated duringmanufacturing of these energetic materials.
This handbook provides extremely useful data and information about theory and industrial applications that formerly were limited to applications in military ordnance, fireworks, and rock blasting. These "civilian" applications include spacecraft, aircraft, underwater vehicle systems, metal forming, cladding, riveting and some other production methods. Also pairs well with: Fireworks, Principles and Practice, 4th Edition, ISBN: 0820604070; Military and Civilian Pyrotechnics, ISBN: 0820603643; Pyrotechnics, ISBN: 0820601128. Visit us at www.chemical-publishing.com
The Karl Fischer titration is used in many different ways following its publication in 1935 and further applications are continually being explored. At the present time we are experiencing another phase of expansion, as shown by the development of new titration equipment and new reagents. KF equipment increasingly incorporates microprocessors which enable the course of a titration to be programmed thus sim plifying the titration. Coulometric titrators allow water determinations in the micro gram-range: the KF titration has become a micro-method. The new pyridine-free re agents make its application significantly more pleasant and open up further possibili ties on account of their accuracy. To make the approach to Karl Fischer titrations easier, we have summarized the present knowledge in this monograph and we have complemented it with our own studies and practical experience. As this book should remain "readable", we have tried to keep the fundamentals to a minimum. Historical developments are only mentioned if they seem to be necessary for understanding the KF reaction. The ap plications are described more fully. Specific details which may interest a particular reader can be found in the original publications cited. The referenced literature is in chronological order as the year of publication may also prove informative. Thus, [6902] for example denotes 69 for 1969 being the year of publication and 02 is a non-recurring progressive number. The referenced litera ture includes summaries which we hope will be of help to find the "right" publica tion easily.
This third edition of the classic on the thermochemical aspects of the combustion of propellants and explosives is completely revised and updated and now includes a section on green propellants and offers an up-to-date view of the thermochemical aspects of combustion and corresponding applications. Clearly structured, the first half of the book presents an introduction to pyrodynamics, describing fundamental aspects of the combustion of energetic materials, while the second part highlights applications of energetic materials, such as propellants, explosives and pyrolants, with a focus on the phenomena occurring in rocket motors. Finally, an appendix gives a brief overview of the fundamentals of aerodynamics and heat transfer, which is a prerequisite for the study of pyrodynamics. A detailed reference for readers interested in rocketry or explosives technology.